# US 5,705,129 A · NOx sensor

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- Number: US 5,705,129 A
- Document ID: US5705129A
- Status: Granted
- Kind: A
- Application number: 08/626,314
- Filed: 1996-04-02
- Granted: 1998-01-06
- Earliest claimed: 1995-04-10
- Assignees: NGK Insulators, Ltd.
- Inventors: Tomonori Takahashi; Naoyuki Ogawa; Toshihiro Yoshida; Yuji Katsuda
- Web page: https://patentgrep.com/patent/US5705129A

## CPC

- G01N 33/0037: {NOx}
- G01N 27/12: of a solid body in dependence upon absorption of a fluid; of a solid body in dependence upon reaction with a fluid {, for detecting components in the fluid}
- Y02A 50/20: Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
- G01N: INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES (measuring or testing apparatus or processes other than immunoassay, involving enzymes or microorganisms C12M, C12Q)
- Y02A: TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE

## Abstract

An NOx sensor has the sensor element made of an oxide, the resistance of which is varied in response to an NOx component in a gas to be measured, and a measuring portion for measuring a resistance variation of the sensor element and for detecting an NOx concentration in the gas to be measured. A catalyst is arranged at an upstream side of a flow of the gas to be measured with respect reach to the sensor element, which makes a partial pressure ratio of NO/NO.sub.2 reach to an equilibrium state and removes a CO component from the gas to be measured. A heater for adjusting a temperature is arranged at a position close to the sensor element, which maintains temperatures of the sensor element and the catalyst constant. An O.sub.2 sensor is arranged at a position close to the sensor element so that the measuring portion can detect accurately the concentration of Nox in the measurement gas by reference to the resistance of the sensor element.

## Claims

### Claim 1

An apparatus for sensing NOx in a measurement gas, comprising:
an oxide sensor element arranged in a flow path of the measurement gas, the resistance of said oxide sensor element varying in response to changes in NOx concentration of the measurement gas;
a catalyst arranged upstream of said oxide sensor element to maintain partial pressures of NO and NO.sub.2 in the measurement gas at an equilibrium state and remove CO from the measurement gas;
heating means arranged proximate said oxide sensor element and said catalyst for maintaining the temperature of said oxide sensor element and said catalyst substantially constant;
an O.sub.2 sensor arranged proximate said oxide sensor element for measuring the concentration of oxygen in the measurement gas; and
measuring means for receiving signals from said oxide sensor element and said O.sub.2 sensor and for determining the concentration of NOx in the measurement gas.

### Claim 2 (depends on 1)

The apparatus of claim 1, wherein said measuring means detects the oxygen concentration of the measurement gas using said O.sub.2 sensor, detects the resistance of said oxide sensor element, and determines the NOx concentration of the measurement gas based on the detected oxygen concentration and the detected resistance of said oxide sensor element.

### Claim 3 (depends on 1)

The apparatus of claim 1, wherein said oxide sensor element comprises a metal oxide semiconductor.

### Claim 4 (depends on 3)

The apparatus of claim 3, wherein said metal oxide semiconductor is selected from the group consisting of SnO.sub.2, TiO.sub.2 and In.sub.2 O.sub.3.

### Claim 5 (depends on 1)

The apparatus of claim 1, wherein said catalyst comprises one of a precious metal and an oxide.

### Claim 6 (depends on 5)

The apparatus of claim 5, wherein said precious metal is selected from the group consisting of platinum, rhodium and gold.

### Claim 7 (depends on 5)

The apparatus of claim 5, wherein said oxide of the catalyst is selected from the group consisting of manganese oxide, cobalt oxide and tin oxide.