# US 5,710,360 A · Thermal desorption system for decontaminating materials > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 5,710,360 A - Document ID: US5710360A - Status: Granted - Kind: A - Application number: 08/728,429 - Filed: 1996-10-09 - Granted: 1998-01-20 - Earliest claimed: 1995-03-31 - Assignees: Vanish, Inc. - Inventors: John R. Self; Robert A. Olexy - Web page: https://patentgrep.com/patent/US5710360A ## CPC - B09C 1/06: thermally - A62D 3/40: by heating to effect chemical change, e.g. pyrolysis - B01J 19/0013: {Controlling the temperature of the process} - B01J 19/20: in the form of helices, e.g. screw reactors - B09B 3/35: Shredding, crushing or cutting - A62D 2101/20: Organic substances - A62D 2101/40: Inorganic substances - A62D 2203/10: Apparatus specially adapted for treating harmful chemical agents; Details thereof - B01J 2219/00058: Temperature measurement - B01J 2219/0009: Coils - B01J 2219/00135: Electric resistance heaters - B01J 2219/182: horizontal - Y10S 588/90: Apparatus - B09C: RECLAMATION OF CONTAMINATED SOIL (gatherers for removing stone or the like from the soil A01B43/00; sterilising soil by steam A01G11/00; removing undesirable matter, e.g. rubbish, from the land E01H15/00) - A62D: CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS - B01J: CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS - B09B: DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR - Y10S: TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS ## Abstract A thermal desorption system for treating and/or removing contaminants from various types of materials employs an induction tube furnace to heat the material to a high enough temperature to completely desorb it. The induction tube furnace includes a metal or metal alloy susceptor tube for containing the material to be treated and at least one induction coil surrounding the tube for heating the same. The susceptor tube is formed from a metal or metal alloy, such as a nickel based alloy, having a very high melting temperature which will allow it to be heated by the induction coil to temperatures as high as 1800.degree. F. The metal or metal alloy also has a relatively high electrical resistance to permit efficient magnetic coupling of energy from the induction coil to the tube, as well as a relatively high thermal conductivity to provide efficient heat transfer from the tube to the material to be treated. Depending upon the nature of the material to be treated, an auger type conveyor can be employed to move the material through the susceptor tube at a controlled rate of speed, which in turn controls the residence time of the material in the tube, and therefore the temperature to which it is heated. An inert atmosphere is maintained within the tube to prevent combustion of the material, and the vaporized contaminants exiting the susceptor tube are condensed for recovery and recycling, while the desorbed material in the form of char is removed for disposal in a conventional manner. ## Claims ### Claim 1 A thermal desorption system for decontaminating materials comprising: an induction tube furnace for heating contaminated materials to be decontaminated, said induction tube furnace including: a metal susceptor tube for receiving materials to be heated, said susceptor tube being formed from a metal having a melting temperature higher than approximately 2300.degree. F., and an electrical resistance of greater than approximately 100 .mu.ohm-cm at 1800.degree. F.; and at least one induction coil surrounding said susceptor tube for heating said tube to a temperature sufficient to completely desorb material contained in said susceptor tube; means for charging material to be decontaminated into said susceptor tube; at least one power supply for supplying current to said at least one induction coil to heat said susceptor tube; means for maintaining an inert atmosphere in said susceptor tube during heating of said material therein; means for removing from said susceptor tube, vaporized contaminants that are released from the material when it is heated; and means for removing desorbed material from said susceptor tube after it has been heated therein. ### Claim 2 (depends on 1) The system of claim 1, wherein said metal susceptor tube is formed from a metal having a thermal conductivity of greater than or equal to approximately 195 BTU-in/ft.sup.2 -hr-.degree.F. at 1800 .degree. F. ### Claim 3 (depends on 2) The system of claim 2, wherein said metal susceptor tube is formed from a metal having a mean coefficient of thermal expansion of less than approximately 9.5 .mu.in/in-.degree.F. at 1800.degree. F. ### Claim 4 (depends on 3) The system of claim 3, wherein said metal susceptor tube is formed from a nickel based alloy. ### Claim 5 (depends on 4) The system of claim 4, wherein said metal susceptor tube is formed from material consisting of one of the two following compositions: ______________________________________ Chemical Element Weight Percentage ______________________________________ Composition 1 Ni 57 Co 5 Fe 3 Cr 22 W 14 Mo 2 Mn 0.5 Si 0.4 Al 0.3 C 0.10 La 0.02 B 0.015 Composition 2 Ni 76.5 Co 0.05 Fe 6.86 Cr 15.8 Mo 0.01 Mn 0.20 Si 0.09 Al 0.046 C 0.042 P 0.011 S 0.001 Cu 0.02 Ti 0.32 N 0.012 Cb 0.02 ______________________________________ ›Haynes .RTM. 230 .TM. Alloy!. ### Claim 6 (depends on 1) The system of claim 1, wherein said metal susceptor tube is formed from a nickel based alloy. ### Claim 7 (depends on 6) The system of claim 6, wherein said metal susceptor tube is formed from material consisting of one of the two following compositions: ______________________________________ Chemical Element