# US 5,702,875 A · Weakly alkaline ascorbic acid developing composition, processing kit and method using same

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- Number: US 5,702,875 A
- Document ID: US5702875A
- Status: Granted
- Kind: A
- Application number: 08/674,497
- Filed: 1996-06-28
- Granted: 1997-12-30
- Earliest claimed: 1996-06-28
- Assignees: Eastman Kodak Company
- Inventors: Robert John Opitz; Silvia Zawadzki
- Web page: https://patentgrep.com/patent/US5702875A

## CPC

- G03C 5/264: {Supplying of photographic processing chemicals; Preparation or packaging thereof}
- G03C 5/30: Developers
- G03C 5/265: {of powders, granulates, tablets (G03C5/267 takes precedence)}
- G03C 5/266: {of solutions or concentrates (G03C5/267 takes precedence)}
- G03C 5/31: Regeneration; Replenishers
- G03C 2005/3007: {Ascorbic acid}
- G03C 2200/44: pH value
- G03C: PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES (for photomechanical purposes G03F); PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY (photographic processes characterised by the use or manipulation of apparatus classifiable per se in subclass G03B, see G03B; photomechanical production of textured or patterned surfaces G03F; electrophotography, magnetography G03G)

## Abstract

A black-and-white developing composition includes as ascorbic acid developing agent, an auxiliary super-additive developing agent, borate buffer and a preservative. The composition pH is from 7 but less than 9. The composition can be formulated from two separately packaged parts that may be in dry or liquid form. The borate buffer is present to maintain the desired pH, and the two developing agents are present in desired molar ratios for optimal developing activity. Improved photographic properties are obtained while avoiding the use of environmentally unfriendly dihydroxybenzenes.

## Claims

### Claim 1

An aqueous black-and-white developing composition that is free of dihydroxybenzene developing agents, said developing composition having a pH of greater than 7 but less than 9, and comprising:
an ascorbic acid developing agent,
an auxiliary super-additive developing agent,
borate as the sole buffer in an amount of at least 0,001 mol/l, and
a preservative,
wherein the molar ratio of said ascorbic acid developing agent to said auxiliary super-additive developing agent is at least about 10:1.

### Claim 2 (depends on 1)

The composition of claim 1 having a pH of from 8 to 8.5.

### Claim 3 (depends on 2)

The composition of claim 2 having a pH of from 8.1 to 8.4.

### Claim 4 (depends on 1)

The composition of claim 1 wherein said ascorbic acid developing agent is D- or L-ascorbic acid, isoascorbic acid, an alkali metal salt of any of these compounds, or any mixture thereof.

### Claim 5 (depends on 4)

The composition of claim 4 wherein said ascorbic acid developing agent is sodium ascorbate or sodium isoascorbate.

### Claim 6 (depends on 1)

The composition of claim 1 wherein said auxiliary super-additive developing agent is 4-hydroxymethyl-4-methyl-1-phenyl-3-pyrazolidone, 1-phenyl-3-pyrazolidone, 4,4-dimethyl-1-phenyl-3-pyrazolidone, or 1-phenyl-4,4-dihydroxymethyl-3-pyrazolidone.

### Claim 7 (depends on 1)

The composition of claim 1 wherein said ascorbic acid developing agent is present in an amount of from about 0.01 to about 0.1 mol/l, said auxiliary super-additive developing agent is present in an amount of from about 2.5.times.10.sup.-4 to about 2.5.times.10.sup.-2 mol/l, said borate buffer is present in an amount of from about 0.001 to about 0.2 mol/l, and said preservative is present in an amount of from about 0.4 to about 1.6 mol/l,
provided that the molar ratio of said ascorbic acid developing agent to said auxiliary super-additive developing agent is from about 20:1 to about 50:1.

### Claim 8 (depends on 1)

The composition of claim 1 wherein said preservative is sulfite ion.