# US 5,708,272 A · Apparatus for determining a parameter of a substance, especially a hydrocarbon

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- Number: US 5,708,272 A
- Document ID: US5708272A
- Status: Granted
- Kind: A
- Application number: 08/642,579
- Filed: 1996-05-03
- Granted: 1998-01-13
- Earliest claimed: 1996-05-03
- Assignees: Intevep, S.A.
- Inventors: Aaron Ranson; Pedro Felipe Tovar; Adriano Filadelfo Parisi
- Web page: https://patentgrep.com/patent/US5708272A

## CPC

- G01N 21/359: using near infrared light
- G01N 21/15: Preventing contamination of the components of the optical system or obstruction of the light path
- G01N 21/3577: for analysing liquids, e.g. polluted water
- G01N: INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES (measuring or testing apparatus or processes other than immunoassay, involving enzymes or microorganisms C12M, C12Q)

## Abstract

An apparatus for determining a parameter of substance includes a cell defining an inner space, an inlet associated with the cell for introducing a sample of the substance to the inner space, an outlet associated with the cell for removing the sample from the inner space, an optic couple for passing NIR radiation through the sample in the inner space along an optic path so as to provide an NIR spectrum indicative of a parameter of the sample, the optic couple defining the optic path, and structure for directing flow in the inner space, whereby vortices within the inner space are inhibited and the NIR spectrum is rapidly provided upon introduction of the sample to the inner space.

## Claims

### Claim 1

An apparatus for determining a parameter of substance, comprising:
a cell defining an inner space;
inlet means associated with said cell for introducing a sample of said substance to said inner space;
outlet means associated with said cell for removing said sample from said inner space;
optic means for passing NIR radiation through said sample in said inner space along an optic path so as to provide an NIR spectrum indicative of a parameter of said sample, said optic means defining said optic path; and
means for directing flow in said inner space, whereby vortices within said inner space are inhibited and said NIR spectrum is rapidly provided upon introduction of said sample to said inner space, said means for directing flow further comprises means for guiding bubbles from said sample into an upper area of said inner space above said optic path, and for guiding sediment from said sample to a lower area of said inner space below said optic path such that substantially all of the bubbles and sediment is diverted away from the optic path.

### Claim 2 (depends on 1)

An apparatus according to claim 1, further comprising analyzer means associated with said cell for analyzing said NIR spectrum so as to determine said parameter.

### Claim 3 (depends on 2)

An apparatus according to claim 2, wherein said analyzer means comprises a neural network trained to quantitatively correlate said NIR spectrum with said parameter.

### Claim 4 (depends on 1)

An apparatus according to claim 1, wherein said optic means comprises an optic source for initiating said NIR radiation along said path, and an optic receiver for receiving said NIR spectrum from said path.

### Claim 5 (depends on 4)

An apparatus according to claim 4, further comprising means associated with said cell for cleaning said optic source and said optic receiver.

### Claim 6 (depends on 5)

An apparatus according to claim 5, wherein said means for cleaning comprises means for exposing said optic source and said optic receiver to a cleaning material.

### Claim 7 (depends on 6)

An apparatus according to claim 6, wherein said means for exposing comprises a solvent inlet for introducing a solvent to said inner space, and a nitrogen inlet for introducing nitrogen to said inner space, whereby said optic source and said optic receiver can be sequentially exposed to said solvent for cleaning and to said nitrogen for drying.

### Claim 8 (depends on 1)

An apparatus according to claim 1, wherein said means for directing comprises at least one contoured member positioned within said inner space to direct flow of said sample in said inner space.

### Claim 9 (depends on 8)

An apparatus according to claim 8, wherein said at least one contoured member defines a first passage having a first axis angled generally upwardly with respect to said optic path, and a second passage having a second axis angled generally downwardly with respect to said optic path.

### Claim 10 (depends on 9)

An apparatus according to claim 9, wherein said cell defines an upper area above said optic path and a lower area below said optic path, and wherein said first passage leads to said upper area and said second passage leads to said lower area.

### Claim 11 (depends on 9)

An apparatus according to claim 9, wherein said optic path has a longitudinal axis and wherein said first axis and said second axis are arranged at angles (.alpha.) respectively with respect to said longitudinal axis of between about 30.degree. to about 60.degree..

### Claim 12 (depends on 11)

An apparatus according to claim 11, wherein said inlet means comprises means for introducing said sample in a flow direction at an angle (.beta.) with respect to said longitudinal axis of between about 45.degree. to about 65.degree..

### Claim 13 (depends on 1)

An apparatus according to claim 1, further comprising heat exchanger means associated with said cell and means for selectively directing said sample to said inlet means and said heat exchanger means.

### Claim 14

A system for obtaining a parameter of a substance, comprising:
a cell defining an inner space;
inlet means associated with said cell for introducing a sample of said substance to said inner space;
outlet means associated with said cell for removing said sample from said inner space;
optic means for passing NIR radiation through said sample in said inner space along an optic path so as to provide an NIR spectrum indicative of a parameter of said sample, said optic means defining said optic path;
means for directing flow in said inner space, whereby vortices within said inner space are inhibited, said means for directing flow further comprises means for guiding bubbles from said sample into an upper area of said inner space above said optic path, and for guiding sediment from said sample to a lower area of said inner space below said optic path such that substantially all of the bubbles and sediment is diverted away from the optic path; and
means for providing said sample of said substance to said inlet means.

### Claim 15 (depends on 14)

A system according to claim 14, wherein said means for providing comprises a source of said sample, and means for filtering said sample so as to substantially remove water and particulate matter from said sample.

### Claim 16 (depends on 15)

A system according to claim 15, wherein said means for providing further comprises conditioning means for providing said sample at a preselected temperature.

### Claim 17 (depends on 14)

A system according to claim 14, further comprising analyzer means associated with said cell for analyzing said NIR spectrum so as to determine said parameter.

### Claim 18 (depends on 17)

An apparatus according to claim 17, wherein said analyzer means comprises a neural network trained to quantitatively correlate said NIR spectrum with said parameter.

### Claim 19 (depends on 14)

A system according to claim 14, further comprising means for providing a cleaning material for cleaning said optic means, and means for selectively connecting said means for providing said sample and said means for providing said cleaning material to said inlet means.

### Claim 20 (depends on 19)

A system according to claim 19, wherein said means for selectively connecting has a first position wherein said means for providing said sample is connected to said inlet means, and a second position wherein said means for providing said cleaning material is connected to said inlet means and said sample is recycled to said means for providing said sample.

### Claim 21 (depends on 20)

A system according to claim 20, further comprising heat exchanger means associated with said cell, and wherein said sample is recycled through said heat exchanger means when said means for selectively connecting is in said second position.

### Claim 22

An apparatus for determining a parameter of substance, comprising:
a cell defining an inner space;
inlet means associated with said cell for introducing a sample of said substance to said inner space;
outlet means associated with said cell for removing said sample from said inner space;
optic means for passing NIR radiation through said sample in said inner space along an optic path so as to provide an NIR spectrum indicative of a parameter of said sample, said optic means defining said optic path;
means for directing flow in said inner space, whereby vortices within said inner space are inhibited and said NIR spectrum is rapidly provided upon introduction of said sample to said inner space; and
heat exchanger means associated with said cell and directing means for selectively directing said sample to said inlet means and said heat exchanger means.