# US 5,707,949 A · Prevention of dye-bleeding and transfer during laundering

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- Number: US 5,707,949 A
- Document ID: US5707949A
- Status: Granted
- Kind: A
- Application number: 08/627,516
- Filed: 1996-04-04
- Granted: 1998-01-13
- Earliest claimed: 1996-04-04
- Assignees: E. I. Du Pont de Nemours and Company
- Inventors: Donald Douglas May; Robert Craig Buck
- Web page: https://patentgrep.com/patent/US5707949A

## CPC

- C11D 3/3703: {Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds}
- C11D 3/0021: {Dye-stain or dye-transfer inhibiting compositions}
- D06P 1/56: Condensation products or precondensation products prepared with aldehydes
- D06P 5/08: macromolecular
- C11D: DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- D06P: DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM

## Abstract

Adding to a laundry detergent a resole condensation polymer prepared by reacting bis(hydroxyphenyl)sulfone with formaldehyde in the presence of a base thereby preventing or suppressing dye-transfer and dye-bleeding during laundering of nylon, rayon, cotton, acetate, or wool fabrics is disclosed.

## Claims

### Claim 1

A composition which comprises (A) a laundry detergent and (B) a resole condensation polymer which had been prepared by reacting formaldehyde with bis(hydroxyphenyl)sulfone in the presence of a base comprising an inorganic compound having a pKa of 8.5 or higher, at a formaldehyde:bis(hydroxy-phenyl)sulfone molar ratio in the range between 0.6:1.0 and 4.0:1.0 and a base:bis(hydroxy-phenyl)sulfone molar ratio in the range between 0.1:1.0 and 3.5:1.0, the addition of said resole condensation polymer to said laundry detergent providing prevention or suppression of dye-transfer and dye-bleeding during laundering of nylon, rayon, cotton, acetate, and wool fabrics, said composition being water-soluble or water-dispersible, and when dissolved or dispersed in water provides an aqueous solution or aqueous dispersion having a pH of 6.0 to 10.0.

### Claim 2 (depends on 1)

The composition of claim 1 wherein said base is an alkali metal hydroxide, alkali metal carbonate, alkali metal bicarbonate, alkali metal borate, alkaline earth metal hydroxide, alkaline earth metal carbonate, alkaline earth metal borate or mixtures thereof.

### Claim 3 (depends on 2)

The composition of claim 2 wherein said formaldehyde:bis(hydroxy-phenyl)sulfone molar ratio is in the range between 0.6:1.0 and 1.1:1.0, and wherein said base:bis(hydroxyphenyl)-sulfone molar ratio is in the range between 0.2:1.0 and 1.0:1.0.

### Claim 4 (depends on 3)

The composition of claim 3, wherein said bis(hydroxyphenyl)sulfone consists essentially of 4,4'-sulfonyldiphenol.

### Claim 5 (depends on 4)

The composition of claim 4 wherein said alkali metal hydroxide is sodium hydroxide.

### Claim 6

In a process in which nylon, rayon, cotton, acetate, or wool fabrics are laundered at a pH of 6.0 to 10.0, the improvement comprising adding a water-soluble or water-dispersible resole condensation polymer to a laundry detergent, said resole condensation polymer having been prepared by reacting bis(hydroxyphenyl)sulfone with formaldehyde in the presence of a base comprising an inorganic compound having a pKa of 8.5 or higher, at a formaldehyde:bis(hydroxyphenyl)sulfone molar ratio in the range between 0.6:1.0 and 4.0:1.0 and a base:bis(hydroxy-phenyl)sulfone molar ratio in the range between 0.1:1.0 and 3.5:1.0, the addition of said resole condensation polymer to said laundry detergent preventing or suppressing dye-transfer and dye-bleeding during said laundering of nylon, rayon, cotton, acetate, polyester, or wool fabrics.

### Claim 7 (depends on 6)

The process of claim 6 wherein said base is an alkali metal hydroxide, alkali metal carbonate, alkali metal bicarbonate, alkali metal borate, alkaline earth metal hydroxide, alkaline earth metal carbonate, alkaline earth metal borate or mixtures thereof.

### Claim 8 (depends on 7)

The process of claim 7 wherein said formaldehyde:bis(hydroxyphenyl)sulfone molar ratio is in the range between 0.6:1.0 and 1.1:1.0, and wherein said base:bis(hydroxyphenyl)-sulfone molar ratio is in the range between 0.2:1.0 and 1.0:1.0.

### Claim 9 (depends on 8)

The process of claim 8, wherein said bis(hydroxy-phenyl)sulfone consists essentially of 4,4'-sulfonyldiphenol.

### Claim 10 (depends on 9)

The process of claim 9 wherein said base is sodium hydroxide.