# US 5,708,124 A · Process for the solid state polycondensation of polyester resins

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- Number: US 5,708,124 A
- Document ID: US5708124A
- Status: Granted
- Kind: A
- Application number: 08/568,636
- Filed: 1995-12-07
- Granted: 1998-01-13
- Earliest claimed: 1994-12-16
- Assignees: Sinco Engineering S.p.A.
- Inventors: Hussain Ali Kashif Al Ghatta; Dario Giordano
- Web page: https://patentgrep.com/patent/US5708124A

## CPC

- C08G 63/80: Solid-state polycondensation
- C08G: MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS

## Abstract

Process for the solid state polycondensation of polyester resins, where an inert gas is circulating in a moving bed of polymer at a temperature between 180.degree. and 230.degree. C., characterized by the fact that the ratio by weight between the gas rate of flow per hour and that one of the discharged polymer is lower than 0.6.

## Claims

### Claim 1

Continuous process for solid state polycondensation of aromatic polyester resins, comprising the steps of: feeding the resin through the top of a moving bed reactor and discharging the resin from the bottom; and circulating an inert gas counter or equicurrent with the resin, wherein the reactor has a temperature between 180.degree. C. and 220.degree. C., with resin average residence times long enough to obtain an increase of polymer intrinsic viscosity of at least 0.1 dl/g, and wherein a ratio R by weight between the gas rate of flow per hour and the rate of flow per hour of the polymer discharged from the reactor is lower than 0.6.

### Claim 2 (depends on 1)

Process according to claim 1, where the ratio R is (comprised) between 0.2 and 0.5.

### Claim 3 (depends on 1)

Process according to claim 1, where the temperature in the reactor is between approximately 190.degree. and 210.degree. C.

### Claim 4 (depends on 2)

Process according to claim 2, where the temperature in the reactor is between approximately 190.degree. and 210.degree. C.

### Claim 5 (depends on 1)

Process according to claim 1, where the inert gas is nitrogen.

### Claim 6 (depends on 2)

Process according to claim 2, where the inert gas is nitrogen.

### Claim 7 (depends on 3)

Process according to claim 3, where the inert gas is nitrogen.

### Claim 8 (depends on 5)

Process according to claim 5, where the nitrogen is circulating in equicurrent with the polymer.

### Claim 9 (depends on 1)

Process according to claim 1, where the polyester resin is polyethylene terephthalate or co-polyethylene terephthalate containing from 1 to 20% of isophthalic acid units.

### Claim 10 (depends on 2)

Process according to claim 2, where the polyester resin is polyethylene terephthalate or co-polyethylene terephthalate containing from 1 to 20% of isophthalic acid units.

### Claim 11 (depends on 3)

Process according to claim 3, where the polyester resin is polyethylene terephthalate or co-polyethylene terephthalate containing from 1 to 20% of isophthalic acid units.

### Claim 12 (depends on 5)

Process according to claim 5, where the polyester resin is polyethylene terephthalate or co-polyethylene terephthalate containing from 1 to 20% of isophthalic acid units.

### Claim 13 (depends on 8)

Process according to claim 8, where the polyester resin is polyethylene terephthalate or co-polyethylene terephthalate containing from 1 to 20% of isophthalic acid units.

### Claim 14 (depends on 1)

Process according to claim 1, further comprising the steps of submitting the gas to a purification process to remove organic impurities and then recycling the gas to the reactor.

### Claim 15 (depends on 2)

Process according to claim 2 further comprising the steps of submitting the gas to a purification process to remove organic impurities and then recycling the gas to the reactor.

### Claim 16 (depends on 3)

Process according to claim 3 further comprising the steps of submitting the gas to a purification process to remove organic impurities and then recycling the gas to the reactor.

### Claim 17 (depends on 5)

Process according to claim 5 further comprising the steps of submitting the gas to a purification process to remove organic impurities and then recycling the gas to the reactor.

### Claim 18 (depends on 8)

Process according to claim 8 further comprising the steps of submitting the gas to a purification process to remove organic impurities and then recycling the gas to the reactor.

### Claim 19 (depends on 9)

Process according to claim 9 further comprising the steps of submitting the gas to a purification process to remove organic impurities and then recycling the gas to the reactor.