Process for producing acetic acid
AssigneeDaicel Chemical Industries, Ltd.
InventorsYoshiaki Morimoto, Hiroyuki Nakayama, Takashi Ueno
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Abstract
The present invention provides a process for producing acetic acid by reacting continuously methanol, methyl acetate and the like with carbon monoxide in the presence of an eighth group metal-containing catalyst, methyl iodide and water, which is characterized in that wherein a liquid separation state in a decanter at the top of the first distillation column is maintained by adding water to the first distillation column. High quality acetic acid which has not so far been achieved can be obtained while controlling the purifying energy in a low level.
Claims1
A process for producing acetic acid by reacting continuously at least one selected from methanol, methyl acetate and dimethyl ether with carbon monoxide in the presence of an eighth group metal-containing catalyst, methyl iodide and water, comprising:
- (a) a step in which a crude reaction liquid is withdrawn from a carbonylation step and introduced into a flash zone, and a catalyst circulating liquid containing a catalyst component which is not evaporated in the flash zone is circulated into a carbonylation reactor,
- (b) a step in which a vapor fraction evaporated in the flash zone is fed into a first distillation column in the form of vapor and/or liquid,
- (c) a step in which a low boiling circulating stream comprising water, methyl acetate, methyl iodide, and acetic acid is withdrawn from the top of the first distillation column, and
- (d) a step in which crude acetic acid is withdrawn from the bottom or the side cut near the bottom of the first distillation column, wherein a liquid separation state in a decanter at the top of the first distillation column is maintained by reducing the concentration of methyl acetate contained in a liquid fed into the decanter at the top of the first distillation column to 40 wt % or less.
Dependencies are inferred from the claim text.