# US 5,705,302 A · Color filter for liquid crystal display device and method for producing the color filter > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 5,705,302 A - Document ID: US5705302A - Status: Granted - Kind: A - Application number: 08/468,479 - Filed: 1995-06-06 - Granted: 1998-01-06 - Earliest claimed: 1989-04-28 - Assignees: Seiko Epson Corporation - Inventors: Yoshihiro Ohno; Hiroshi Kiguchi; Fumiaki Matsushima; Taeko Nakano; Kuniyasu Matsui; Tsuyoshi Sunagawa; Toshiki Nakajima; Satoru Miyashita; Shigeyuki Ogino - Web page: https://patentgrep.com/patent/US5705302A ## CPC - G02B 5/20: Filters (polarising elements G02B5/30) - G02B 5/201: {in the form of arrays} - G02F 1/1335: Structural association of cells with optical devices, e.g. polarisers or reflectors - G02F 1/133514: {Colour filters} - G02F 1/13439: {characterised by their electrical, optical, physical properties; materials therefor; method of making} - G02B: OPTICAL ELEMENTS, SYSTEMS OR APPARATUS - G02F: OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS ## Abstract A color filter for a liquid crystal display device comprises an optically transparent substrate, a transparent conductive layer formed on the substrate, and a color layer formed on the transparent conductive layer with red, green and blue pixels arranged in a predetermined pattern. The color layer comprises pigments for coloring purpose and transparent conductive particles having a hydrophobic surface. The transparent conductive particles are included from 5% to 50% by volume of the color layer. The color layer may preferably have a specific resistivity of from 10.sup.-1 .OMEGA..multidot.cm to 10.sup.8 .OMEGA..multidot.cm. The transparent conductive particles comprise base transparent conductive particles having a hydrophobic compound bound on their surface by coupling or graft polymerization. A typical process of the color filter production comprises the steps of: (a) forming the transparent conductive layer of a predetermined pattern on the transparent substrate, (b) preparing a micelle colloid dispersion by dispersing a pigment and transparent conductive particles having hydrophobic surface in a medium containing a redox reactive surfactant and an electrolyte, and (c) carrying out an electrolysis in the micelle colloid dispersion by utilizing the transparent conductive layer on the transparent substrate for the anode to deposit the color layer comprising the pigment and the transparent conductive particles on the transparent conductive layer. ## Claims ### Claim 1 A color filter for liquid crystal display device comprising an optically transparent substrate, a transparent conductive layer formed on the substrate, and a color layer formed on the transparent conductive layer with red, green and blue pixels arranged in a selected pattern, wherein said color layer includes at least pigments for coloring and transparent conductive particles having a hydrophobic surface, and said transparent conductive particles are included from 5% to 50% by volume of said color layer. ### Claim 2 (depends on 1) The color filter for liquid crystal display device according to claim 1 wherein said transparent conductive particles are included from 10% to 50% by volume of said color layer. ### Claim 3 (depends on 1) The color filter for liquid crystal display device according to claim 1 wherein said color layer has a specific resistivity of from 10.sup.-1 .OMEGA..multidot.cm to 10.sup.8 .OMEGA..multidot.cm. ### Claim 4 (depends on 3) The color filter for liquid crystal display device according to claim 3 wherein said color layer has a specific resistivity of from 10.sup.-1 .OMEGA..multidot.cm to 10.sup.7 .OMEGA..multidot.cm. ### Claim 5 (depends on 1) The color filter for liquid crystal display device according to claim 1 wherein said transparent conductive particles comprise base transparent conductive particles having a hydrophobic compound bound on their surface. ### Claim 6 (depends on 5) The color filter for liquid crystal display device according to claim 5 wherein said hydrophobic compound is at least one member selected from the group consisting of silane coupling agents, titanium coupling agents, aluminum coupling agents, zirconium coupling agents, and zircoaluminate agents. ### Claim 7 (depends on 6) The color filter for liquid crystal display device according to claim 6 wherein said silane coupling agent is at least one member selected from the group consisting of compounds represented by formula (1): ##STR7## wherein X is an alkoxy group, an acyloxy group, amino group or chlorine, R.sup.1 and R.sup.2 are independently an alkyl group, an alkenyl group, cyclohexyl group or phenyl group which optionally has a side chain or oxygen bridge, and (m+n) is from 0 to 4; and compounds represented by formula (1)': ##STR8## wherein R is an alkyl group, Y is an organic group containing vinyl group, glycidyl group, methacryl group; amino group, mercapto group, isocyanate group, or azide group, or an organic group having a halogen atom selected from chlorine and fluorine on its terminal, and n is 2 or 3. ### Claim 8 (depends on 6) The color filter for liquid crystal display device according to claim 6 wherein said titanium