# US 5,708,502 A · Random access charge transfer devices for multi-element atomic absorption spectrometry and temporal shifting > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 5,708,502 A - Document ID: US5708502A - Status: Granted - Kind: A - Application number: 08/609,777 - Filed: 1996-03-01 - Granted: 1998-01-13 - Earliest claimed: 1996-03-01 - Assignees: Thermo Jarrell Ash Corporation - Inventors: M. Bonner Denton; J. Bruce True - Web page: https://patentgrep.com/patent/US5708502A ## CPC - G01J 3/42: Absorption spectrometry; Double beam spectrometry; Flicker spectrometry; Reflection spectrometry (beam switching arrangements G01J3/08) - G01J 3/2803: {using photoelectric array detector} - G01J: MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY (light sources F21, H01J, H01K, H05B; investigating properties of materials by optical means G01N) ## Abstract A simultaneous multi-element atomic absorption spectrometry system includes a light source, a furnace, a spectrometer, and a random access charge transfer device. The furnace creates vapors of a sample contained within the furnace. The light source passes a light beam through the furnace so that wavelengths of the light beam corresponding to spectral lines of multiple elements contained in the vapors are absorbed by the vapors. The spectrometer receives the light beam after the light beam has passed through the furnace, and disperses the light beam into a spectrum. The random access charge transfer device receives the light beam after the light beam has passed through the spectrometer, integrates and stores charge corresponding to the intensity of the light beam, and randomly accesses for readout subarrays of the random access charge transfer device corresponding to spectral lines of the multiple elements. The spectrometry system also includes an optical apparatus that receives the light beam and shifts the light beam between a first and a second position. ## Claims ### Claim 1 A simultaneous multi-element atomic absorption spectrometry system, comprising: a light source; a furnace for creating vapors of a sample contained within said furnace, said light source being arranged to pass a light beam through said furnace so that wavelengths of said light beam corresponding to spectral lines of multiple elements contained in said vapors are absorbed by said vapors; a spectrometer arranged to receive said light beam after said light beam has passed through said furnace, and to disperse said light beam into a spectrum; a random access charge transfer device arranged to receive said light beam after said light beam has passed through said spectrometer, to integrate and store charge corresponding to the intensity of said light beam, and to randomly access for readout subarrays of said random access charge transfer device corresponding to spectral lines of said multiple elements; and an optical apparatus configured to receive said light beam and to shift said light beam between a first and a second position, said light beam forming a first image on said random access charge transfer device corresponding to said first position of said light beam and a second image on said random access charge transfer device corresponding to said second position of said light beam, said second image being displaced with respect to said first image; and a controller configured, while said light beam is in said first position, to cause charge to be integrated and stored within a subarray of said random access charge transfer device corresponding to a portion of said first image that is a spectral line of one of said multiple elements, and, while said light beam is in said second position, to cause charge to be integrated and stored within another subarray of said random access charge transfer device corresponding to a portion of said second image that is also said spectral line of said one of said multiple elements, said controller further being configured to cause stored charge representing said portion of said first image and said portion of said second image to be read from said random access charge transfer device. ### Claim 2 (depends on 1) A system in accordance with claim 1, wherein said controller is configured, while said light beam is in said first position, to cause stored charge representing at least said portion of said second image to be read and simultaneously to cause charge within said random access charge transfer device representing at least said portion of said first image to be integrated and stored, and, while said light beam is in said second position, to cause stored charge representing at least said portion of said first image to be read from said random access charge transfer device and simultaneously to cause charge within said random access charge transfer device representing at least said portion of said second image to be integrated and stored. ### Claim 3 (depends on 1) A system in accordance with claim 1, wherein said random access charge transfer device is further configured to collectively read pixels within said subarrays simultaneously. ### Claim 4 (depends on 1) A system in accordance with claim 1, wherein said random access charge transfer device is further configured to read out said subarrays non-destructively a plurality of times. ### Claim 5 (depends on 1) A system in accordance with claim 1, wherein said random access charge transfer device is further configured to monitor charge stored in each of said subarrays and to erase said charge stored in any one of said subarrays when said one of said subarrays is near full well capacity. ### Claim 6 (depends on 1) A system in accordance with claim 1, wherein said furnace comprises a graphite furnace. ### Claim 7 (depends on 1) A system in accordance with claim 1, wherein said random access charge transfer device comprises a charge injection device. ### Claim 8 A simultaneous multi-element atomic absorption spectrometry system, comprising: a light source; a furnace for creating vapors of a sample contained within said furnace, said light source being arranged to pass a light beam through said furnace so that wavelengths of said light beam corresponding to spectral lines of multiple elements contained in said vapors are absorbed by said vapors; a spectrometer arranged to receive said light beam after said light beam has passed through said furnace, and to disperse said light beam into a spectrum; a random access charge transfer device arranged to receive said light beam after said light beam has passed through said spectrometer, to integrate and store charge corresponding to the intensity of said light beam, and to randomly access for readout subarrays of said random access charge transfer device corresponding to spectral lines of said multiple elements; and an optical apparatus configured to receive said light beam and to shift said light beam between a first and a second position, said light beam forming a first image on said random access charge transfer device corresponding to said first position of said light beam and a second image on said random access charge transfer device corresponding to skid second position of said light beam, said second image being displaced with respect to said first image; and a controller configured, while said light beam is in said first position, to cause charge to be integrated and stored within said random access charge transfer device representing at least a portion of said first image and simultaneously to cause stored charge representing at least a portion of said second image to be read from said random access charge transfer device, and, while said light beam is in said second position, to cause charge to be integrated and stored within said random access charge transfer device representing at least a portion of said second image and simultaneously to cause stored charge representing at least a portion of said first image to be read from said random access charge transfer device; wherein: said spectrometer disperses said light beam into a spectrum comprising a plurality of orders separated by spaces; said first and second images each comprise a plurality of orders of said spectrum; and said second image is displaced with respect to said first image such that the orders of said second image are interspaced between the orders of said first image. ### Claim 