# US 5,703,031 A · Granular bleaching compositions

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- Number: US 5,703,031 A
- Document ID: US5703031A
- Status: Granted
- Kind: A
- Application number: 08/614,445
- Filed: 1996-03-12
- Granted: 1997-12-30
- Earliest claimed: 1994-03-14
- Assignees: The Procter & Gamble Company
- Inventors: Marina Trani; Guiseppe Trigiante; Ellie Marie Frasier
- Web page: https://patentgrep.com/patent/US5703031A

## CPC

- C11D 3/394: {Organic compounds}
- C11D 3/08: Silicates
- C11D 3/1273: {Crystalline layered silicates of type NaMeSixO2x+1YH2O}
- C11D 3/33: Amino carboxylic acids
- C11D 3/3942: {Inorganic per-compounds (C11D3/3902 takes precedence)}
- C11D: DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL

## Abstract

A granular laundry composition is disclosed which comprises a source of available-oxygen, a stabilizer like chelant together with an alkali metal salt of silicate. Such compositions allow to produced wash solutions wherein the bleaching activity is retained upon longer periods of time. Optionally said compositions may further comprise a soil suspender and be formulated so as to allow to keep the pH of the wash solution below 9.5 and thereby boost the cleaning performance on particulate soil (clay).

## Claims

### Claim 1

A granular composition comprising from about 10% to about 80% by weight of a source of available oxygen, from about 0.01% to about 5% by weight of diethylene triamino pentacetic acid, and from about 2% to about 7% by weight of an alkali metal salt of silicate which is sodium crystalline layered silicate having the formula NaMSi.sub.x O.sub.2x+1 .multidot.yH.sub.2 O wherein M is sodium or hydrogen, x is a number from about 1.9 to about 4 and y is a number from 0 to about 20, wherein said source of available oxygen is a percarbonate compound.

### Claim 2 (depends on 1)

A composition according to claim 1 which comprises from about 15% to about 50% by weight of the total composition of said source of available oxygen.

### Claim 3 (depends on 1)

A composition according to claim 1 wherein said composition further comprises magnesium sulfate.

### Claim 4 (depends on 1)

A composition according to claim 1 wherein said composition further comprises up to about 20% by weight of the total composition of a soil suspender, or mixtures thereof.

### Claim 5 (depends on 1)

A composition according to claim 1 wherein said composition further comprises from about 3% to about 15% by weight of the total composition of a soil suspender, or mixtures thereof.

### Claim 6 (depends on 1)

A composition according to claim 1 wherein said composition further comprises an acidifying system, said acidifying system preferably comprising citric acid and/or sodium citrate and optionally bicarbonate.

### Claim 7 (depends on 6)

A composition according to claim 6 wherein the weight ratio of the source of available oxygen, alkali metal salt of silicate together with carbonate, if present, to said acidifying system is inferior to about 4.

### Claim 8 (depends on 1)

A composition according to claim 1 wherein said composition further comprises a bleach activator or mixtures thereof.

### Claim 9 (depends on 8)

A composition according to claim 8 wherein said composition comprises n-nonanoyloxybenzenesulphonate and a second bleach activator, said second bleach activator being selected from the group of tetracetyl ethylene diamine, acetyl triethyl citrate, acetyl caprolactam, benzoyl caprolactam or mixtures thereof, preferably said composition comprises more than 3% by weight of the total composition of n-nonanoyloxybenzenesulphonate and more than about 0.5% by weight of the total composition of said second bleach activator.