Composite gage and drain hole sealer
AssigneesE. I. Du Pont de Nemours and Company, Sika Corporation
InventorsRalph Delle Donne, Elizabeth Alexander Schowe, John Lynch Hanley, IV, Rohit Kumar Shah
Life of this patent
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Abstract
A two-component, heat reactive patch particularly useful for sealing gage and drain holes in automobile bodies which comprises an ionomer component and an olefinic/elastomeric component. The ionomer component contains an ionomeric copolymer of ethylene and an .alpha.,.beta.-ethylenically-unsaturated C.sub.3 -C.sub.8 carboxylic acid, a metallic coagent and a filler and, optionally, a non-ionomeric copolymer of ethylene. The olefinic/elastomeric component contains an uncrosslinked elastomer, a multifunctional acrylic monomer, and a free-radical curing agent.
Claims18
A composite preformed thermoplastic patch for sealing aperture in a workpiece comprising two components, an ionomer component and an olefinic/elastomeric component:
- a. the ionomer component comprising a melt blend of:
- i. an ionomeric copolymer of ethylene and an .alpha.,.beta.-ethylenically-unsaturated C.sub.3 -C.sub.8 carboxylic acid partially neutralized with a metallic cation;
- ii. 0 to 25 parts by weight (based on 100 parts ionomeric copolymer) of a non-ionomeric copolymer of the form E/X.sub.ii /Y.sub.ii where E is ethylene;
- X.sub.ii is one or more monomers selected from alkyl acrylate, alkyl methacrylate, vinyl acetate and alkyl monoesters of dicarboxylic acid wherein the alkyl groups have from 1-12 carbon atoms;
- and Y.sub.ii is one or more monomers selected from .alpha.,.beta.-ethylenically-unsaturated C.sub.3 -C.sub.8 carboxylic acids;
- wherein X.sub.ii is 0 to 60 weight percent and Y.sub.ii is 0 to 35 weight percent of the E/X.sub.ii /Y.sub.ii copolymer provided that X.sub.ii must be present if Y.sub.ii is not and Y.sub.ii must be present if X.sub.ii is not;
- iii. 1 to 10 parts by weight (based on 100 parts ionomeric copolymer) of a metallic coagent selected from the group consisting of metallic salts of acrylic acid and metallic salts of methacrylic acid;
- and
- iv. 0.2 to 15 parts by weight (based on 100 parts ionomeric copolymer) of filler;
- and
- b. the olefinic/elastomeric component comprising:
- i. 25 to 90 weight percent of an uncrosslinked elastomer, an olefinic polymer or a blend of an uncrosslinked elastomer and an olefinic polymer;
- ii. 1 to 10 weight percent multifunctional acrylic monomer;
- and
- iii. 0.1 to 5 weight percent of a free-radical curing agent;
- wherein the ionomer-based component (a) and the olefinic/elastomeric component (b) are intimately contacted under conditions sufficient to bond the components as layers into a unitary multi-layer structure to insure intimate, positive contact between the layers so that the structure retains its unitary form during storage and is installable as an integral preformed patch in a single application over the aperture in the workpiece but are contacted under conditions that are insufficient to cause free radical polymerization at the interface between the layers.
Dependencies are inferred from the claim text.