Weight Percentage ______________________________________ Composition 1 Ni 57 Co 5 Fe 3 Cr 22 W 14 Mo 2 Mn 0.5 Si 0.4 Al 0.3 C 0.10 La 0.02 B 0.015 Composition 2 Ni 76.5 Co 0.05 Fe 6.86 Cr 15.8 Mo 0.01 Mn 0.20 Si 0.09 Al 0.046 C 0.042 P 0.011 S 0.001 Cu 0.02 Ti 0.32 N 0.012 Cb 0.02 ______________________________________ ›Haynes .RTM. 230 .TM. Alloy!. ### Claim 8 (depends on 1) The system of claim 1, further comprising: a conveyor disposed in said susceptor tube for conveying material to be heated therein through said susceptor tube; a variable speed motor for driving said conveyor; a plurality of temperature sensing devices for sensing the temperature of said susceptor tube and of material and contaminated vapors exiting said susceptor tube; and means responsive to signals generated by said temperature sensing devices for controlling said variable speed motor to control the residence time, and thereby exit temperature, of material being conveyed through said susceptor tube. ### Claim 9 (depends on 1) The system of claim 1, further comprising: a plurality of temperature sensing devices for sensing the temperature of said susceptor tube and of material and contaminated vapors exiting said susceptor tube; and means responsive to signals generated by said temperature sensing devices for controlling the amount of current supplied by said at least one power supply to said at least one induction coil to thereby control the temperature to which said susceptor tube, and thereby material contained in said susceptor tube, is heated by said induction coil. ### Claim 10 (depends on 9) The system of claim 9, further comprising: a conveyor disposed in said susceptor tube for conveying material to be heated therein through said susceptor tube; and a variable speed motor for driving said conveyor, said variable speed motor being controlled by said means responsive to signals generated by said temperature sensing devices to control the residence time, and thereby further control the exit temperature of material being conveyed through said susceptor tube. ### Claim 11 (depends on 1) The system of claim 1, further comprising: a second induction coil surrounding said susceptor tube for heating said tube to a temperature sufficient to completely desorb material contained in said susceptor tube; and a second power supply for supplying current to said second induction coil to heat said susceptor tube. ### Claim 12 (depends on 1) The system of claim 1, wherein said means for charging material to be decontaminated into said susceptor tube comprises: a material charging tube attached to an entrance end of said susceptor tube; and a charging ram disposed in said charging tube for pushing material contained in said charging tube into said susceptor tube. ### Claim 13 (depends on 1) The system of claim 1, further comprising: means for treating removed vaporized contaminants from said susceptor tube to remove condensible liquids therefrom. ### Claim 14 A method for thermal desorption of contaminated materials comprising the steps of: providing a metal susceptor tube having a melting temperature higher than approximately 2300.degree. F., and an electrical resistance of greater than approximately 100 .mu.ohm-cm at 1800.degree. F.; charging contaminated material to be treated into said metal susceptor tube; supplying current to an induction coil surrounding said susceptor tube for heating said tube to a temperature sufficient to completely desorb the material contained therein; maintaining an inert atmosphere in said susceptor tube during heating of said material therein; removing from said susceptor tube, vaporized contaminants that are released from the material when it is heated; and removing desorbed material from said susceptor tube after it has been heated therein. ### Claim 15 (depends on 14) The method of claim 14, wherein said step of providing said metal susceptor tube further comprises providing a metal susceptor tube formed from a metal having a thermal conductivity of greater than or equal to approximately 195 BTU-in/ft.sup.2 -hr-.degree.F. at 1800.degree. F. ### Claim 16 (depends on 15) The method of claim 15, wherein said step of providing said metal susceptor tube further comprises providing a metal susceptor tube formed from a nickel based alloy. ### Claim 17 (depends on 14) The method of claim 14, further comprising the steps of: sensing the temperature of said susceptor tube at one or more locations thereon; sensing the temperature of a vapor stream exiting said susceptor tube; sensing the temperature of desorbed material exiting said susceptor tube; and controlling the amount of current supplied to said induction coil in response to said sensed temperatures. ### Claim 18 (depends on 17) The method of claim 17, further comprising the steps of: providing a conveyor in said susceptor tube for conveying material to be heated therein through said susceptor tube; providing a variable speed motor for driving said conveyor; and controlling the speed of said variable speed motor in response to said sensed temperatures to control the residence time, and thereby exit temperature, of material being conveyed through said susceptor tube. ### Claim 19 (depends on 18) The method of claim 18, wherein said step of heating said susceptor tube further comprises heating said susceptor tube to a temperature of approximately 1800.degree. F. ### Claim 20 (depends on 14) The method of claim 14, wherein said step of heating said susceptor tube further comprises heating said susceptor tube to a temperature sufficient to heat material contained in susceptor tube to approximately 800.degree.-1200.degree. F.