# US 5,705,220 A · Manufacture of a substrate having a modified orientation layer and of a liquid crystalline display device comprising such a substrate

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- Number: US 5,705,220 A
- Document ID: US5705220A
- Status: Granted
- Kind: A
- Application number: 08/530,783
- Filed: 1995-09-19
- Granted: 1998-01-06
- Earliest claimed: 1994-09-20
- Assignees: U.S. Philips Corporation
- Inventors: Gerard Cnossen; Nicolaas P. Willard
- Web page: https://patentgrep.com/patent/US5705220A

## CPC

- G02F 1/133711: {by organic films, e.g. polymeric films}
- C09K 2323/025: Polyamide
- G02F: OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- C09K: MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE

## Abstract

The invention relates to a method of manufacturing a substrate having a modified orientation layer and a liquid-crystalline display device comprising such a substrate. The orientation layer is made from a polymer and is modified with organic groups which induce a pretilt in the liquid-crystalline material when they are used in a liquid-crystalline display device. According to the invention, for modifying the orientation layer use is made of a precursor compound of the organic groups which is vaporized, whereafter the substrate carrying the orientation layer is exposed to the vapour formed in the process. Preferably, the orientation layer comprises hydroxyl groups such as PVA, and a carboxylic acid halogenide such as an alkyloyl chloride is used as the precursor. A further favourable combination comprises orientation layers of polyamide acid and alkylamine precursor compounds.

## Claims

### Claim 1

A method of reacting pretilt-inducing organic groups with an orientation layer of an organic polymer which is provided on a substrate, the orientation layer being intended to induce a molecular ordering in the plane of the substrate of molecules of a liquid crystalline material lying against the orientation layer, and the pretilt-inducing organic groups being intended to induce a pretilt angle between the substrate and molecules of the liquid crystalline material in contact with the pretilt-inducing organic groups on the orientation layer, characterized in that a precursor compound of the organic group is vaporized and in that the substrate carrying the orientation layer is exposed to the vapour formed in this process.

### Claim 2 (depends on 1)

A method as claimed in claim 1, characterized in that the orientation layer comprises hydroxyl groups and in that a carboxylic acid halogenide is used as the precursor compound.

### Claim 3 (depends on 2)

A method as claimed in claim 2, characterized in that the orientation layer is mainly composed of polyvinyl alcohol and in that an alkyloyl chloride is used as the precursor compound.

### Claim 4 (depends on 1)

A method as claimed in claim 1, characterized in that the orientation layer is composed of a polyamide acid and in that an alkylamine is used as the precursor compound.

### Claim 5 (depends on 1)

A method of manufacturing a liquid-crystalline display device comprising two parallel substrates whose facing surfaces are provided with an orientation layer and between which substrates a liquid-crystalline material is interposed, characterized in that said orientation layers comprise organic groups which are provided by means of the method as claimed in claim 1.