Polyols having reduced terminal unsaturation and a process for producing same
AssigneeThe Dow Chemical Company
InventorsZenon Lysenko, Ritchie A. Wessling
Life of this patent
Estimating the term…
Abstract
The unsaturation of a hydroxyl-containing compound can be reduced by reaction with a nitrile oxide compound such as tetramethyl terephthalonitrile, N,N'-dioxide. The reaction of a nitrile oxide with terminal unsaturation associated with the preparation of a polyol from propylene oxide reduces the monol content of the polyol composition.
Claims15
A composition comprising (a) a polyol of the formula:
- I((CH.sub.2 --CH(R')--O).sub.n --H).sub.m
- wherein I is an initiator remnant;
- R.sup.1 is hydrogen or alkyl, in each occurrence;
- n is an integer from 1 to 200;and m is an integer from 2 to 8 and (b) a polyol having an isoxazoline group.
A composition comprising (a) a polyether polyol having a poly(propylene oxide/ethylene oxide) group or a poly(propylene oxide) group and (b) the reaction product of a nitrile oxide with a propoxylated allyl alcohol.
Dependencies are inferred from the claim text.