# US 5,705,580 A · Process for preparing beads of polymers having an acrylic basis

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- Number: US 5,705,580 A
- Document ID: US5705580A
- Status: Granted
- Kind: A
- Application number: 08/801,462
- Filed: 1997-02-18
- Granted: 1998-01-06
- Earliest claimed: 1996-02-19
- Assignees: Atohaas Holding C.V.
- Inventors: Fabio Giberti
- Web page: https://patentgrep.com/patent/US5705580A

## CPC

- C08F 265/04: on to polymers of esters
- C08F 220/10: Esters
- C08F: MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS

## Abstract

Process for preparing beads based on acrylic polymers which comprises the preparation of microbeads from 10 to 40 micron by means of a polymerization process in suspension of acrylic monomers in the presence of at least a crosslinking monomer at least bifunctional, characterized in that a second polymerization of the acrylic monomers is carried out in absence of crosslinking monomers and using as suspending phase a fraction of the suspension obtained in the preceding polymerization containing a crosslinking agent, said fraction containing an amount of microbeads comprised between 3 and 40% by weight with respect to the final polymer obtained in the second polymerization.

## Claims

### Claim 1

Process for preparing beads based on acrylic polymers which comprises the preparation of microbeads from 10 to 40 micron by means of a polymerization process in suspension of acrylic monomers in the presence of at least a crosslinking monomer at least bifunctional, characterized in that a second polymerization of the acrylic monomers is carried out in absence of crosslinking monomers and by using as suspending phase a fraction of the suspension obtained in the preceding polymerization containing a crosslinking agent, said fraction containing an amount of microbeads comprised between 3 and 40% by weight with respect to the final polymer obtained in the second polymerization.

### Claim 2 (depends on 1)

Process according to claim 1 wherein a fraction of the suspension obtained in the preceding polymerization containing a crosslinking agent is used as suspending agent, said fraction containing an amount of microbeads of from 4.5 to 25.

### Claim 3 (depends on 1)

Process according to claim 1 wherein waste waters are utilized as dispersing phase instead of water in the second polymerization in absence of crosslinking agent, optionally diluted with water, coming from the polymerization in suspension of acrylic monomers which produce beads of sizes greater than 100 microns.

### Claim 4 (depends on 1)

Process according to claim 1 wherein the acrylic monomers for preparing polymers having an acrylic basis are C.sub.1 -C.sub.8 alkyl(meth)acrylates linear or branched when possible, selected from
a1) methyl(meth)acrylate, ethyl(meth)acrylate, propyl(meth)acrylate, isopropyl(meth)acrylate, butylacrylate, secbutyl(meth)acrylate, ter-butyl(meth)acrylate;
b1) optionally one or more monomers soluble in water having solubility in water of at least 5 g per 100 g of water at T of 23.degree. C. in amount of 50% by weight, selected from acrylic, methacrylic acids, acrylamide, hydroxyethyl(meth)acrylate, hydroxypropyl(meth)acrylate;
c1) optionally another monomer in amount of 50% by weight at most, selected from styrene, alphamethylstyrene, (meth)acrylonitrile, n-alkyl- or arylmaleimides with alkyl from 1 to 10 carbon atoms and aryl from 6 to 12 carbon atoms, butadiene, styrenesulphonic acid, N-vinylpyrolidone.

### Claim 5 (depends on 1)

Process according to claim 1 wherein the polyvinylic alcohol is used as suspending agent in the first polymerization in the presence of crosslinking agent, in concentration generally of at least 1.5% by weight and up to values of about 10% by weight.

### Claim 6 (depends on 1)

Process according to claim 1 wherein the ratio between aqueous phase and monomers in the polymerization in the presence of crosslinking agent for the preparation of microbeads is higher than 2:1.

### Claim 7 (depends on 1)

Process according to claim 1, wherein the ratio between aqueous phase and monomers in the polymerization in absence of crosslinking agent is 1.4:1 or higher.

### Claim 8 (depends on 1)

Beads based on acrylic polymers having sizes from 80 to 300 microns obtained by the process according to claim 1.

### Claim 9 (depends on 8)

Beads based on acrylic polymers according to claim 8 having sizes between 140 and 250 microns.