# US 5,707,494 A · Process for preparing water soluble polyaluminosilicates

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- Number: US 5,707,494 A
- Document ID: US5707494A
- Status: Granted
- Kind: A
- Application number: 08/779,099
- Filed: 1997-01-06
- Granted: 1998-01-13
- Earliest claimed: 1994-03-14
- Assignees: E. I. Du Pont de Nemours and Company
- Inventors: John Derek Rushmere; Robert Harvey Moffett
- Web page: https://patentgrep.com/patent/US5707494A

## CPC

- C01B 33/26: Aluminium-containing silicates {, i.e. silico-aluminates}
- D21H 17/66: Salts, e.g. alums
- C01B: NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; {METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C}
- D21H: PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR

## Abstract

An improved method for the production of water soluble polyaluminosilicate microgels, formed by the reaction of solutions of alkali metal silicates with solutions of acids containing dissolved aluminum compounds, is provided.

## Claims

### Claim 1

A process for making paper comprising the steps of
(a) adding to an aqueous paper furnish containing pulp and optionally inorganic filler, 0.01-1% by weight, based on the dry weight of the furnish, of a water soluble polyparticulate polyaluminosilicate microgel having a mole ratio of alumina:silica of between 1:10 and 1:1500 prepared by a process comprising the steps of
(i) acidifying an aqueous solution of an alkali metal silicate containing 0.1-6% by weight of SiO.sub.2 to a pH of 2-10.5 by adding an aqueous acidic solution containing sufficient aluminum salt to provide said mole ratios; and
(ii) adjusting the pH of the product of step (i) to between 1-4 before, after or concurrently with a dilution step, but prior to gelation, to achieve a SiO.sub.2 content of .ltoreq.5% by weight; and at least approximately 0.001% by weight, based on the dry weight of the furnish, of a water soluble cationic polymer;
wherein the microgel has an average particle size of 20-250 nm; and
(b) forming and drying the product of step (a).

### Claim 2

A process for making paper comprising the steps of
(a) adding to an aqueous paper furnish containing pulp and optionally inorganic filler a water soluble polyparticulate polyaluminosilicate microgel consisting essentially of
(i) microgels having mole ratios of alumina:silica of between 1:25 and 1:1500 wherein aluminum ions are present both intra- and inter-particle and wherein the particles of the microgel have diameter of 1-2 nm; and
(ii) water such that the microgels are present at .ltoreq.5% by weight based on SiO.sub.2 content and at a pH of 1-4, and at least approximately 0.001% by weight based on the dry weight of the furnish of a water soluble cationic polymer;
wherein the microgel has an average particle size of 20-250 nm; and
(b) forming and drying the product of step (a).

### Claim 3 (depends on 2)

The process of claim 2 wherein there is an additional amount of aluminum compound added to the paper furnish.

### Claim 4 (depends on 1)

The process of claim 1 wherein there is an ionic polymer added to the paper furnish.