# US 5,705,255 A · Method and an apparatus for making a graphic representation on objects made of a polyolefin polymer and film for implementing said method > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 5,705,255 A - Document ID: US5705255A - Status: Granted - Kind: A - Application number: 08/509,330 - Filed: 1995-07-31 - Granted: 1998-01-06 - Earliest claimed: 1994-07-29 - Assignees: Grazioli S.p.A. - Inventors: Vittorio Grazioli - Web page: https://patentgrep.com/patent/US5705255A ## CPC - B29C 45/14811: {Multilayered articles (B29C45/14827 takes precedence)} - B29K 2995/002: Coloured - B29K 2995/0026: Transparent - Y10T 428/24802: Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] - Y10T 428/24868: Translucent outer layer - Y10T 428/24901: including coloring matter - Y10T 428/24959: of adhesive layers - Y10T 428/269: including synthetic resin or polymer layer or component - Y10T 428/31507: Of polycarbonate - Y10T 428/31692: Next to addition polymer from unsaturated monomers - Y10T 428/31699: Ester, halide or nitrile of addition polymer - Y10T 428/31909: Next to second addition polymer from unsaturated monomers - B29C: SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING (making preforms B29B11/00; making laminated products by combining previously unconnected layers which become one product whose layers will remain together B32B37/00 - B32B41/00) - B29K: INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR {MOULDS, } REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS - Y10T: TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION ## Abstract The method for making a graphic representation on objects made of a polyolefin polymer, consists of printing a graphic representation on a face of a first film made of a stretched polymer, chosen among a polyester polymer and an acrylic polymer, associating the first film with a second film in order to obtain a membrane formed by the associated first and second films containing the graphic representation between them, transferring the membrane inside an injection mold and injecting a polyolefin polymer in the mold for forming the object, obtaining at least a partial melting of the second film so that the membrane forms one body with said object. ## Claims ### Claim 1 A method of making a graphic representation on an object made of a polyolefin polymer, comprising the steps of: printing a graphic representation on a face of a first transparent film selected from the group which consists of a polyester polymer, an acrylic polymer and an polyamide polymer to form a first printed film; associating said first printed film with a second film in order to obtain a membrane formed by said associated first and second films containing said graphic representation between them; transferring said membrane into an injection mold; and injecting a polyolefin polymer in said mold for forming said object, obtaining at least a partial melting of said second film in order that said membrane forms one body with said object and said graphic representation is visible exclusively through said transparent first film. ### Claim 2 (depends on 1) The method defined in claim 1, wherein said second film is substantially unstretched polypropylene. ### Claim 3 (depends on 1) The method defined in claim 1 wherein at least said first film is first stabilized with additives for improving its resistance to the atmospheric oxygen and to solar light. ### Claim 4 (depends on 1) The method defined in claim 1 wherein said second film has a melting point substantially lower than the temperature of said polymer injected into said mold when said polymer makes contact with said second film. ### Claim 5 (depends on 1) The method defined in claim 1 wherein an adhesive is disposed between said films, and said adhesive is protected from ultraviolet rays. ### Claim 6 (depends on 1) The method defined in claim 1 wherein said membrane is electrostatically charged before being inserted into said mold. ### Claim 7 (depends on 1) The method defined in claim 1 wherein said second film is produced with an unstretched polyolefin polymer. ### Claim 8 (depends on 1) The method defined in claim 1 wherein said first film and said second film are associated by an adhesive. ### Claim 9 (depends on 8) The method defined in claim 8 wherein said adhesive has a polyurethane base preferably added with a methyl-hindered monomeric HALS mixture. ### Claim 10 (depends on 1) The method defined in claim 1 wherein said first film is a polyester and the melting point of said first film is comprised between 185.degree. C. and 300.degree. C. ### Claim 11 (depends on 1) The method defined in claim 1 wherein the melting point of said second film is comprised between 120.degree. C. and 190.degree. C. ### Claim 12 (depends on 1) The method defined claim 1 wherein during the printing step of said graphic representation on said first film, the regions of said first film which are not affected by said graphic representation are covered by an ink having the same color as said object on which the membrane is applied. ### Claim 13 (depends on 1) The method defined in claim 1 wherein said polyester polymer is selected from the group which consists of PET (polyethyleneterephthalate), PBT (polybuthyleneterephthalate) and PC (polycarbonate). ### Claim 14 (depends on 1) The method defined in claim 1 wherein said acrylic polymer is a polymethyl methacrylate or a polydimethyl methacrylate. ### Claim 15 (depends on 1) The method defined in claim 1 wherein said first film is soluble in a solvent of an ink used for printing said graphic representation. ### Claim 16 (depends on 1) The method defined in claim 1 wherein said solvent is ethyl acetate, said first film being formed by polymethyl methacrylate. ### Claim 17 (depends on 1) The method defined in claim 1 wherein said first film has additives adapted to increase the resistance to ultraviolet rays. ### Claim 18 A membrane for making a graphic representation on objects made of a polyolefin polymer, comprising a first transparent film formed by a polymer chosen selected from the group which consists of a polyester polymer, an acrylic polymer and a polyamide polymer, said graphic representation being printed on one face of said first film, said first film being associated with a second film, by means of a polypropylene adhesive, so that said graphic representation is visible through said transparent first film. ### Claim 19 (depends on 18) The membrane defined in claim 18 wherein said second film has a melting point substantially lower than the temperature of said polyolefin polymer when said polyolefin polymer is injected into a mold in which the membrane is disposed, when said polyolefin polymer makes contact with said second film. ### Claim 20 (depends on 18) The membrane defined in claim 18, containing additives for increasing its resistance to ultraviolet rays. ### Claim 21 (depends on 18) The membrane defined in claim 18 wherein said acrylic polymer is a polyalkyl methacrylate selected from the group which consists of a polymethyl methacrylate and polydimethyl methacrylate. ### Claim 22 An injection molded object comprising an external layer formed by a polymer selected from the group which consists of a polyester polymer, an acrylic polymer and a polyamide polymer, a first lower layer formed by at least one ink adapted to define a graphic representation, a second lower layer formed by an adhesive polymer, a third lower layer formed by a polyolefin polymer having a lower melting point than that of said external layer, said third layer adhering by melting to the body of said molded object. ### Claim 23 A molded object according to clam 22 wherein the melting point of said external layer is comprised between 185.degree. C. and 300.degree. C., and preferably between 205.degree. C. and 280.degree. C. and more preferably between 220.degree. C., and 265.degree. C., said external layer being formed with a polyester polymer. ### Claim 24 (depends on 22) The molded object defined in claim 22, wherein the melting point of said third layer is comprised between 120.degree. C. and 190.degree. C., and preferably between 135.degree. C. and 170.degree. C. and more preferably between 145.degree. C. and 150 .degree. C. ### Claim 25 (depends on 22) The molded object defined in claim 22, wherein the melting point of the body of said molded object is higher than the melting point of said third layer. ### Claim 26 (depends on 22) The molded object defined in claim 22 wherein said acrylic polymer is a polyalkyl methacrylate selected from the group which consists of polymethyl methacrylate and polydimethyl methacrylate.