# US 5,706,881 A · Heat treatment of superalloy casting with partial mold removal > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 5,706,881 A - Document ID: US5706881A - Status: Granted - Kind: A - Application number: 08/801,168 - Filed: 1997-02-18 - Granted: 1998-01-13 - Earliest claimed: 1994-05-12 - Assignees: Howmet Research Corporation - Inventors: Robert E. Grunstra; Julie A. Faison; Jacqueline B. Wahl - Web page: https://patentgrep.com/patent/US5706881A ## CPC - C22F 1/02: in inert or controlled atmosphere or vacuum (adjusting the composition of the atmosphere C21D1/76) - C30B 29/54: Organic compounds - C30B 33/00: After-treatment of single crystals or homogeneous polycrystalline material with defined structure (C30B31/00 takes precedence) - C22F: CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS (surface treatment of metallic material involving at least one process provided for in class C23 and at least one process covered by this subclass, C23F17/00) - C30B: SINGLE-CRYSTAL GROWTH (by using ultra-high pressure, e.g. for the formation of diamonds, B01J3/06); UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL (zone-refining of metals or alloys C22B); PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE (casting of metals, casting of other substances by the same processes or devices B22D; working of plastics B29; modifying the physical structure of metals or alloys C21D, C22F); SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE (for producing semiconductor devices or parts thereof H10); APPARATUS THEREFOR ## Abstract A method of making a single crystal or columnar grain superalloy casting comprises casting a superalloy in a mold wherein at least one of the mold and optional core comprises an oxygen-bearing ceramic, directionally solidifying the superalloy to form a single crystal or columnar grain superalloy casting, and solution heat treating the superalloy casting. The heat treatment is conducted under an atmosphere including a carbon-bearing gas, such as a carbon monoxide and inert gas mixture, wherein the carbon-bearing gas is present in an effective amount to reduce loss of carbon from the casting during the heat treatment. The heat treatment can be conducted prior to removal of all of the mold and core, if present, such as, for example, when the cast mold is in the as-knocked out condition wherein residual mold and/or core material is present on the casting. Alternately, the heat treatment can be conducted after removal of the mold and core, if present. ## Claims ### Claim 1 A method of reducing occurrence of unacceptable recrystallized grain regions in making a directionally solidified superalloy casting, comprising casting a superalloy in a mold in which an optional core may be present, at least one of the mold and optional core comprising an oxygen-bearing ceramic, directionally solidifying the superalloy to form a single crystal or columnar grain solidified casting, and conducting a post casting treatment that includes removing a portion of the mold from the solidified casting and then subjecting the solidified casting with a remainder of said mold on the casting to a solution heat treatment, said solution heat treatment being conducted in an atmosphere comprising a carbon bearing gas present in an effective amount to reduce loss of carbon by oxidation of said casting from a carbon oxidation reaction between said oxygen-bearing ceramic and said casting during said solution heat treatment. ### Claim 2 (depends on 1) The method of claim 1 wherein the superalloy is cast in an oxygen-bearing ceramic mold. ### Claim 3 (depends on 1) The method of claim 1 wherein the portion of the mold is removed by a knock out operation. ### Claim 4 (depends on 2) The method of claim 2 wherein the superalloy is in contact with an oxygen-bearing ceramic core. ### Claim 5 (depends on 2) The method of claim 2 wherein said carbon bearing gas comprises a mixture comprising about 3 to 20% by volume of carbon monoxide and the balance inert gas. ### Claim 6 (depends on 1) The method of claim 1, wherein said atmosphere has a pressure of about 100 microns and above. ### Claim 7 A method of reducing occurrence of unacceptable recrystallized grain regions in making a single crystal superalloy casting, comprising casting a superalloy in a mold in which an optional core may be present, at least one of the mold and optional core comprising an oxygen-bearing ceramic, directionally solidifying the superalloy to form a single crystal superalloy casting, and subjecting the mold with the solidified casting therein to a post casting treatment including a mechanical knock-out operation to remove a portion of said mold from the casting, leaving a residual portion of said mold on the solidified casting, and subjecting the solidified casting in the as-knocked-out condition to a solution heat treatment, said solution heat treatment being conducted in an atmosphere comprising a carbon bearing gas present in an effective amount to reduce loss of carbon by oxidation of said casting from a carbon oxidation reaction between said oxygen-bearing ceramic and said casting during said solution heat treatment.