# US 5,707,511 A · Cyclic process for hydrotreating petroleum feedstocks

> Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt

- Number: US 5,707,511 A
- Document ID: US5707511A
- Status: Granted
- Kind: A
- Application number: 08/362,073
- Filed: 1994-12-22
- Granted: 1998-01-13
- Earliest claimed: 1994-12-22
- Assignees: Exxon Research & Engineering Co.
- Inventors: Gerald E. Markley; George C. Hadjiloizou
- Web page: https://patentgrep.com/patent/US5707511A

## CPC

- C10G 45/02: to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G: CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION (cracking to hydrogen or synthesis gas C01B; cracking or pyrolysis of hydrocarbon gases to individual hydrocarbons or mixtures thereof of definite or specified constitution C07C; cracking to cokes C10B); RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES

## Abstract

A process for simultaneously removing heteroatoms, such as sulfur, from a virgin distillate stream and a light catalytic cyclic stream in two reaction zones in a hydrotreating process unit. One reaction zone will be a low temperature reaction zone and the other will be the high temperature zone. In the low temperature reaction zone, the cracked stream is reacted with a hydrotreating catalyst at a predetermined temperature and in high temperature reaction zone, the virgin distillate stream is reacted with a catalyst which is less reactive than that of the first reaction zone. When catalyst in the high reaction zone is replaced with fresh catalyst the temperature is lowered so that it now becomes the low temperature zone in which the cracked stream is redirected. Correspondingly, the virgin stream is redirected to the other reaction zone whose temperature is now raised and which becomes the high temperature zone and which now contains a catalyst less active than the low temperature reaction zone which now contains the fresher more active catalyst. This cyclic operation is repeated each time fresh catalyst is substituted for spent catalyst.

## Claims

### Claim 1

A process for removing sulfur from a virgin distillate feedstock and a light catalytic cycle oil in two reaction zones, wherein one reaction zone is the lower temperature reaction zone and the other is the higher temperature reaction zone, and wherein said lower temperature reaction zone contains a hydrotreating catalyst which is more active than that of said higher temperature reaction zone, which process comprises:
(a) feeding cracked distillate feedstock into said lower temperature reaction zone which is operated at a temperatures from about 225.degree. to about 340.degree. C. and contains the more active catalyst, which catalyst is comprised of at least one Group VI metal and at least one Group VIII metal on a inorganic support;
(b) feeding the virgin distillate feedstock into said higher temperature reaction zone containing the less active catalyst, which higher temperature reaction zone is operated at a temperature from about 325.degree. C. to about 425.degree. C., but at a temperature at least 25.degree. C. in excess of the temperature of said lower temperature zone;
(c) raising the temperature of each reaction zone to compensate for catalyst deactivation until a temperature is reached wherein the color of either product stream or the combined product stream, is outside of a predetermined target color range;
(d) removing the deactivated catalyst from the higher temperature reaction zone and replacing it with fresh catalyst;
(e) lowering the temperature of said higher temperature zone to a temperature at least about 25.degree. C. lower than said lower temperature zone;
(f) redirecting the cracked feedstock to the now lower temperature zone which now contains the more active catalyst and which is now operated at a temperature from about 225.degree. C. to about 340.degree. C.; and
(g) redirecting the virgin distillate feedstock to the now higher temperature zone which now contains the less active catalyst and which is now operated at a temperature from about 325.degree. C. to about 425.degree. C., but at a temperature at least 25.degree. C. in excess of that of the now lower temperature reaction zone; and
(h) repeating the above steps when the color of either product stream, or the combined product stream exceeds a predetermined color range for an indefinite number of cycles.

### Claim 2 (depends on 1)

The process of claim 1 wherein both the virgin feedstock and the cracked feedstock boil in the range of about 140.degree. C. to about 360.degree. C.

### Claim 3 (depends on 2)

The process of claim 2 wherein the cracked feedstock is a light cycle oil from a fluid catalytic cracking process unit.

### Claim 4 (depends on 2)

The process of claim 2 wherein the catalyst in each of the reaction zones is comprised of about 2 to 20 wt. % Group VIII metal and about 5 to 50 wt. % Group VI metal on an alumina support.

### Claim 5 (depends on 4)

The process of claim 4 wherein the amount of Group VIII metal is from about 4 to 12 wt. % and the mount of Group VI metal is from about 20 to 30 wt. %.