# US 5,707,710 A · Composite sheet for artificial leather > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 5,707,710 A - Document ID: US5707710A - Status: Granted - Kind: A - Application number: 08/625,058 - Filed: 1996-03-29 - Granted: 1998-01-13 - Earliest claimed: 1996-03-29 - Assignees: E. I. Du Pont de Nemours and Company - Inventors: Dimitri Peter Zafiroglu - Web page: https://patentgrep.com/patent/US5707710A ## CPC - B32B 5/26: another layer {next to it} also being fibrous or filamentary {(relative arrangement of fibres or filaments of different layers B32B5/12)} - B32B 5/024: {Woven fabric} - B32B 5/026: {Knitted fabric} - B32B 5/06: characterised by a fibrous {or filamentary} layer {mechanically connected, e.g. by needling} to another layer, e.g. of fibres, of paper - B32B 38/08: Impregnating - D06N 3/0002: {characterised by the substrate} - D06N 3/0013: {using multilayer webs} - D06N 3/0022: {Glass fibres} - D06N 3/14: with polyurethanes - B32B 2260/021: Fibrous or filamentary layer - B32B 2260/046: Synthetic resin - B32B 2262/0261: Polyamide fibres - B32B 2262/0276: Polyester fibres - B32B 2262/062: Cellulose fibres, e.g. cotton - B32B 2451/00: Decorative or ornamental articles - Y10S 428/904: Artificial leather - Y10T 428/24438: Artificial wood or leather grain surface - Y10T 428/24446: Wrinkled, creased, crinkled or creped - Y10T 428/24521: with component conforming to contour of nonplanar surface - Y10T 428/24562: Interlaminar spaces - Y10T 428/24612: Composite web or sheet - Y10T 428/24992: Density or compression of components - Y10T 428/27: Web or sheet containing structurally defined element or component, the element or component having a specified weight per unit area [e.g., gms/sq cm, lbs/sq ft, etc.] - Y10T 428/31551: Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.] - Y10T 442/3008: Woven fabric has an elastic quality - B32B: LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM - D06N: WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR - Y10S: TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS - Y10T: TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION ## Abstract An improved composite sheet suited for use as artificial leather is prepared by treating with an elastomeric resin a fabric having an interior yarn network and an outer layer of well separated fibers that loop in and out of the yarn network. The resin completely or partially impregnates the outer layer. ## Claims ### Claim 1 An improved composite sheet comprising a fabric which is treated with an elastomeric resin, the composite sheet having a total thickness in the range of 0.5 to 3.0 millimeters, a unit weight in the range of 200 to 1000 g/m.sup.2 and a void content in the range of 60 to 90%, the fabric having a longitudinal direction, a transverse direction, an upper outer layer, a lower outer layer and a stitched, knitted or woven planar network of yarns located between and parallel to the upper and lower outer layers, the planar network of yarns containing a multiplicity of tie points and having a thickness in the range of one-tenth to one-third of the total thickness of the fabric, and at least the upper or the lower outer layer having a thickness in the range of 0.5 to 2.0 mm, containing an elastomeric resin and comprising fibers of 0.5 to 5 decitex that are substantially separated from each other and form loops that pass back and forth through the planar network of yarns, the improvement comprising, in combination, the composite sheet having an over-all density of in the range of 0.2 to 0.45 g/cm.sup.3, the fabric having a tie point concentration in the range of 25 to 400 tie points per cm.sup.2, with a tie point frequency of no more than 25 per cm in each of the longitudinal and transverse directions, the resin-containing outer layer having an effective fiber concentration in the range of 0.03 to 0.25 g/cm.sup.3, an average density in the range of 0.15 to 0.35 g/cm.sup.3 and a layer parameter P of no greater than 0.25 g/cm.sup.3, and the elastomeric resin being a polyurethane resin having a break elongation of at least 125%, a Shore A hardness of no greater than 70 and substantially immediate recovery to its original length after release from a stretch of 100%. ### Claim 2 (depends on 1) A composite sheet according to claim 1 wherein the tie point concentration is in the range of 50 to 250 per cm.sup.2, the tie point frequency is in the range of 5 to 20 per cm and the resin comprises 20 to 45 weight percent of the composite sheet and at least partially impregnates the outer layer of the fabric. ### Claim 3 (depends on 1) A composite sheet according to claim 1 wherein the elastomeric resin impregnates the entire thickness of the fabric. ### Claim 4 (depends on 1) A composite sheet according to claim 1 wherein the composite sheet has a thin polymeric coating atop the outer layer containing the elastomeric resin. ### Claim 5 A composite sheet according to any one of the preceding claims having a compressibility of 10 to 40% which is at least 80% recoverable, a bending length of no greater than 5.5 cm per mm of composite sheet thickness and a moisture retention in g/m.sup.2 of at least 1.25 times the total area weight of the resin impregnated composite fabric. ### Claim 6 (depends on 5) A composite sheet according to claim 5 having a tongue tear strength of at least 2 Kg in each direction, a tensile strength of at least 5 Kg in each direction and a stretchability of least 15% in at least the longitudinal or the transverse direction. ### Claim 7 (depends on 5) A composite sheet according to claim 5 wherein the yarns in at least one direction of the planar yarn network include spandex elastic yarns. ### Claim 8 (depends on 5) A composite sheet according to claim 5 wherein the yarns in at least one direction of the planar yarn network include yarns of partially molecularly oriented fibers of polyester or nylon. ### Claim 9 (depends on 5) A composite sheet according to claim 5 wherein at least 30 weight percent of the fibers in the upper or lower layer are cellulosic fibers.