9 A method of operating a multi-element atomic absorption spectrometry system, comprising the steps of: producing a light beam from a light source; passing said light beam through a furnace that creates vapors of a sample contained within said furnace so that wavelengths of said light beam corresponding to spectral lines of multiple elements contained in said vapors are absorbed by said vapors; passing said light beam through a spectrometer, after said light beam has passed through said furnace, that disperses said light beam into a spectrum; projecting said light beam dispersed into said spectrum onto a random access charge transfer device; shifting said light beam between a first and a second position, said light beam forming a first image on said random access charge transfer device corresponding to said first position of said light beam and a second image on said random access charge transfer device corresponding to said second position of said light beam, said second image being displaced with respect to said first image; while said light beam is in said first position, integrating and store charge within a subarray of said random access charge transfer device corresponding to a portion of said first image that is a spectral line of one of said multiple elements; while said light beam is in said second position, integrating and storing charge within another subarray of said random access charge transfer device corresponding to a portion of said second image that is also said spectral line of said one of said multiple elements; and randomly accessing for readout said subarrays of said random access charge transfer device corresponding to said spectral line of said one of said multiple elements. ### Claim 10 (depends on 9) A method in accordance with claim 9, further comprising the steps of: while said light beam is in said first position, reading stored charge representing at least said portion of said second image and simultaneously integrating and storing charge within said random access charge transfer device representing at least said portion of said first image; and while said light beam is in said second position, reading from said random access charge transfer device stored charge representing at least said portion of said first image and simultaneously integrating and storing charge within said random access charge transfer device representing at least said portion of said second image. ### Claim 11 (depends on 9) A system in accordance with claim 9, further comprising the step of collectively reading pixels within said subarrays simultaneously. ### Claim 12 (depends on 9) A system in accordance with claim 9, further comprising the step of reading out said subarrays nondestructively a plurality of times. ### Claim 13 (depends on 9) A system in accordance with claim 9, further comprising the steps of monitoring charge stored in each of said subarrays and erasing said charge stored in any one of said subarrays when said one of said subarrays is near full well capacity. ### Claim 14 A method of operating a multi-element atomic absorption spectrometry system, comprising the steps of: producing a light beam from a light source; passing said light beam through a furnace that creates vapors of a sample contained within said furnace so that wavelengths of said light beam corresponding to spectral lines of multiple elements contained in said vapors are absorbed by said vapors; passing said light beam through a spectrometer, after said light beam has passed through said furnace, that disperses said light beam into a spectrum; projecting said light beam dispersed into said spectrum onto a random access charge transfer device; shifting said light beam between a first and a second position, said light beam forming a first image on said random access charge transfer device corresponding to said first position of said light beam and a second image on said random access charge transfer device corresponding to said second position of said light beam, said second image being displaced with respect to said first image; while said light beam is in said first position, integrating and store charge within said random access charge transfer device representing at least a portion of said first image while simultaneously randomly accessing for readout subarrays of said random access charge transfer device corresponding to spectral lines of said multiple elements including at least a portion of said second image; while said light beam is in said second position, integrating and storing charge within said random access charge transfer device representing at least a portion of said second image while simultaneously randomly accessing for readout subarrays of said random access charge transfer device corresponding to spectral lines of said multiple elements including at least a portion of said first image; wherein: said step of passing said light beam through said spectrometer comprises dispersing said light beam into a spectrum comprising a plurality of orders separated by spaces; said first and second images each comprise a plurality of orders of said spectrum; and said second image is displaced with respect to said first image such that the orders of said second image are interspaced between the orders of said first image. ### Claim 15 A system for analyzing an image, comprising: an optical apparatus configured to receive a light beam and to shift said light beam between a first and a second position; a random access charge transfer device arranged to receive said light beam from said optical apparatus, said light beam forming a first image on said random access charge transfer device corresponding to said first position of said light beam and a second image on said random access charge transfer device corresponding to said second position of said light beam, said second image being displaced with respect to said first image; and a controller configured, while said light beam is in said first position, to cause charge to be integrated and stored within said random access charge transfer device representing at least a portion of said first image and simultaneously to cause stored charge representing at least said portion of said second image to be read from said random access charge transfer device, and, while said light beam is in said second position, to cause charge to be integrated and stored within said random access charge transfer device representing at least a portion of said second image and simultaneously to cause stored charge representing at least said portion of said first image to be read from said random access charge transfer device. ### Claim 16 (depends on 15) A system in accordance with claim 15, wherein said second, image is identical to said-first image. ### Claim 17 (depends on 15) A system in accordance with claim 15, wherein said portion of said second image is identical to said portion of said first image. ### Claim 18 A method of analyzing an image, comprising the steps of: providing a light beam; projecting said light beam onto an optical apparatus that causes said light beam to be projected in a first position onto a random access charge transfer device to form a first image, while integrating and storing charge within said random access charge transfer device representing at least a portion of said first image; and continuing to project said light beam onto said optical apparatus while said optical apparatus shifts said light beam to project said light beam in a second position onto said random access charge transfer device to form a second image, while integrating and storing charge within said random access charge transfer device representing at least a portion of said second image; said step of integrating and storing charge within said random access charge transfer device representing at least said portion of said first image being performed while stored charge representing at least said portion of said second image is simultaneously read from said random access charge transfer device; said step of integrating and storing charge within said random access charge transfer device representing at least said portion of said second image being performed while stored charge representing at least said portion of said first image is simultaneously read from said random access charge transfer device.