# US 5,710,218 A · Ethylene-propylene-diene rubber, elastomer composition and vulcanized rubber thereof > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 5,710,218 A - Document ID: US5710218A - Status: Granted - Kind: A - Application number: 08/430,259 - Filed: 1995-04-28 - Granted: 1998-01-20 - Earliest claimed: 1989-10-05 - Assignees: Mitsui Petrochemical Industries, Ltd. - Inventors: Hidenari Nakahama; Takashi Mishima - Web page: https://patentgrep.com/patent/US5710218A ## CPC - B60C 1/0016: {Compositions of the tread} - B60C 1/0025: {Compositions of the sidewalls} - C08J 3/215: at least one additive being also premixed with a liquid phase - C08K 3/06: Sulfur - C08L 23/16: Ethylene-propylene or ethylene-propylene-diene copolymers - C08J 2323/16: Ethene-propene or ethene-propene-diene copolymers - C08L 2205/02: containing two or more polymers of the same C08L -group - C08L 2205/025: containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure - B60C: VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES - C08J: WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H (working, e.g. shaping, of plastics B29) - C08K: Use of inorganic or non-macromolecular organic substances as compounding ingredients (paints, inks, varnishes, dyes, polishes, adhesives C09) - C08L: COMPOSITIONS OF MACROMOLECULAR COMPOUNDS (compositions based on polymerisable monomers C08F, C08G; artificial filaments or fibres D01F; textile treating compositions D06) ## Abstract The invention provides ethylene-propylene-diene rubbers capable of imparting excellent heat resistance, weather resistance and dynamic fatigue resistance to vulcanized rubbers made therefrom. The ethylene-propylene-diene rubbers have sulfur dispersed therein at a temperature of 90.degree. to 160.degree. C. prior to the addition of vulcanization accelerators or other rubber additives. The ethylene-propylene-diene rubbers contain (A) 90 to 40% by weight of a high-molecular weight ethylene-propylene-diene copolymer rubber having an ethylene content of 60 to 82 mol %, an intrinsic viscosity (.eta.) of 3.0 to 5.0 dl/g as measured at 135.degree. C. in decalin and an iodine value of 8 to 35, (B) 10 to 60% by weight of a low-molecular-weight ethylene-propylene-diene copolymer rubber having an ethylene content of 60 to 82 mol %, an intrinsic viscosity (.eta.) of 0.15 to 0.8 dl/g as measured at 135.degree. C. in decalin and an iodine value of 8 to 35, and (C) sulfur in an amount of 0.1 to 5 parts by weight based on 100 parts by weight of the rubber dispersed therein at a temperature of 90.degree. to 160.degree. C. prior to the addition of a vulcanization accelerator or other rubber additive. The vulcanized rubbers are particularly suitable for use as automobile components which require dynamic fatigue resistance such as muffler hangers, belts, rubber vibration insulators, engine mounts, tire treads for pneumatic tires, sidewalls for pneumatic tires and white sidewalls. ## Claims ### Claim 1 An unvulcanized vulcanizable rubber mixture which consists essentially of (A) 90% to 40% by weight of a high-molecular-weight ethylene-propylene-diene rubber having an ethylene content of 60 to 82 mol %, an intrinsic viscosity (.eta.) of 3.0 to 5.0 dl/g as measured at 135.degree. C. in decalin and an iodine value of 8 to 35, (B) 10 to 60% by weight of a low-molecular-weight ethylene-propylene-diene rubber having an ethylene content of 60 to 82 mol %, an intrinsic viscosity (.eta.) of 0.15 to 0.8 dl/g as measured at 135.degree. C. in decalin and an iodine value of 8 to 35, and (C) sulfur, in an amount of 0.3 to 3 parts by weight based on 100 parts be weight of said ethylene-propylene-diene rubber, wherein the sulfur is uniformly dispersed therein at a temperature of 90.degree. to 160.degree. C., prior to the addition of a vulcanization accelerator, wherein the diene component of said rubber is a non-conjugated diene and said rubber mixture has