# US 5,705,174 A · Process for the preparation of microcapsule compositions > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 5,705,174 A - Document ID: US5705174A - Status: Granted - Kind: A - Application number: 08/482,586 - Filed: 1995-06-07 - Granted: 1998-01-06 - Earliest claimed: 1995-06-07 - Assignees: American Cyanamid Company - Inventors: Brian Eric Benoff; Robin William Dexter - Web page: https://patentgrep.com/patent/US5705174A ## CPC - B01J 13/16: Interfacial polymerisation - Y10T 428/2987: Addition polymer from unsaturated monomers only - B01J: CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS - Y10T: TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION ## Abstract The present invention provides a process for the preparation of microcapsule compositions, methods for using those microcapsule compositions, compositions containing those microcapsule compositions and microcapsules prepared by the process of the present invention. ## Claims ### Claim 1 A process for the preparation of a microcapsule composition which comprises: (a) providing an aqueous solution containing (i) a salt or mixture of salts and (ii) an emulsifier or mixture of emulsifiers; wherein the salt or mixture of salts is selected from the group consisting of lithium chloride, sodium chloride, potassium chloride, ammonium chloride, magnesium chloride, calcium chloride, lithium nitrate, sodium nitrate, potassium nitrate, magnesium nitrate, calcium nitrate, lithium sulfate, sodium sulfate, potassium sulfate, ammonium sulfate, magnesium sulfate, sodium monohydrogen phosphate, potassium monohydrogen phosphate, ammonium monohydrogen phosphate, sodium dihydrogen phosphate, potassium dihydrogen phosphate, ammonium dihydrogen phosphate and mixtures thereof; (b) dispersing, with agitation, in the aqueous solution, a salt water-immiscible solution containing a first reactive wall forming component selected from the group consisting of a polyisocyanate, a polyacid chloride, a polychloroformate and a polysulfonylchloride; and a salt water-immiscible material selected from the group consisting of a salt water-immiscible agricultural compound, pharmaceutical compound, dye, ink, and flavoring agent to form a dispersion; and (c) adding, with agitation, to the dispersion of step (b), a second reactive wall forming component selected from the group consisting of a polyamine and polyol which reacts with the first reactive wall forming component to form a polycondensate shell wall about the salt water-immiscible material. ### Claim 2 (depends on 1) A pesticidal composition which comprises an agronomically acceptable carrier and a pesticidally effective amount of a microencapsulated pesticide which is microencapsulated by the process of claim 1. ### Claim 3 (depends on 1) The process according to claim 1 wherein the salt is selected from the group consisting of sodium chloride, potassium chloride, calcium chloride and magnesium sulfate. ### Claim 4 (depends on 3) The process according to claim 3 wherein the salt is magnesium sulfate. ### Claim 5 (depends on 1) The process according to claim 1 wherein the aqueous solution contains about 5% to 30% by weight of the salt or mixture of salts. ### Claim 6 (depends on 1) The process according to claim 1 wherein the salt water-immiscible material is an agricultural product. ### Claim 7 (depends on 6) The process according to claim 6 wherein the agricultural product is selected from the group consisting of a herbicide and an insecticide. ### Claim 8 (depends on 7) The process according to claim 7 wherein the herbicide is selected from the grou consisting of a dinitroaniline compound and an acetanilide compound, and the insecticide is selected from the group consisting of a phosphoric acid ester compound and a pyrethroid compound. ### Claim 9 (depends on 8) The process according to claim 8 wherein the dinitraniline compound is selected from the group consisting of pendimethalin and trifluralin, the acetanilide compound is selected from the group consisting of alachlor and metolachlor, the phosphoric acid ester compound is selected from the group consisting of terbufos, malathion and chlorpyrifos, and the pyrethroid compound is selected from the group consisting of cypermethrin, alpha-cypermethrin and permethrin. ### Claim 10 (depends on 9) The process according to claim 9 wherein the dinitroaniline compound is pendimethalin. ### Claim 11 (depends on 1) The process according to claim 1 wherein the aqueous solution contains about 0.5% to 5% by weight of the emulsifier or mixture of emulsifiers. ### Claim 12 (depends on 1) The process according to claim 1 wherein the first reactive wall forming component is a polyisocyanate. ### Claim 13 (depends on 12) The process according to claim 12 wherein the polyisocyanate is a polymethylene polyphenylene isocyanate. ### Claim 14 (depends on 1) The process according to claim 1 wherein the salt water-immiscible solution contains about 1% to 15% by weight of the first reactive component. ### Claim 15 (depends on 1) The process according to claim 1 wherein the second reactive wall forming component is a polyamine. ### Claim 16 (depends on 15) The process according to claim 15 wherein the polyamine is 1,6-hexamethylenediamine. ### Claim 17 (depends on 1) The process according to claim 1 wherein the second reactive component is present in an amount of about 0.3% to 5% by weight relative to that of the salt water-immiscible solution. ### Claim 18 (depends on 1) The process according to claim 1 wherein the median diameter of the microcapsules is about 3 micrometers to 50 micrometers. ### Claim 19 (depends on 18) The process according to claim 18 wherein the median diameter of the microcapsules is about 5 micrometers to 15 micrometers. ### Claim 20 (depends on 1) The process according to claim 1 wherein the process is conducted at a temperature of about 35.degree. C. to 85.degree. C. ### Claim 21 (depends on 1) A microcapsule comprising a salt water-immiscible material within a shell wall of a polycondensate which is prepared by the process of claim 1. ### Claim 22 (depends on 1) A method for controlling a pest which comprises applying to the locus of the pest a pesticidally effective amount of a microencapsulated pesticide which is microencapsulated by the process of claim 1.