# US 5,705,702 A · Method for preparing triarylsulfonium salts

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- Number: US 5,705,702 A
- Document ID: US5705702A
- Status: Granted
- Kind: A
- Application number: 08/713,257
- Filed: 1996-09-12
- Granted: 1998-01-06
- Earliest claimed: 1996-09-12
- Assignees: Shin-Etsu Chemical Co., Ltd.
- Inventors: Yoichi Osawa; Satoshi Watanabe; Junji Shimada; Toshinobu Ishihara
- Web page: https://patentgrep.com/patent/US5705702A

## CPC

- C07C 381/12: Sulfonium compounds
- C07C: ACYCLIC OR CARBOCYCLIC COMPOUNDS

## Abstract

By reacting an aryl Grignard reagent of the following general formula (1) with thionyl chloride and then reacting the reaction product with a triorganosilyl sulfonate or triorganohalide of the general formula (2): (R.sup.6).sub.3 SiY wherein R.sup.6, which may be the same or different, is a monovalent hydrocarbon group and Y is a substituted or unsubstituted alkylsulfonate or arylsulfonate or halogen atom, there is prepared a triarylsulfonium salt of the following general formula (3). ##STR1## In the formulae, each of R.sup.1 to R.sup.5, which may be the same or different, is a hydrogen atom or a monovalent organic group, especially alkyl, aryl, alkoxy, aryloxy, dialkylamino, dialkylaminoalkyl, alkylthio or arylthio group and X is a bromine or chlorine atom.

## Claims

### Claim 1

A method for preparing a triarylsulfonium salt of the following general formula (3): ##STR6## wherein R.sup.1 to R.sup.5 and Y are as defined below, characterized by comprising the steps of
reacting an aryl Grignard reagent of the following general formula (1): ##STR7## wherein each of R.sup.1 to R.sup.5, which may be the same or different, is a hydrogen atom or a monovalent organic group and X is a bromine or chlorine atom with thionyl chloride, and
then reacting the reaction product with a triorganosilyl sulfonate or triorganosilylhalide of the following general formula (2):
(R.sup.6).sub.3 SiY (2)
wherein R.sup.6, which may be the same or different, is a monovalent hydrocarbon group and Y is a substituted or unsubstituted alkylsulfonate or arylsulfonate or halogen atom.

### Claim 2 (depends on 1)

A method for preparing a triarylsulfonium salt according to claim 1 wherein each of R.sup.1 to R.sup.5 in the general formula (1) is a hydrogen atom, alkyl, aryl, alkoxy, acetal, ketal, aryloxy, dialkylamino, dialkylaminoalkyl, alkylthio or arylthio group.

### Claim 3 (depends on 1)

A method for preparing a triarylsulfonium salt according to claim 1 wherein 0.1 to 0.4 mol of thionyl chloride is reacted per mol of the aryl Grignard reagent of the general formula (1) and thereafter, 0.1 to 1 mol of the triorganosilyl sulfonate or triorganosilyl halide of the general formula (2) is reacted per mol of the aryl Grignard reagent.

### Claim 4 (depends on 1)

A method for preparing a triarylsulfonium salt according to claim 1 wherein thionyl chloride is added to a reactor where the aryl Grignard reagent of the general formula (1) has been prepared and thereafter, the triorganosilyl sulfonate or triorganosilyl halide of the general formula (2) is added to the reactor without isolating the reaction product.