a Mooney viscosity ML.sub.1+4 (100.degree. C.) of 60 to 120 and .omega..sub.r =50 to 150. ### Claim 2 A vulcanized rubber obtained by vulcanizing a vulcanizable elastomer composition comprising an unvulcanized vulcanizable rubber mixture which mixture consists essentially of (A) 90 to 40% by weight of a high-molecular-weight ethylene-propylene-diene rubber having an ethylene content of 60 to 82 mol %, an intrinsic viscosity ( ) of 3.0 to 5.0 dl/g as measured at 135.degree. C. in decalin and an iodine value of 8 to 35, (B) 10 to 60% by weight of a low-molecular-weight ethylene-propylene-diene rubber having an ethylene content of 60 to 82 mol %, an intrinsic viscosity ( ) of 0.15 to 0.8 dl/g as measured at 135.degree. C. in decalin and an iodine value of 8 to 35, and (C) sulfur, in an amount of 0.1 to 3 parts by weight based on 100 parts by weight of said ethylene-propylene-diene rubber, wherein the sulfur is uniformly dispersed therein at a temperature of 90.degree. to 160.degree. C., prior to the addition of a vulcanization accelerator, and (D) a vulcanization accelerator, wherein the ethylene-propylene-diene rubber has a Mooney viscosity of ML.sub.1+4 (100.degree. C.) of 60 to 120. ### Claim 3 (depends on 2) The vulcanized rubber of claim 2 wherein in the ethylene-propylene-diene rubber mixture .omega..sub.r =50 to 150. ### Claim 4 A process for preparing a vulcanized rubber which comprises the successive steps of: (a) uniformly dispersing sulfur at a temperature of 90.degree.-160.degree. C. in an ethylene-propylene-diene rubber, in an amount of 0.1 to 5.0 parts by weight of sulfur based on 100 parts by weight of the rubber, which is a mixture of (A) 90-40% by weight of a high-molecular-weight ethylene-propylene-diene rubber having an ethylene content of 60 to 80 mol %, an intrinsic viscosity (.eta.) of 3.0 to 5.0 dl/g as measured at 135.degree. C. in decalin and an iodine value of 8 to 35, and (B) 10 to 60% by weight of a low-molecular-weight ethylene-propylene-diene rubber having an ethylene content of 60 to 82 mol %, an intrinsic viscosity (.eta.) of 0.15 to 0.8 dl/g as measured at 135.degree. C. in decalin and an iodine value of 8 to 35, wherein the sulfur is dispersed prior to the addition of an accelerator, to obtain an unvulcanized vulcanizable rubber having a Mooney viscosity ML.sub.1+4 (100.degree. C.) of 60 to 120, (b) adding an accelerator to the sulfur dispersed mixture to produce a vulcanizable elastomer composition, and (c) vulcanizing the vulcanizable elastomer composition to obtain vulcanized rubber. ### Claim 5 (depends on 4) The process for preparing a vulcanized rubber of claim 4, wherein the ethylene-propylene-diene rubber mixture .omega..sub.r =50 to 150. ### Claim 6 (depends on 4) The process for preparing a vulcanized rubber of claim 4 wherein the sulfur is dispersed in the ethylene-propylene-diene rubber at a temperature of 110.degree. to 150.degree. C. ### Claim 7 (depends on 2) A vulcanized rubber as claimed in claim 2 wherein the vulcanized rubber has a Monsanto Fatigue Endurance Test value of at least 400,000. ### Claim 8 (depends on 2) A vulcanized rubber as claimed in claim 2 wherein the vulcanized rubber has a Monsanto Fatigue Endurance Test value of at least 1,000,000. ### Claim 9 An unvulcanized vulcanizable rubber mixture which consists essentially of (A) 90 to 40% by weight of a high-molecular-weight ethylene-propylene-diene rubber having an ethylene content of 60 to 82 mol %, an intrinsic viscosity (.eta.) of 3.0 to 5.0 dl/g as measured at 135.degree. C. in decalin and an iodine value of 8 to 35, (B) 10 to 60% by weight of a low-molecular-weight ethylene-propylene-diene rubber having an ethylene content of 60 to 82 mol %, an intrinsic viscosity (.eta.) of 0.15 to 0.8 dl/g as measured at 135.degree. C. in decalin and an iodine value of 8 to 35, and (C) sulfur, in an amount of 0.1 to 3 parts by weight based on 100 parts by weight