# US 5,710,301 A · Organosilicon compounds

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- Number: US 5,710,301 A
- Document ID: US5710301A
- Status: Granted
- Kind: A
- Application number: 08/198,787
- Filed: 1994-02-18
- Granted: 1998-01-20
- Earliest claimed: 1993-02-23
- Inventors: Michiya Fujiki
- Web page: https://patentgrep.com/patent/US5710301A

## CPC

- C07F 7/0803: {Compounds with Si-C or Si-Si linkages}
- B82Y 10/00: Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic
- B82Y 30/00: Nanotechnology for materials or surface science, e.g. nanocomposites
- C07F 7/12: Organo silicon halides
- C08G 77/60: in which all the silicon atoms are connected by linkages other than oxygen atoms
- C07F: ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM (metal-containing porphyrins C07D487/22)
- B82Y: SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- C08G: MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS

## Abstract

The present invention provides an oganosilicon compound possessing a .beta.-branched alkyl group or a .beta.-branched aralkyl group represented by Formula (I): ##STR1## wherein R.sup.1 represents methyl group or ethyl group; R.sup.2 represents C1-C18 alkyl group or aryl group. The present invention relates to optically active organosilicon compounds for use as a new type of enantio-recognitive material, and organosilicons which can be anticipated for use as a high polymer standard material in one-dimensional semiconductor quantum wire structures.

## Claims

### Claim 1

An organosilicon compound possessing a .beta.-branched alkyl group and represented by Formula (II): ##STR18## wherein R.sup.1 represents a methyl group or an ethyl group; R.sup.2 represents a C1-C18 alkyl group; R.sup.3, R.sup.4, and R.sup.5, each independently represent Si, Cl, an alkyl group, an aryl group, or an aralkyl group, with the exception of those compounds in which, at the same time:
(a) R.sup.1 and R.sup.2 each represent a methyl group, and R.sup.3, R.sup.4, and R.sup.5 each independently represent Cl;
(b) one of R.sup.1 and R.sup.2 represents a methyl group and the other represents an ethyl group, and two of R.sup.3, R.sup.4, and R.sup.5 represent Cl and the third represents a methyl group; and
(c) R.sup.1 and R.sup.2 each represent a methyl group, and two of R.sup.3, R.sup.4, and R.sup.5 represent Cl and the third represents a methyl group.

### Claim 2 (depends on 1)

An organosilicon compound as recited in claim 1, which is optically active, and wherein the .beta.-branched alkyl group is chiral.

### Claim 3 (depends on 2)

An organosilicon compound as recited in claim 2, wherein R.sup.1 is a methyl group; R.sup.2 is an ethyl group; R.sup.3 represents an alkyl group, an aryl group, or an aralkyl group; R.sup.4 and R.sup.5 each represent Cl.

### Claim 4 (depends on 2)

An organosilicon compound as recited in claim 2, wherein R.sup.1 is a methyl group; R.sup.2 is an ethyl group; R.sup.3, R.sup.4, and R.sup.5 each represent Cl.

### Claim 5 (depends on 1)

An organosilicon compound as recited in claim 1, which is not optically active, wherein the .beta.-branched alkyl group is achiral, and wherein both R.sup.1 and R.sup.2 represent a methyl group or an ethyl group; R.sup.3 represents an alkyl group, an aryl group, or an aralkyl group; and R.sup.4 and R.sup.5 each represent Cl.

### Claim 6

An organosilicon compound possessing a .beta.-branched alkyl group and represented by Formula (II): ##STR19## wherein R.sup.1 represents a methyl group or an ethyl group; R.sup.2 represents a C1-C18 alkyl group; R.sup.3, R.sup.4, and R.sup.5, each independently represent Si, Cl, an alkyl group, an aryl group, or an aralkyl group, and further wherein said organosilicon compound is an organopolysilane.

### Claim 7 (depends on 6)

An organopolysilane as recited in claim 6, said organopolysilane being derived from an optically active dichlorosilane represented by formula (II) wherein the .beta.-branched alkyl is chiral, and having the Formula (III): ##STR20## wherein R.sup.1 is a methyl group; R.sup.2 is an ethyl group; R.sup.3 represents an alkyl group, an aryl group, or an aralkyl group; and n is an integer of 10 or more.

### Claim 8 (depends on 6)

An organopolysilane as recited in claim 6, said organopolysilane being derived from an optically active trichlorosilane represented by formula (II) wherein the .beta.-branched alkyl group is chiral, and having the Formula (IV): ##STR21## wherein R.sup.1 is a methyl group; R.sup.2 is an ethyl group; and n is an integer of 10 or more.

### Claim 9 (depends on 6)

An organopolysilane as recited in claim 6, said organopolysilane being derived from an optically inactive dichlorosilane represented by formula (II) wherein the .beta.-branched alkyl group is achiral, and having the Formula (V): ##STR22## wherein R.sup.1 is a methyl group; R.sup.2 is an ethyl group; R.sup.3 represents Cl; and n is an integer of 10 or more.

### Claim 10 (depends on 6)

An organosilicon compound as recited in claim 6, which is an optically active polysilane copolymer.

### Claim 11 (depends on 10)

An optically active polysilane copolymer as recited in claim 10, said optically active polysilane copolymer being derived from an optically active silane compound of formula (II), wherein the .beta.-branched alkyl group is chiral, and an optically inactive silane compound of formula (II), wherein the .beta.-branched alkyl group is achiral, and having the Formula (VI): ##STR23## wherein R.sup.1 represents a methyl group or an ethyl group; R.sup.2 represents a C1-C18 alkyl group; and R.sup.3 represents Si, Cl, an alkyl group, an aryl group, or an aralkyl group; R.sup.6 and R.sup.7 each independently represent an alkyl group, an aryl group, or an aralkyl group; and 0.01<m<1.