Stabilized fluids containing soluble zinc
AssigneeTexas United Chemical Company, LLC.
InventorsJames W. Dobson, Jr., James P. Cashon
Life of this patent
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AssigneeTexas United Chemical Company, LLC.
InventorsJames W. Dobson, Jr., James P. Cashon
Estimating the term…
Disclosed are low solids, high density fluids useful as drilling, workover, and completion fluids and the like in oil and gas well operations. The fluids comprise a brine having dissolved therein a zinc salt such as zinc bromide, and optionally one or more additional water soluble salts, a viscosifier which is a high surface area silica, a biopolymer viscosifier, a fluid loss control additive which is preferably a starch derivative, zinc carbonate, and, optionally, an alkaline buffer, a polar additive, and a bridging agent. It has been found that zinc carbonate will increase the low shear rate viscosity of fluids containing a zinc salt dissolved therein. Additionally, the combination of zinc carbonate and zinc oxide as the alkaline buffer provides fluids having increased thermal stability as indicated by the low shear rate viscosity of the fluids.
A fluid useful in various downhole oil and gas well operations which comprises a brine having dissolved therein a zinc salt and, optionally, one or more additional water soluble salts, the brine having a density from about 1560 kg/m.sup.3 to about 2400 kg/m.sup.3, a silica viscosifier having an ultimate particle size less than about 100 millimicrons, a biopolymer viscosifier, a fluid loss control additive, and zinc carbonate, wherein the zinc carbonate is present in an mount sufficient to increase the low shear rate viscosity of the fluid.
The method of increasing the low shear rate viscosity of a fluid, the fluid comprising a brine having dissolved therein a zinc salt and one or more additional water soluble salts, the brine having a density from about 1560 kg/m.sup.3 to about 2400 kg/m.sup.3, a silica viscosifier having an ultimate particle size less than about 100 millimicrons, a biopolymer viscosifier, and a fluid loss control additive, which comprises adding to the fluid zinc carbonate.
Dependencies are inferred from the claim text.