# US 5,707,420 A · Process for the production of a copper powder containing dispersoids

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- Number: US 5,707,420 A
- Document ID: US5707420A
- Status: Granted
- Kind: A
- Application number: 08/534,038
- Filed: 1995-09-26
- Granted: 1998-01-13
- Earliest claimed: 1994-09-27
- Assignees: Norddeutsche Affinerie Aktiengesellschaft
- Inventors: Bernd E. Langner; Peter Stantke; Rene-Holger Wilde
- Web page: https://patentgrep.com/patent/US5707420A

## CPC

- C22C 32/0021: {Matrix based on noble metals, Cu or alloys thereof}
- C22C 1/059: Making alloys comprising less than 5% by weight of dispersed reinforcing phases
- C22C 1/1026: {starting from a solution or a suspension of (a) compound(s) of at least one of the alloy constituents}
- C22C: ALLOYS (treatment of alloys C21D, C22F)

## Abstract

The copper powder contains at least one substance, which is not soluble in copper, e.g. Al.sub.2 O.sub.3, TiO.sub.2, SiO.sub.2 or B.sub.2 O.sub.3. For the production of this copper powder, a surplus of copper metal granulate is mixed with an ammonium salt and/or ammonium hydroxide, together with a saline solution in an aqueous solution, while a gas containing oxygen is added, and at a pH-value of at least 4. A copper-containing precipitate is produced, which is separated and treated at a temperature in the range from 150.degree. to 500.degree. C. in a reducing atmosphere. During this process, Cu(OH).sub.2 and Cu-oxide are transformed into metallic copper powder, which contains the dispersoid. The dispersoid content of the copper powder is preferably in the range from 0.1 to 5% by weight.

## Claims

### Claim 1

A process for the production of a copper powder that contains as a dispersoid at least one substance not soluble in copper, comprising the steps of:
(a) mixing an excess of a copper metal granulate in a mixing zone with an ammonium salt and/or ammonium hydroxide together with a metered addition of a salt in an aqueous solution, and adding along with said mixing a gas which contains oxygen, a pH-value of at least 4 being maintained in the mixing zone, wherein a precipitate of at least one copper-dispersoid precursor compound is produced;
(b) separating the precipitate from the copper metal granulate, and
(c) treating the precipitate at a temperature in the range from 150.degree. to 500.degree. C. in a reducing atmosphere, to produce as a reduction product copper powder containing the dispersoid.

### Claim 2 (depends on 1)

A process according to claim 1, comprising the further step of an after-treatment of suspending the reduction product in an acidic or alkaline solution, separating the reduction product from the solution, and washing and drying the separated reduction product, whereby any dispersoid substance on the surface of the copper powder is removed.

### Claim 3 (depends on 2)

A process according to claim 2, wherein the copper powder from the after-treatment process is heated in a reducing atmosphere to temperatures in the range from 150.degree. to 650.degree. C. for a subsequent reduction.

### Claim 4 (depends on 3)

A process according to claim 3, wherein a pH-value of at least 8 is provided in the mixing zone.

### Claim 5 (depends on 4)

A process according to claim 4, wherein a pH-value in the area from 9 to 12 is used in the mixing zone and the dispersoid is Al.sub.2 O.sub.3.

### Claim 6 (depends on 2)

A process according to claim 2, wherein the salt of the metered addition is a salt of aluminum, boron, silicon, or titanium.

### Claim 7 (depends on 2)

A process according to claim 2, wherein a pH-value of at least 8 is provided in the mixing zone.

### Claim 8 (depends on 7)

A process according to claim 7, wherein a pH-value in the area from 9 to 12 is used in the mixing zone and the dispersoid is Al.sub.2 O.sub.3.

### Claim 9 (depends on 1)

A process according to claim 1, wherein the salt of the metered addition is a salt of aluminum, boron, silicon, or titanium.

### Claim 10 (depends on 9)

A process according to claim 9, wherein a pH-value of at least 8 is provided in the mixing zone.

### Claim 11 (depends on 10)

A process according to claim 10, wherein a pH-value in the area from 9 to 12 is used in the mixing zone and the dispersoid is Al.sub.2 O.sub.3.

### Claim 12 (depends on 1)

A process according to claim 1, wherein a pH-value of at least 8 is provided in the mixing zone.

### Claim 13 (depends on 12)

A process according to claim 12, wherein a pH-value in the area from 9 to 12 is used in the mixing zone and the dispersoid is Al.sub.2 O.sub.3.