# US 5,702,842 A · Process for charging and discharging zinc/bromine batteries

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- Number: US 5,702,842 A
- Document ID: US5702842A
- Status: Granted
- Kind: A
- Application number: 08/464,620
- Filed: 1995-06-23
- Granted: 1997-12-30
- Earliest claimed: 1992-12-23
- Assignees: Elin Energieanwendung Gesellschaft M.B.H.
- Inventors: Gerd Tomazic
- Web page: https://patentgrep.com/patent/US5702842A

## CPC

- H01M 50/77: with external circulating path
- H01M 12/085: {Zinc-halogen cells or batteries}
- H01M 10/42: Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells (H01M10/60 takes precedence)
- Y02E 60/10: Energy storage using batteries
- H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

## Abstract

A process for charging and discharging zinc/bromine batteries with a plurality of anode and cathode chambers into and from which anolyte or catholyte fluids are fed and drained. Metallic zinc is deposited on the anode and atomic and/or molecular bromine is deposited at the cathode, and bromine is bonded in an only slightly water soluble complex with a complex-forming agent from the aqueous phase. The anolyte and/or catholyte fluids are circulated periodically. The oleophilic cathode phase is separated from the hydrophilic cathode phase. Only the aqueous phase of the catholyte is circulated through the cathode chambers, and the times at which the fluid is circulated is dependent upon the temperature of the anolyte in the anode chambers.

## Claims

### Claim 1

A process for charging and discharging zinc/bromine batteries with a plurality of bipolar electrodes including a positive electrode and a negative electrode, a plurality of cathode spaces associated with the positive electrode and a plurality of anode spaces associated with the negative electrode, an anolyte reservoir associated with the negative electrode for supplying a circulating anolyte fluid, a cathodelyte reservoir associated with the positive electrode for supplying a circulating cathodelyte fluid, said process comprising:
during a charging phase, precipitating out metallic zinc at the negative electrode;
depositing at least one of atomic and molecular bromine onto the positive electrode;
binding bromine from an aqueous phase in a poorly water soluble complex with a complex former,
wherein the anode spaces and the cathode spaces communicate via diaphragms,
during a charging and a discharging phase, circulating at least one of the fluid and fluid;
separating, within the catholyte reservoir, an oleophilic cathotyte phase from a hydrophilic catholyte phase; and
after supplying or removing electrical energy from the zinc-bromine battery, passing only the aqueous phase of the catholyte fluid through the cathode spaces and thereafter effecting a temporary interruption and intermittently circulating the aqueous phase through the cathode spaces,
wherein the circulation of the aqueous phase is initiated as a function of temperature of the anolyte fluid in the anode space.

### Claim 2 (depends on 1)

The process according to claim 1, characterized in that a temporary pause is provided between the draining of current and the next circulation of the aqueous phase of the electrolyte.

### Claim 3 (depends on 1)

The process according to claim 1, characterized in that a circulation of the aqueous phase of the electrolyte takes place at least twice.

### Claim 4 (depends on 1)

The process according to claim 1, characterized in that the temporary pauses of the diversion of the aqueous phase are from 10-30 times, as long as the circulation time.

### Claim 5 (depends on 1)

The process according to claim 1, characterized in that the ciculation of the aqueous phase is switched at least one of on and off by means of a time switch element.

### Claim 6 (depends on 1)

The process according to claim 1, characterized in that the circulation of the aqueous phase of the electrolyte after the draining or supply of electrical energy is carried out at a low flow velocity, of approximately 1/3 to 1/2 the flow velocity of the circulation done during at least one of charging and discharging.

### Claim 7 (depends on 1)

The process according to claim 1, characterized in that the anolyte is circulated at the same time as the aqueous phase of the catholyte fluid.

### Claim 8 (depends on 1)

The process according to claim 1, said circulating at least one of the anolyte and the catholyte fluid comprising intermittent circulation.

### Claim 9 (depends on 1)

The process according to claim 1, wherein, after the electrical energy is removed or supplied, the circulation of the aqueous phase of the anolyte fluid occurs with a flow velocity less than a flow velocity occurring during at least one of charging and discharging.

### Claim 10 (depends on 9)

The process according to claim 9, the flow velocity of the circulation being between approximately one-third and approximately one-half the flow velocity occurring during at least one of charging and discharging.

### Claim 11 (depends on 9)

The process according to claim 9, the anolyte is circulated concurrently with the aqueous phase of the catholyte fluid.

### Claim 12 (depends on 1)

The process according to claim 1, characterized in that the temporary pauses of the circulation of the aqueous phase are from 15-20 times as long as the circulation time.