# US 5,708,363 A · Liquid conductivity measurement system using a variable-frequency AC voltage > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 5,708,363 A - Document ID: US5708363A - Status: Granted - Kind: A - Application number: 08/543,504 - Filed: 1995-10-16 - Granted: 1998-01-13 - Earliest claimed: 1995-10-16 - Assignees: Signet Scientific Company - Inventors: Ronald J. Yates; Martin M. Munzer; Frederic D. Hook - Web page: https://patentgrep.com/patent/US5708363A ## CPC - G01N 27/06: of a liquid (involving electrolysis G01N27/26) - G01R 27/22: Measuring resistance of fluids - G01N: INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES (measuring or testing apparatus or processes other than immunoassay, involving enzymes or microorganisms C12M, C12Q) - G01R: MEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES (indicating correct tuning of resonant circuits H03J3/12) ## Abstract A liquid conductivity measurement system is disclosed that accurately measures a liquid's conductivity over a range spanning at least several orders of magnitude using just a single sensor, but minimizing the adverse effects of capacitive and other non-linear factors on the conductivity measurement. The system includes a sensor having two spaced-apart electrodes immersed in the liquid and a drive signal source that applies to the sensor an ac electrical signal having a selected frequency and predetermined magnitude. A voltage detector monitors a sensor voltage signal across the sensor's two electrodes and produces a measurement of the liquid's conductivity. The drive signal source is configured to iteratively adjust the frequency of the ac electrical signal based on the sensor voltage signal, to optimize the liquid's conductivity measurement. ## Claims ### Claim 1 Apparatus for measuring the conductivity of a liquid, comprising: a sensor having two spaced-apart electrodes disposed in a contact with the liquid; a drive signal source that provides an ac electrical signal of a selected frequency across the two electrodes of the sensor; and a voltage detector that is coupled to the sensor and that monitors a sensor voltage signal across the two electrodes, the magnitude of the sensor voltage signal providing a measurement of the liquid's conductivity; wherein the drive signal source is configured to iteratively adjust the frequency of the ac electrical signal based on the sensor voltage signal, to optimize the measurement of the liquid's conductivity. ### Claim 2 (depends on 1) Apparatus for measuring a liquid's conductivity as defined in claim 1, wherein the drive signal source includes: a variable-frequency voltage generator that generates a sine-wave voltage signal having a predetermined ac voltage; and a source resistance coupled in series with the voltage generator, wherein the series combination of the voltage generator and the source resistance produces the predetermined ac electrical signal. ### Claim 3 (depends on 2) Apparatus for measuring a liquid's conductivity as defined in claim 2, wherein: the spaced-apart electrodes of the sensor define a cell constant; and the apparatus further includes a processor that determines a resistance through the sensor based on the ac voltage of the sine-wave voltage signal, the source resistance, and the sensor voltage signal, and that provides the measurement of conductivity based on the resistance through the sensor and the cell constant. ### Claim 4 (depends on 3) Apparatus for measuring a liquid's conductivity as defined in claim 3, wherein: the source resistance includes a plurality of source resistors having resistances that differ over at least two orders of magnitude; and the processor is configured to iteratively select from among the plurality of source resistors, based on the determined resistance through the sensor, such that the source resistance is within an order of magnitude of the sensor's resistance. ### Claim 5 (depends on 3) Apparatus for measuring a liquid's conductivity as defined in claim 3, wherein: the processor includes a lookup table that indicates a desired relationship between the frequency of the ac electrical signal and the value of the measured sensor resistance; and the processor, using the lookup table, selects a frequency based on the sensor's resistance and controls the drive signal source to operate at the selected frequency. ### Claim 6 (depends on 5) Apparatus for measuring a liquid's conductivity as defined in claim 5, wherein the processor uses linear interpolation to calculate the frequency for a resistance value lying between the resistance values contained in the lookup table. ### Claim 7 (depends on 2) Apparatus for measuring a liquid's conductivity as defined in claim 2, wherein the voltage generator is configured to adjust the selected frequency in frequency steps of less than 100 Hz. ### Claim 8 (depends on 2) Apparatus for measuring a liquid's conductivity as defined in claim 2, wherein the voltage generator is configured to adjust the selected frequency in frequency steps of less than 10 Hz. ### Claim 9 (depends on 2) Apparatus for measuring a liquid's conductivity as defined in claim 2, wherein the voltage generator is configured to adjust the selected frequency substantially continuously over a frequency range from 500 Hz to 50 KHz. ### Claim 10 (depends on 1) Apparatus for measuring a liquid's conductivity as defined in claim 1, and further comprising a temperature monitor, integrated within the sensor, to measure the sensor's temperature. ### Claim 11 (depends on 10) Apparatus for measuring a liquid's conductivity as defined in claim 10, and further comprising means for normalizing the conductivity reading to a 25.degree. C. temperature compensated conductivity reading. ### Claim 12 A method for measuring the conductivity of a liquid, comprising: providing a sensor having two spaced-apart electrodes that electrically contact the liquid; applying an ac drive signal to the electrodes of the sensor, the ac drive signal having a predetermined initial frequency; detecting the voltage across the sensor that results from the applied ac drive signal, such voltage constituting a measurement of the liquid's conductivity; adjusting the frequency of the ac drive signal to a frequency selected to provide an accurate measurement for the liquid's conductivity; applying the ac drive signal with the adjusted frequency to the sensor; and iteratively repeating the detecting, adjusting and applying steps. ### Claim 13 (depends on 12) A method as defined in claim 12, wherein: the ac drive signal used in the steps of applying is sinusoidal; and the steps of applying include connecting a source resistance in series with the sensor. ### Claim 14 (depends on 13) A method as defined in claim 13, wherein the step of adjusting includes selecting the value of the source resistance. ### Claim 15 (depends on 12) A method as defined in claim 12, wherein the step of adjusting includes selecting the frequency by reference to a lookup table that indicates a desired relationship between the frequency of the ac drive signal and the measurement of the liquid's conductivity. ### Claim 16 (depends on 15) A method as defined in claim 15, wherein the step of adjusting includes interpolating between discrete values included in the lookup table. ### Claim 17 (depends on 12) A method as defined in claim 12, wherein the step of adjusting includes adjusting the selected frequency in frequency steps of less than 100 Hz. ### Claim 18 (depends on 12) A method as defined in claim 12, wherein the step of adjusting includes adjusting the selected frequency in frequency steps of less than 10 Hz. ### Claim 19 (depends on 12) A method as defined in claim 12, wherein the step of adjusting includes adjusting the selected frequency substantially continuously over a frequency range from 500 Hz to 50 KHz. ### Claim 20 (depends on 12) A method as defined in claim 12, and further comprising normalizing the successive conductivity measurements to 25 degrees C.