# US 5,706,133 A · Retroreflective signage articles, kits for producing same, and methods of making signage articles > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 5,706,133 A - Document ID: US5706133A - Status: Granted - Kind: A - Application number: 08/386,280 - Filed: 1995-02-09 - Granted: 1998-01-06 - Earliest claimed: 1995-02-09 - Assignees: Minnesota Mining and Manufacturing Company - Inventors: Bruce D. Orensteen; Lisa Flatt Nelson; Thomas F. Look; Joseph R. Zwack - Web page: https://patentgrep.com/patent/US5706133A ## CPC - G02B 5/128: transparent spheres being embedded in matrix - Y10S 359/90: Methods - Y10S 428/914: Transfer or decalcomania - Y10T 428/24901: including coloring matter - Y10T 428/31786: Of polyester [e.g., alkyd, etc.] - G02B: OPTICAL ELEMENTS, SYSTEMS OR APPARATUS - Y10S: TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS - Y10T: TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION ## Abstract Retroreflective signage articles comprise a colorant layer directly thermally transferred to a top layer of a reretroreflective sheeting, the top layer devoid of priming treatments and extraneous print-receptive layers. Systems or kits are also described comprising a retroreflective base sheeting in combination with a thermal mass transfer donor element, the donor elements comprising a carrier and a colorant layer adhered thereto, the colorant layer of the signage articles and the donor elements comprising a binder and a colorant. Methods of producing the signage articles employing the systems or kits are also presented. ## Claims ### Claim 1 A retroreflective signage article comprising: a) a retroreflective base sheeting comprising a top layer positioned between retroreflective elements and a source of light, the top layer having an exposed surface devoid of mechanical and chemical primer treatments and extraneous print-receptive layers, the top layer comprising materials selected from the group consisting of polyester, polyester melamine resin, vegetable oil extended polyester melamine resin, plasticized polyvinylchloride, crosslinked aliphatic polyurethane, acrylic resins, polyvinylbutyral resin, crosslinked polyurethane/acrylics, and extruded substantially thermoplastic polymers having an elongation of at least 50% and a tensile relaxation force from 50% elongation after 5 minutes relaxation of no more than 2300 N/m width; and b) thermal mass transfer printed matter adhered to the exposed surface of the top layer, the thermal mass transfer printed matter consisting essentially of a polymeric binder and a colorant dispersed therein, the polymeric binder selected from the group consisting of polyethylene polymers, physical mixtures of a polyethylene polymer and an acrylic polymer, and copolymers of ethylene and an acrylic monomer. ### Claim 2 An embedded lens retroreflective signage article comprising: a) a retroreflective base material comprising: i) a binder layer; ii) a monolayer of lenses anchored in the binder layer; and iii) a specularly reflective layer underlying and spaced from the lenses by a transparent material; b) a weather-resistant, transparent cover film attached to the binder layer of the retroreflective base material, the cover film comprising extruded, substantially thermoplastic polymer having an elongation of at least 50% and a tensile relaxation force from 50% elongation after 5 minutes relaxation of no more than 2300 N/m width; and c) thermal mass transfer printed matter adhered to the cover film, the thermal mass transfer printed matter consisting essentially of a polymeric binder and a colorant dispersed therein, the polymeric binder selected from the group consisting of polyethylene polymers, physical mixtures of a polyethylene polymer and an acrylic polymer, and copolymers of ethylene and an acrylic monomer. ### Claim 3 (depends on 2) Article in accordance with claim 2 wherein the substantially thermoplastic polymer comprises a copolymer of monomers comprising by weight a major proportion of at least one of ethylene and propylene and a minor proportion of a second monomer. ### Claim 4 (depends on 3) Article in accordance with claim 3 wherein the second monomer is a first acid-functional monomer selected from the group consisting of acrylic acid and methacrylic acid. ### Claim 5 (depends on 4) Article in accordance with claim 4 wherein the first acid-functional monomer is crosslinked by cations selected from the group consisting of zinc, sodium, and potassium. ### Claim 6 (depends