# US 5,704,538 A · Method for joining rhenium to columbium > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 5,704,538 A - Document ID: US5704538A - Status: Granted - Kind: A - Application number: 08/655,036 - Filed: 1996-05-29 - Granted: 1998-01-06 - Earliest claimed: 1996-05-29 - Assignees: AlliedSignal Inc. - Inventors: Donald Lee Mittendorf - Web page: https://patentgrep.com/patent/US5704538A ## CPC - B23K 35/3013: {Au as the principal constituent} - B23K 35/005: {at least one of the workpieces being of a refractory metal} - B23K 35/007: {at least one of the workpieces being of copper or another noble metal} - Y10T 428/12771: Transition metal-base component - Y10T 428/12819: Group VB metal-base component - Y10T 428/12875: Platinum group metal-base component - Y10T 428/12889: Au-base component - B23K: SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM - Y10T: TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION ## Abstract A method for joining rhenium to columbium and columbium based alloys that minimizes the formation of brittle intermetallics. First, a layer of ruthenium is applied to both the rhenium and columbium and then heated until the ruthenium diffuses with the rhenium and columbium respectively. A braze foil is place between the two outer ruthenium layers and the assembly is heated in a range of 50.degree. C. to 100.degree. C. above the liquidus of the braze, thereby joining the rhenium to the columbium. Alternatively, the ruthenium coated surfaces are placed in contact and diffused together under a compressive load of at least 1000 psi. ## Claims ### Claim 1 A method for joining rhenium to columbium and columbium based alloys, comprising the following steps: (a) providing a first article having at least a portion of rhenium; (b) providing a second article having at least a portion taken from the group consisting of columbium and columbium based alloys; (c) applying a first layer of ruthenium to said rhenium portion; (d) applying a second layer of ruthenium to said columbium portion; (e) heating said ruthenium layered rhenium portion to form a mixed layer of ruthenium and rhenium therebetween; (f) heating said ruthenium layered columbium portion to form a mixed layer of ruthenium and columbium therebetween; (g) providing a braze foil; (h) placing said ruthenium layered rhenium portion and said ruthenium layered columbium portion in contact with opposite sides of said braze foil; (i) heating the assembly of the previous step to a temperature above the liquidus of said braze; and (j) cooling the assembly of step (i) to ambient temperature. ### Claim 2 (depends on 1) The method of claim 1 wherein each of said steps of applying a layer of ruthenium is electroplating. ### Claim 3 (depends on 1) The method of claim 1 wherein each of said ruthenium layers is between 0.001 inches to 0.003 inches thick. ### Claim 4 (depends on 1) The method of claim 1 further including the step of holding the temperature in step (i) constant for 5 to 20 minutes. ### Claim 5 (depends on 4) The method of claim 4 wherein step (e) is at a temperature range between 1200.degree. C. and 1900.degree. C. for a period of 1 to 4 hours. ### Claim 6 (depends on 5) The method of claim 5 wherein step (f) is at a temperature range between 1560.degree. C. and 1770.degree. C. for 1 to 4 hours. ### Claim 7 (depends on 6) The method of claim 6 wherein the heating in steps (e), (f), and (i) occur in a vacuum. ### Claim 8 (depends on 6) The method of claim 6 further including after step (b) the step of cleaning said rhenium and columbium portions in a nonpolar solvent. ### Claim 9 (depends on 1) The method of claim 1 further including after step (h) the step of applying a compressive load to the assembly of step (h). ### Claim 10 (depends on 9) The method of claim 9 wherein said compressive load is in the range of 50 psi to 200 psi. ### Claim 11 A method for joining rhenium to columbium and columbium based alloys, comprising the following steps: (a) providing a first article having at least a portion of rhenium; (b) providing a second article having at least a portion taken from the group consisting of columbium and columbium based alloys; (c) applying a first layer of ruthenium to said rhenium portion; (d) applying a second layer of ruthenium to said columbium portion; (e) placing said first ruthenium layer in contact with said second ruthenium layer and applying a compressive load thereto; (f) heating the assembly of step (e) until said rhenium diffuses with said first ruthenium layer, said first ruthenium layer diffuses with said second ruthenium layer, and said second ruthenium layer diffuses with said columbium; and (g) releasing said compressive load and cooling said assembly to ambient temperature. ### Claim 12 (depends on 11) The method of claim 11 wherein step (f) is at a temperature in the range of 1750.degree. C. to 1900.degree. C. for at least one hour. ### Claim 13 (depends on 12) The method of claim 12 wherein the compressive load of step (e) is at least 1000 psi. ### Claim 14 A method for joining rhenium to columbium and columbium based alloys, comprising the following steps: (a) providing a first article having at least a portion of rhenium; (b) providing a second article having at least a portion taken from the group consisting of columbium and columbium based alloys; (c) applying a first layer of ruthenium to said rhenium portion; (d) applying a second layer of ruthenium to said columbium portion; and (e) bonding said first layer of ruthenium to said second layer of ruthenium .