# US 5,707,953 A · Fluidized bed coated amidoperoxyacid bleach composition

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- Number: US 5,707,953 A
- Document ID: US5707953A
- Status: Granted
- Kind: A
- Application number: 08/537,710
- Filed: 1996-01-26
- Granted: 1998-01-13
- Earliest claimed: 1993-04-19
- Assignees: Akzo Nobel N.V.
- Inventors: Cornelis Marinus Van't Land; Johannes Gerhardus Bernardus Bouwmeester; Cornelis Kooijman; Charles Frederik Hansfort Manuhutu; Jan Joseph Hubert Ploumen
- Web page: https://patentgrep.com/patent/US5707953A

## CPC

- C11D 17/0039: {Coated compositions or coated components in the compositions, (micro)capsules}
- C11D 3/3945: {Organic per-compounds (C11D3/3902 takes precedence)}
- C11D 11/0088: {the liquefied ingredients being sprayed or adsorbed onto solid particles}
- C11D: DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL

## Abstract

A coated bleach composition for laundering which contains from 1-97 weight percent of an amidoperoxyacid, and 0-98 weight percent of a hydratable amidoperoxyacid compatible material, less than 2.0 weight percent of water, and a coating of 2-30 weight percent of a water-soluble salt applied by spray coating on a fluidized bed, is disclosed. Also disclosed is a process for the coating of an amidoperoxyacid-containing bleach composition characterized by the steps of spraying, at a temperature below the decomposition temperature of the amidoperoxyacid, a sufficient amount of an atomized spray of an aqueous solution of a water-soluble salt onto a fluidized bed of bleach composition containing an amidoperoxyacid to provide 2-30 weight percent of the water-soluble salt to the composition, and drying the coated composition to a water content of less than 2.0 weight percent. The coating of the composition eliminates caking problems encountered with the uncoated composition.

## Claims

### Claim 1

A coated bleach composition for laundering having a reduced tendency to cake wherein the coated composition comprises:
(a) from 1-99 weight percent of an amidoperoxyacid represented by the formulas I-II: ##STR3## wherein R.sup.1 and R.sup.2 are alkyl(ene), aryl(ene) or alkaryl(ene) groups containing 1-14 carbon atoms, and R.sup.3 is hydrogen or an alkyl, aryl or an aralkyl group containing 1 to 10 carbon atoms;
(b) 0-97 weight percent of an amidoperoxyacid compatible material;
(c) less than 2.0 weight percent of water; and a coating of 2-30 weight percent of a water-soluble salt which has been applied by spraying onto a fluidized bed of bleach composition.

### Claim 2 (depends on 1)

The coated bleach composition of claim 1 which further comprises 0.25-10 weight percent of a bleach stable surfactant selected from anionics, nonionics, ampholytics, zwitterionics or combination thereof.

### Claim 3 (depends on 1)

The coated bleach composition of claim 1 wherein the coating comprises 4-15 weight percent of the composition.

### Claim 4 (depends on 1)

The coated bleach composition of claim 1 wherein the water-soluble salt is a salt selected from sodium monobasic phosphate, sodium dibasic phosphate, sodium sulfate, magnesium sulfate, magnesium ammonium sulfate, aluminum magnesium nitrate, potassium magnesium sulfate, potassium aluminum sulfate, ammonium aluminum sulfate, potassium sulfate, sodium nitrate, sodium carbonate, sodium citrate, sodium tartrate, sodium acetate, sodium aluminum sulfate, or mixtures thereof.

### Claim 5 (depends on 1)

The coated bleach composition of claim 1 wherein the amidoperoxyacid is nonyl amido peroxy adipic acid and the water-soluble salt is sodium sulfate.

### Claim 6

A process for the coating of an amidoperoxyacid-containing bleach composition which comprises:
(a) spraying, at a bed temperature below the decomposition temperature of the amidoperoxyacid and above the adiabatic saturation temperature of the air/solution system, a sufficient amount of an atomized spray of an aqueous solution of a water-soluble salt onto a fluidized bed of bleach composition containing from 1-99 weight percent of an amidoperoxyacid represented by the formulas I-II: ##STR4## wherein R.sup.1 and R.sup.2 are alkyl(ene), aryl(ene) or alkaryl(ene) groups containing 1-14 carbon atoms, and R.sup.3 is hydrogen or an alkyl, aryl or an aralkyl group containing 1 to 10 carbon atoms; to provide 2-30 weight percent of water-soluble salt to the composition and
(b) drying the coated composition to a water content of less than 2.0 weight percent.

### Claim 7 (depends on 6)

The process of claim 6 wherein the aqueous solution of the water-soluble salt is not saturated.

### Claim 8 (depends on 6)

The process of claim 6 wherein the water-soluble salt is a hydratable salt, during the spraying step, the fluidized bed is maintained at a temperature at which the hydratable water-soluble salt in its solid form does not carry water of hydration.

### Claim 9 (depends on 6)

The process of claim 6 wherein 4-15 weight percent of water-soluble salt is provided to the composition in the spraying step.

### Claim 10 (depends on 6)

The process of claim 6 wherein a two-fluid spray nozzle is employed to spray the aqueous solution of water-soluble salt.

### Claim 11 (depends on 6)

The process of claim 6 wherein the water-soluble salt is sodium sulfate and the amidoperoxyacid is nonyl amido peroxy adipic acid.

### Claim 12 (depends on 6)

The process of claim 6 wherein the drying step is carried out using warm fluidizing air.