on 2) Article in accordance with claim 2 wherein the printed matter has a melting point ranging from about 50.degree. to about 140.degree. C. ### Claim 7 (depends on 2) Article in accordance with claim 2 wherein the colorant is selected from the group consisting of carbon black, titania, phthalocyanines, anthraquinones, perylenes, carbazoles, monoazo- and disazobenzimidazolone, isoindolinones, monoazonaphthol, diarylidepyrazolone, rhodamine, indigoid, quinacridone, disazopyranthrone, dinitraniline, pyrazolone, dianisidine, pyranthrone, tetrachloroisoindolinone, dioxazine, monoazoacrylide, anthrapyrimidine, methine, pyrazolone, quinophthalone, naphthazine, perinone, anthraquinone, and monoazo compounds. ### Claim 8 (depends on 2) Article in accordance with claim 2 wherein the thermal mass transfer printed matter adhered to the cover film is non-black. ### Claim 9 (depends on 8) Article in accordance with claim 8 wherein the thermal mass transfer printed matter adhered to the cover film is transparent. ### Claim 10 A kit for producing retroreflective signage articles, the kit comprising: a) a retroreflective base sheeting having a top layer; and b) a thermal mass transfer donor element comprising a carrier and a thermal mass transfer composition adhered to the carrier, the thermal mass transfer composition consisting essentially of a polymeric binder and a colorant dispersed therein, the polymeric binder selected from the group consisting of polyethylene polymers, physical mixtures of a polyethylene polymer and an acrylic polymer, and copolymers of ethylene and an acrylic monomer. ### Claim 11 (depends on 10) Kit in accordance with claim 10 wherein the retroreflective base sheeting is selected from the group consisting of embedded lens sheeting, encapsulated lens sheeting, cube-corner sheeting, and combinations thereof. ### Claim 12 (depends on 11) Kit in accordance with claim 11 wherein the retroreflective base sheeting is embedded lens sheeting comprising: a) a retroreflective base material comprising: i) a binder layer; ii) a monolayer of lenses anchored in the binder layer; and iii) a specularly reflective layer underlying and spaced from the lenses by a transparent material, b) a weather-resistant, transparent cover film attached to the binder layer of the retroreflective base material, the cover film comprising extruded, substantially thermoplastic polymer having an elongation of at least 50% and a tensile relaxation force from 50% elongation after 5 minutes relaxation of no more than 2300 N/m width (preferably no more than 1000 N/m). ### Claim 13 A method of making a retroreflective signage article, the method comprising the steps of: a) selecting a retroreflective base sheeting having a top layer, the top layer positioned between retroreflective elements and a source of light, the top layer having an exposed surface devoid of mechanical and chemical primer treatments and extraneous print-receptive layers, the top layer comprising materials selected from the group consisting of polyester, polyester melamine resin, vegetable oil extended polyester melamine resin, plasticized polyvinylchloride, crosslinked aliphatic polyurethane, acrylic resins, polyvinylbutyral resin, crosslinked polyurethane/acrylics, and extruded substantially thermoplastic polymers having an elongation of at least 50% and a tensile relaxation force from 50% elongation after 5 minutes relaxation of no more than 2300 N/m width; b) selecting a thermal mass transfer donor article, the donor article comprising a carrier and a thermal mass transfer composition adhered to the carrier, the thermal mass transfer composition consisting essentially of a polymeric binder and a colorant dispersed therein, the polymeric binder selected from the group consisting of polyethylene polymers, physical mixtures of a polyethylene polymer and an acrylic polymer, and copolymers of ethylene and an acrylic monomer; and c) thermal mass transfer printing at least a portion of the composition to the top layer of the retroreflective base sheeting. ### Claim 14 (depends on 13) Method in accordance with claim 13 wherein said top layer comprises materials selected from the group consisting of polyester melamine resins, oil modified polyester melamine resins, plasticized polyvinylchloride, acrylic resins, and extruded substantially thermoplastic polymers having an elongation of at least 50% and a tensile relaxation force from 50% elongation after 5 minutes relaxation of no more than 2300 N/m width.