# US 5,710,626 A · Rugged fiber optic probe for raman measurement

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- Number: US 5,710,626 A
- Document ID: US5710626A
- Status: Granted
- Kind: A
- Application number: 08/746,711
- Filed: 1996-11-15
- Granted: 1998-01-20
- Earliest claimed: 1996-11-15
- Assignees: Westinghouse Savannah River Company
- Inventors: Patrick E. O'Rourke; William R. Toole, Jr.; Stanley E. Nave
- Web page: https://patentgrep.com/patent/US5710626A

## CPC

- G01J 3/44: Raman spectrometry; Scattering spectrometry {; Fluorescence spectrometry}
- G01J: MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY (light sources F21, H01J, H01K, H05B; investigating properties of materials by optical means G01N)

## Abstract

An optical probe for conducting light scattering analysis is disclosed. The probe comprises a hollow housing and a probe tip. A fiber assembly made up of a transmitting fiber and a receiving bundle is inserted in the tip. A filter assembly is inserted in the housing and connected to the fiber assembly. A signal line from the light source and to the spectrometer also is connected to the filter assembly and communicates with the fiber assembly. By using a spring-loaded assembly to hold the fiber connectors together with the in-line filters, complex and sensitive alignment procedures are avoided. The close proximity of the filter assembly to the probe tip eliminates or minimizes self-scattering generated by the optical fiber. Also, because the probe can contact the sample directly, sensitive optics can be eliminated.

## Claims

### Claim 1

An optical probe for use in light scattering analysis of a sample comprising:
a) a housing having a proximal end, a distal end and defining a first cavity;
b) a filter assembly positioned within the first cavity;
c) a probe tip positioned at the distal end of the housing and defining a second cavity which communicates with the first cavity;
d) a fiber assembly positioned within the second cavity and communicating with the filter assembly;
e) a transmitting/receiving line positioned in the first cavity and communicating with the filter assembly; and
f) at least one spring urging the fiber assembly and the transmitting receiving line together thereby holding the filter assembly therebetween.

### Claim 2 (depends on 1)

The probe of claim 1 in which the fiber assembly comprises:
a) a transmitting fiber having a proximal end and a distal end;
b) a receiving bundle having a proximal end and a distal end; and
c) an epoxy matrix in which distal ends of the transmitting fiber and the receiving bundle are embedded.

### Claim 3 (depends on 1)

The probe of claim 1 in which the probe tip comprises a housing having an end and a window affixed to the end in which the fiber assembly abuts the window.

### Claim 4 (depends on 2)

The probe of claim 2 in which the transmitting fiber comprises at least one optical fiber.

### Claim 5 (depends on 2)

The probe of claim 2 in which the receiving bundle comprises at least one optical fiber.

### Claim 6 (depends on 2)

The probe of claim 2 in which the receiving bundle comprises a plurality of optical fibers.

### Claim 7 (depends on 2)

The probe of claim 2 in which the receiving bundle comprises six optical fibers.

### Claim 8 (depends on 2)

The probe of claim 2 in which the transmitting fiber comprises a silica core fiber optic cable with doped silica cladding having a low OH and a polyimide buffer.

### Claim 9 (depends on 2)

The probe of claim 2 in which the receiving bundle comprises at least one silica core fiber optic cable with doped silica cladding having a low OH and a polyimide buffer.

### Claim 10 (depends on 2)

The probe of claim 2 in which the receiving bundle comprises a plurality of silica core fiber optic cables with doped silica cladding having a low OH and a polyimide buffer.

### Claim 11 (depends on 2)

The probe of claim 2 in which the receiving bundle comprises six silica core fiber optic cables with doped silica cladding having a low OH and a polyimide buffer.

### Claim 12 (depends on 2)

The probe of claim 2 in which the fiber assembly further comprises:
a) a first connector attached to the proximal end of the transmitting fiber; and
b) a second connector attached to the proximal end of the receiving bundle.

### Claim 13 (depends on 12)

The probe of claim 12 in which the transmitting/receiving line comprises:
a) a transmitting line having a proximal end and a distal end, the proximal end connected to a light source and the distal end affixed to a third connector; and
b) a receiving line having a proximal end and a distal end, the proximal end connected to a spectrometer and the distal end affixed to a fourth connector.

