# US 5,704,228 A · Process and device for the evaporation of a liquid flow > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 5,704,228 A - Document ID: US5704228A - Status: Granted - Kind: A - Application number: 08/616,214 - Filed: 1996-03-15 - Granted: 1998-01-06 - Earliest claimed: 1995-03-15 - Assignees: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude - Inventors: Jean-Pierre Tranier - Web page: https://patentgrep.com/patent/US5704228A ## CPC - F25J 3/04466: {for producing oxygen as a mixing column overhead gas by mixing gaseous air feed and liquid oxygen} - F25J 3/0409: {of oxygen} - F25J 3/04303: {Lachmann expansion, i.e. expanded into oxygen producing or low pressure column} - F25J 3/0446: {using the heat generated by mixing two different phases} - F25J 2200/06: in a classical double column flow-sheet, i.e. with thermal coupling by a main reboiler-condenser in the bottom of low pressure respectively top of high pressure column - F25J 2200/34: using a side column fed by a stream from the low pressure column - F25J 2200/54: in the low pressure column of a double pressure main column system - F25J 2235/50: the fluid being oxygen - Y10S 62/903: Heat exchange structure - Y10S 62/905: Column - Y10S 62/924: Argon - F25J: LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS {OR LIQUEFIED GASEOUS} MIXTURES BY PRESSURE AND COLD TREATMENT {OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE (cryogenic pumps F04B37/08; gas storage vessels, gas holders F17; filing vessels with, or discharging from vessels, compressed, liquefied or solidified gases F17C; refrigeration machines, plants, or systems F25B)} - Y10S: TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS ## Abstract In a process for liquid evaporation by heat exchange with a gas which condenses, the pressure of the liquid to be evaporated is reduced and it is enriched in a constituent which has little volatility after evaporation. According to an alternative form, the gas to be condensed can be enriched in the constituent which has little volatility. ## Claims ### Claim 1 Process for the evaporation of a liquid flow by heat exchange with a gas flow which condenses, each of the two flows comprising at least two constituents, the process comprising: evaporating the liquid flow by heat exchange with the gas flow so as to obtain an evaporated liquid mixture; enriching the evaporated liquid mixture in less volatile constituent by conveying it into a mixing column, and by exchange of heat with the gas flow. ### Claim 2 (depends on 1) Process according to claim 1, wherein the gas flow is enriched in less volatile constituent before condensation by heat exchange with the liquid flow. ### Claim 3 (depends on 1) Process according to claim 1, wherein the less volatile constituent is oxygen and another, more volatile constituent is nitrogen. ### Claim 4 (depends on 1) Process according to claim 1, wherein the evaporated liquid mixture is enriched in less volatile constituent by conveying it into a vessel of a mixing column, said mixing column having a head which is fed by a liquid which is richer in less volatile constituent than the evaporated liquid mixture to be enriched. ### Claim 5 (depends on 4) Process according to claim 4, wherein impure oxygen is produced, an oxygen-rich liquid fraction is evaporated to produce an evaporated liquid fraction which is conveyed into the mixing column where the evaporated liquid fraction and a liquid oxygen flow drawn off from a vessel of a low-pressure column of a double column, with a purity slightly greater than the impure oxygen in vapor form, are brought in contact, for exchange of heat and of material, and impure oxygen is drawn off at the head of the mixing column. ### Claim 6 (depends on 5) Process according to claim 5, wherein liquid drawn off from the vessel of the mixing column is conveyed into the low-pressure column. ### Claim 7 Device for the evaporation of a liquid flow by heat exchange with a gas flow, each of the two flows comprising at least two constituents, the device comprising: evaporating means for exchanging heat between the gas flow and the liquid flow so as to obtain an evaporated liquid mixture, mixing column means, positioned downstream of the evaporating means, for enriching in less volatile constituent the evaporated liquid mixture. ### Claim 8 (depends on 7) Device according to claim 7, further comprising means for enriching in less volatile constituent the gas flow upstream of the evaporating means. ### Claim 9 (depends on 8) Device according to claim 8, wherein the mixing column means are fed by a fluid which is richer in less volatile constituent than the evaporated liquid mixture to be enriched. ### Claim 10 (depends on 9) Device according to claim 9, wherein the evaporating means comprise an exchanger situated in a vessel of the mixing column. ### Claim 11 Process for the evaporation of a liquid flow heat exchange with a gas flow which condenses, each of the two flows comprising at least two constituents, the process comprising: enriching the gas flow in less volatile constituent before condensing the gas flow by heat exchange with the liquid flow so as to obtain a gaseous fluid enriched in less volatile constituent, the less volatile constituent being oxygen and the other, more volatile constituent being nitrogen, the gas flow being enriched in less volatile constituent by conveying the gas flow into the bottom of a mixing column fed at the head by a liquid which is richer in less volatile constituent than the gas flow to be enriched, wherein the gaseous fluid enriched in less volatile constituent condenses in a vessel evaporator of a low-pressure column of a medium-pressure/low-pressure double column, said low-pressure column containing an intermediate evaporator which condenses the head nitrogen of the medium-pressure column, said oxygen being evaporated by heat exchange with a vapor, is richer in oxygen than air, drawn off from the head of a mixing column where a fraction of the air to be distilled and the liquid fraction which is richer in oxygen originating from an intermediate level of the low-pressure column are brought into contact for exchange of heat and material; and conveying liquid produced in the vessel of the mixing column and the condensed vapor into the low-pressure column. ### Claim 12 (depends on 11) Process according to claim 11, wherein the liquid fraction is part of the rich liquid originating from the medium-pressure column. ### Claim 13 (depends on 12) Process according to claim 12, wherein the liquid fraction is a mixture of rich liquid and of liquid drawn off from a vessel tray of the mixing column. ### Claim 14 Device for the evaporation of a liquid flow by heat exchange with a gas flow, each of the two flows comprising at least two constituents, the device comprising: evaporator means for exchanging heat between the gas flow and the liquid flow so as to obtain an evaporated liquid mixture, and mixing column means, positioned downstream of evaporator means, for enriching in less volatile constituent the evaporated liquid mixture, said evaporator means comprising an exchanger situated at the bottom of a low-pressure column. ### Claim 15 (depends on 14) Device according to claim 14, further comprising means for enriching in less volatile constituent the gas flow upstream of the evaporator means. ### Claim 16 (depends on 14) Device according to claim 14, wherein the mixing column means are fed by a fluid which is richer in volatile constituent than the evaporated liquid mixture. ### Claim 17 (depends on 7) Plant for the separation of a gas mixture by distillation containing a device according to claim 7, wherein the liquid flow is a separation product and the gas flow is the gas mixture to be separated. ### Claim 18 (depends on 17) Plant according to claim 17, wherein the liquid flow is a pressurized flow of at least one constituent of air and the gas flow is air. ### Claim 19 (depends on 14) Plant for the separation of a gas mixture by distillation containing a device according to claim 14, wherein the liquid flow is a separation product and the gas flow is the gas mixture to be separated.