of said ethylene-propylene-diene rubber, wherein the sulfur is uniformly dispersed therein by mixing a solution of sulfur with a solution of ethylene-propylene-diene rubber, followed by removing the solvent, prior to the addition of a vulcanization accelerator, wherein said rubber mixture has a Mooney viscosity ML.sub.1+4 (100.degree.) of 60 to 120. ### Claim 10 (depends on 9) The vulcanizable rubber mixture of claim 9, wherein .omega..sub.r =50 to 150. ### Claim 11 A vulcanized rubber obtained by vulcanizing a vulcanizable elastomer composition comprising an ethylene-propylene-diene rubber mixture which consists essentially of (A) 90 to 40% by weight of a high-molecular weight ethylene-propylene-diene rubber having an ethylene content of 60 to 82 mol %, an intrinsic viscosity ( ) of 3.0 to 5.0 dl/g as measured at 135.degree. C. in decalin and an iodine value of 8 to 35, (B) 10 to 60% by weight of a low-molecular-weight ethylene-propylene-diene rubber having an ethylene content of 60 to 82 mol %, an intrinsic viscosity ( ) of 0.15 to 0.8 dl/g as measured at 135.degree. C. in decalin and an iodine value of 8 to 35, and (C) sulfur, in an amount of 0.1 to 3 parts by weight based on 100 parts by weight of said ethylene-propylene-diene rubber, wherein the sulfur is uniformly dispersed therein by mixing a solution of sulfur with a solution of ethylene-propylene-diene rubber, followed by removing the solvent, prior to the addition of a vulcanization accelerator, and (D) a vulcanization accelerator, wherein the ethylene-propylene-diene rubber has a Mooney viscosity ML.sub.1+4 (100.degree. C.) of 60 to 120. ### Claim 12 (depends on 11) The vulcanized rubber of claim 11, wherein in the ethylene-propylene-diene rubber mixture .omega..sub.r =50 to 150. ### Claim 13 A process for preparing a vulcanized rubber which comprises the successive steps of: (a) uniformly dispersing sulfur in an ethylene-propylene-diene rubber by mixing a solution of the sulfur with a solution of the ethylene-propylene-diene rubber at a temperature of 90.degree. to 160.degree. C., in an amount of 0.1 to 3.0 parts by weight of sulfur based on 100 parts by weight of the rubber, prior to the addition of a vulcanization accelerator to obtain a vulcanizable elastomer composition, (b) removing the solvent, (c) adding a vulcanization accelerator, and (d) vulcanizing the vulcanizable elastomer composition to obtain the vulcanized rubber, wherein said ethylene-propylene-diene rubber is a mixture of (A) 90 to 40% by weight of a high-molecular-weight ethylene-propylene-diene rubber having an ethylene content of 60 to 82 mol %, an intrinsic viscosity (.eta.) of 3.0 to 5.0 dl/g as measured at 135.degree. C. in decalin and an iodine value of 8 to 35, (B) 10 to 60% by weight of a low-molecular-weight ethylene-propylene-diene rubber having an ethylene content of 60 to 82 mol %, an intrinsic viscosity (.eta.) of 0.15 to 0.8 dl/g as measured at 135.degree. C. in decalin and an iodine value of 8 to 35, wherein the ethylene-propylene-diene rubber has a Mooney viscosity ML.sub.1+4 (100.degree. C.) of 60 to 120. ### Claim 14 (depends on 13) The process for preparing a vulcanized rubber of claim 13, wherein in the ethylene-propylene-diene mixture .omega..sub.r =50 to 150. ### Claim 15 (depends on 2) The vulcanized rubber of claim 2, wherein the diene component of the ethylene-propylene-diene rubber is a cyclic non-conjugated diene which is a member selected from the group consisting of ethylidenenorbornene, norbornadiene, methylnorbornene, dicyclopentadiene, 2-methylnorbornadiene and 5-vinyl-2-norbornene. ### Claim 16 (depends on 4) The process of claim 4, wherein the diene component of the ethylene-propylene-diene rubber is a cyclic non-conjugated diene which is a member selected from the group consisting of ethylidenenorbornene, norbornadiene, methylnorbornene, dicyclopentadiene, 2-methylnorbornadiene and 5-vinyl-2-norbornene.