### Claim 14 (depends on 13)

The probe of claim 13 in which the transmitting line comprises at least one optical fiber.

### Claim 15 (depends on 13)

The probe of claim 13 in which the transmitting line comprises at least one silica core fiber optic cable with doped silica cladding having a low OH and a polyimide buffer.

### Claim 16 (depends on 13)

The probe of claim 13 in which the receiving line comprises at least one optical fiber.

### Claim 17 (depends on 13)

The probe of claim 13 in which the receiving line comprises at least one silica core fiber optic cable with doped silica cladding having a low OH and a polyimide buffer.

### Claim 18 (depends on 13)

The probe of claim 13 in which the receiving line comprises a plurality of optical fibers.

### Claim 19 (depends on 13)

The probe of claim 13 in which the receiving line comprises a plurality of silica core fiber optic cables with doped silica cladding having a low OH and a polyimide buffer.

### Claim 20 (depends on 13)

The probe of claim 13 in which the filter assembly comprises:
a) a cylinder having a first bore and a second bore;
b) an input filter disposed in the first bore; and
c) an output filter disposed in the second bore.

### Claim 21 (depends on 20)

The probe of claim 20 in which the first connector and the third connector are positioned in the first bore with the input filter disposed therebetween.

### Claim 22 (depends on 21)

The probe of claim 21 in which the second connector and the fourth connector are positioned in the second bore with the output filter disposed therebetween.

### Claim 23 (depends on 22)

The probe of claim 22 in which the first, second, third and fourth connectors are held in position by at least one spring positioned within the first cavity such that the spring urges the first and third connectors together and the second and fourth connectors together.

### Claim 24 (depends on 20)

The probe of claim 20 in which the first, second, third and fourth connectors are conventional SMA connectors with the hoods removed.

### Claim 25 (depends on 20)

The probe of claim 20 in which the light source is a laser having a laser line.

### Claim 26 (depends on 25)

The probe of claim 25 in which the input filter is a laser pass dielectric filter having greater than seventy-five percent transmission at the laser line with a half-width corresponding to five-hundred cm-1.

### Claim 27 (depends on 26)

The probe of claim 26 in which the output filter is a long-pass dielectric filter with forty decibel or greater blocking at the laser line but greater than seventy-five percent transmission for wavelengths about five-hundred cm-1 or more away from the laser line.

### Claim 28

An optical probe for use in light scattering analysis of a sample comprising:
a) a housing;
b) first carrying means, positioned within the housing, for carrying first and second test signals in which the first test signal is delivered to a sample and the second test signal is received from the sample;
c) second carrying means, positioned within the housing and communicating with the first carrying means, for carrying the first and second test signals;
d) means, interposed between the first and second carrying means, for filtering the first test signal;
e) means, interposed between the first and second carrying means, for filtering the second test signal; and
f) means for urging the first and second carrying means together thereby holding the first and second test signal filtering means therebetween.

### Claim 29 (depends on 28)

The optical probe of claim 28 in which the first carrying means comprises:
a) a transmitting fiber having a proximal end, which is affixed within a first SMA connector, and a distal end, which is affixed in a matrix; and
b) a receiving bundle having a proximal end, which is affixed within a second SMA connector, and a distal end, which is affixed in the matrix proximate the transmitting fiber.

### Claim 30 (depends on 29)

The optical probe of claim 29 in which the second carrying means comprises:
a) a transmitting line having a distal end, which is affixed within a third SMA connector, and a proximal end, which communicates with a light source; and
b) a receiving line having a distal end, which is affixed within a fourth SMA connector, and a proximal end, which communicates with a detector.

### Claim 31 (depends on 30)

The optical probe of claim 30 in which:
a) the first test signal filtering means comprises an input filter disposed between the transmitting line and the transmitting fiber; and
b) the second test signal filtering means comprises an output filter disposed between the receiving line and the receiving bundle.

### Claim 32 (depends on 31)

The optical probe of claim 31 in which the urging means comprises at least one coil spring.