coupling agent is at least one member selected from the group consisting of compounds represented by formula (2): RO-Ti-X.sub.3 ( 2) wherein RO is a hydrolyzable alkoxy group; and X is a long chain hydrophobic group containing carboxyl group, sulfonyl group or phosphate group. ### Claim 9 (depends on 5) The color filter for liquid crystal display device according to claim 5 wherein said hydrophobic compound comprises a graft polymerized hydrophobic monomer. ### Claim 10 (depends on 9) The color filter for liquid crystal display device according to claim 9 wherein said monomer is at least one member selected from an acrylamide derivative, an alkyl (meth)acrylate compound, an aromatic vinyl compound, a halogen-containing vinyl compound, and a cyanated vinyl compound. ### Claim 11 (depends on 1, 2, 3, 4, 5, 6, 7, 8, 9, 10) The color filter for liquid crystal display device according to any one of claims 1 to 10 wherein said color layer has a thickness of from 0.4 .mu.m to 2.0 .mu.m. ### Claim 12 (depends on 1, 2, 3, 4, 5, 6, 7, 8, 9, 10) The color filter for liquid crystal display device according to any one of claims 1 to 10 further comprising a transparent flattening layer formed on the color layer. ### Claim 13 (depends on 12) The color filter for liquid crystal display device according to claim 12 wherein said flattening layer has a thickness of from 0.1 .mu.m to 1.0 .mu.m. ### Claim 14 A method for producing a color filter for liquid crystal display device (a) forming a transparent conductive layer of a predetermined pattern on a transparent substrate; (b) preparing a micelle colloid dispersion by dispersing a pigment and transparent conductive particles having hydrophobic surface in a medium containing a redox reactive surfactant and an electrolyte; and (c) carrying out an electrolysis in said micelle colloid dispersion by utilizing the transparent conductive layer on the transparent substrate produced in the step (a) for the anode to deposit a color layer comprising said pigment and said transparent conductive particles on the transparent conductive layer. ### Claim 15 (depends on 14) The method for producing a color filter for liquid crystal display device according to claim 14 wherein said surfactant used in said step (b) is a ferrocene derivative. ### Claim 16 (depends on 14, 15) The method for producing a color filter for liquid crystal display device according to claim 14 or 15 wherein said transparent conductive particles having the hydrophobic surface used in said step (b) are produced by a coupling treatment comprising the steps of; introducing a functional group on base transparent conductive particles; and allowing a coupling agent to react with said base transparent conductive particles via said functional group. ### Claim 17 (depends on 16) The method for producing a color filter for liquid crystal display device according to claim 16 wherein said base transparent conductive particles have an average primary particle size of from 25 .ANG. to 1,000 .ANG.. ### Claim 18 (depends on 14, 15) The method for producing a color filter for liquid crystal display device according to claim 14 or 15 wherein said transparent conductive particles having the hydrophobic surface used in said step (b) are produced by a graft polymerization treatment comprising the steps of; introducing a functional group on base transparent conductive particles; and graft polymerizing a monomer having a hydrophobic organic group on its terminal onto said base transparent conductive particles via said functional group. ### Claim 19 A method for producing a color filter for liquid crystal display device (a) forming a transparent conductive layer of a predetermined pattern on a transparent substrate, (b) preparing a dispersion includes at least a pigment, transparent conductive particles having hydrophobic surface and resin; and (c) coating said dispersion on said transparent conductive layer and curing said coating to form a color layer. ### Claim 20 (depends on 19) The method for producing a color filter for liquid crystal display device according to claim 19 wherein said transparent conductive particles having the hydrophobic surface used in said step (b) are produced by a coupling treatment comprising the steps of; introducing a functional group on base transparent conductive particles; and allowing a coupling agent to react with said base transparent conductive particles via said functional group. ### Claim 21 (depends on 19) The method for producing a color filter for liquid crystal display device according to claim 19 wherein said transparent conductive particles having the hydrophobic surface used in said step (b) are produced by a graft polymerization treatment comprising the steps of; introducing a functional group on base transparent conductive particles; and graft polymerizing a monomer having a hydrophobic organic group on its terminal onto said base transparent conductive particles via said functional group. ### Claim 22 (depends on 20, 21) The method for producing a color filter for liquid crystal display device according to claim 20 or 21 wherein said base transparent conductive particles have an average primary particle size of from 25 .ANG. to 1,000 .ANG..