# US 5,705,046 A · Process for treating effluent from flue-gas desulfurization system and apparatus therefor

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- Number: US 5,705,046 A
- Document ID: US5705046A
- Status: Granted
- Kind: A
- Application number: 08/484,820
- Filed: 1995-06-07
- Granted: 1998-01-06
- Earliest claimed: 1991-10-17
- Assignees: Chubu Electric Power Co., Inc.; Mitsubishi Jukogyo Kabushiki Kaisha; Asahi Glass Company, Limited
- Inventors: Tatunori Miwata; Tsumoru Nakamura; Shinichiro Kotake; Yoshiharu Aoki
- Web page: https://patentgrep.com/patent/US5705046A

## CPC

- C02F 9/00: Multistage treatment of water, waste water or sewage
- B01D 53/73: After-treatment of removed components
- B01D 61/44: Ion-selective electrodialysis
- B01D 61/52: Accessories; Auxiliary operation
- C02F 1/04: by distillation or evaporation
- C02F 1/469: by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis
- C02F 1/52: by flocculation or precipitation of suspended impurities {(C02F1/463 takes precedence)}
- C02F 11/00: Treatment of sludge; Devices therefor
- C02F 2103/18: from the purification of gaseous effluents
- C02F: TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE (separation in general B01D; special arrangements on waterborne vessels of installations for treating water, waste water or sewage, e.g. for producing fresh water, B63J; adding materials to water to prevent corrosion C23F; treating radioactively-contaminated liquids G21F9/04; regeneration of reactants for recirculation into processes, see the relevant places for the processes)
- B01D: SEPARATION (separating solids from solids by wet methods B03B, B03D; by pneumatic jigs or tables B03B; by other dry methods B07; magnetic or electrostatic separation of solid materials from solid materials or fluids, separation by high-voltage electric fields B03C; centrifuges, vortex apparatus B04; presses per se for squeezing-out liquid from liquid-containing material B30B9/02; treatment of water C02F, e.g. softening by ion-exchange C02F1/42; {arrangements of air intake cleaners in gas turbine plants F02C7/05} ; arrangements or mounting of filters in air-conditioning, air-humidification or ventilation F24F13/28)

## Abstract

A process for treating effluent from a flue-gas desulfurization system wherein the resulting gypsum is removed, comprises filtering the gypsum and fly ash free effluent by a filter, transferring the filtrate to an electrodialyzer wherein cation-exchange membranes and univalent anion-exchange membranes are alternately set up, concentrating chlorine ions in the solution therein by dialysis, further concentrating the solution by evaporation in an evaporator, kneading the concentrated solution with cement or a mixture of cement and coal ash to a solid matter with no harm, and thereafter abandoning for landfill; and an apparatus for treating effluent from a flue-gas desulfurization system, comprising a filter for filtering the effluent to a turbidity low enough for treatment by an electrodialyzer wherein the effluent is to be separated into concentrated and dilute solutions, the electrodialyzer equipped with an alternate arrangement of cation- and anion-exchange membranes, with concentration and dilution compartments alternately provided between the both ion-exchange membranes, means for conducting the concentrated solution to a step for final disposal, and means for recycling the dilute solution as makeup water to the desulfurization system.

## Claims

### Claim 1

A process for treating effluent from a flue-gas desulfurization system wherein flue gas containing sulfur oxides gas is brought into contact with limestone or hydrated lime slurry and the sulfur oxides gas is thereby absorbed and removed and then fixed and separated as gypsum, which process comprises filtering the liquid to free it from gypsum/coal fly ash therein to produce a filtrate,
transferring the filtrate to an electrodialyzer wherein cation-exchange membranes and univalent anion-exchange membranes are arranged so as to have at least two of either said cation-exchange membranes or anion-exchange membranes side-by-side directly parallel to each other, concentrating chloride ions in the solution therein by dialysis, further concentrating the solution by evaporation in an evaporator, kneading the concentrated solution with cement or a mixture of cement and coal ash to produce an inert solid matter, and thereafter disposing of the solid matter as landfill.

### Claim 2

In a process for treating an effluent from a flue-gas desulfurization system wherein flue gas containing sulfur oxides and chlorine values is contacted with limestone or a hydrated lime slurry, the sulfur oxide gas is absorbed and fixed in the slurry as gypsum and the gypsum is separated leaving a liquid containing chloride ions, the improvement which comprises filtering the liquid containing the chloride ions from gypsum/coal fly ash containing therein by filtration, subjecting the filtrate to electrodialysis in an electrodialyzer comprising concentration compartments and dilution compartments formed by cation-exchange membranes and univalent anion-exchange membrane to produce a concentrated chloride ion containing solution in the dilution compartments, wherein at least two of either of said cation-exchange membranes or anion-exchange membrane are positioned side-by-side and directly parallel to each other, subjecting the concentrated chloride ion containing solution to further concentration by evaporation in an evaporator, kneading the thus further concentrated solution with cement or a mixture of cement and coal ash to form a solid, thereafter disposing of the solid, and recycling the dilute chloride ion containing solution as make up water for the slurry.

### Claim 3

A method for treating desulfurized wastewater comprising performing electrodialysis thereof using an electrodialysis apparatus having ion exchange membranes adjacent to positive and negative pole plates for forming an electric field necessary for electrophoresis, formed by sequentially arranging, in this order between an anode plate and a cathode plate; first, second and third cathode exchange membranes, a first anion exchange membrane, a first additional cathode exchange membrane, a second anion exchange membrane, a second additional cathode exchange membrane, a third anode exchange membrane, and fourth and fifth cathode exchange membranes, the first and fifth cathode exchange membranes being adjacent to the respective anode and cathode plates, by passing a polar liquid between the anode plate and the adjacent first cation exchange membrane and between the cathode plate and the adjacently disposed fifth cathode plate, passing a dilute solution between the first and second, second and third cation exchange membranes, and fourth and fifth cation exchange membranes, between the first anion exchange membrane and the first additional cation exchange membrane, between the second anion exchange membrane and second additional cation membrane and between the first anion exchange resin and the fourth cation exchange membrane, and passing a concentrated solution between the third cation exchange membrane and the first anion exchange membrane and between the second additional cation exchange membrane and the third anion exchange membrane.

### Claim 4

A method for cleaning a desulfurized wastewater treating electrodialysis apparatus having ion exchange membranes adjacent to positive and negative pole plates for forming an electric field necessary for electrophoresis, formed by sequentially arranging, in this order between an anode plate and a cathode plate; first, second and third cathode exchange membranes, a first anion exchange membrane, a first additional cathode exchange membrane, a second anion exchange membrane, a second additional cathode exchange membrane, a third anode exchange membrane, and fourth and fifth cathode exchange membranes, the first and fifth cathode exchange membranes being adjacent to the respective anode and cathode plates, comprising changing the polarity of the anode plate to the cathode, changing the polarity of the cathode plate to anode, and passing sodium chloride solution between the respective cathode plate, anode plate, cation and anion exchange resins.