# US 5,702,803 A · Electrostatic color imaging paper with an intrinsic release dielectric layer

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- Number: US 5,702,803 A
- Document ID: US5702803A
- Status: Granted
- Kind: A
- Application number: 07/914,807
- Filed: 1992-07-16
- Granted: 1997-12-30
- Earliest claimed: 1992-07-16
- Assignees: Minnesota Mining and Manufacturing Company
- Inventors: John F. Eisele; Valdis Mikelsons; Gaye K. Lehman; Paul J. Wang; Patricia J. A. Brandt
- Web page: https://patentgrep.com/patent/US5702803A

## CPC

- G03G 5/0211: {obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds}
- Y10T 428/24802: Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
- Y10T 428/31663: As siloxane, silicone or silane
- G03G: ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- Y10T: TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION

## Abstract

The invention provides electrographic imaging sheets comprising a substrate carrying a layer of dielectric material which has abhesive properties suitable for the release of a multicolored toner image from the dielectric surface during image transfer, while also having good toning properties during the several development stages of a multicolor toner imaging process.

## Claims

### Claim 1

An electrographic imaging sheet for use with liquid toner developers, said sheet comprising:
a conductive substrate selected from the group consisting of metallized polymer, metal-filled polymer, conductive particle-filled polymer and conductive polymer and, on at least one surface of said substrate,
a layer of dielectric material between 3 and 40 micrometers in thickness, said dielectric material comprising at least one polymer comprising a silicone,
said layer of dielectric having an exposed surface exhibiting dried liquid toner developer release properties characterized by a surface energy value between 14 and 20 dynes/cm.sup.2, said surface energy having no more than 5% of the energy contributed by a polar component of the energy,
said liquid toner developer comprising a hydrocarbon carrier liquid, and said dielectric material being substantially insoluble in said hydrocarbon carrier liquid used in liquid toner developers,
wherein there is no second dielectric layer between said dielectric layer and said substrate.

### Claim 2

An electrographic imaging sheet for use with liquid toner developers, said sheet comprising:
a conductive substrate selected from the group consisting of metallized polymer, metal-filled polymer, conductive particle-filled polymer and conductive polymer and, on at least one surface of said substrate,
a layer of dielectric material between 3 and 40 micrometers in thickness, said dielectric material comprising at least one polymer comprising a silicone,
said layer of dielectric having an exposed surface exhibiting dried liquid toner developer release properties characterized by a surface energy value between 14 and 20 dynes/cm.sup.2, said surface energy having no more than 5% of the energy contributed by a polar component of the energy,
said liquid toner developer comprising a hydrocarbon carrier liquid, and said dielectric material being substantially insoluble in said hydrocarbon carrier liquid used in liquid toner developers,
wherein said dielectric layer comprises a single layer of silicone containing polymer,
wherein there is no second dielectric layer between said dielectric layer and said substrate.

### Claim 3

An electrographic imagine sheet for use with liquid toner developers, said sheet comprising:
a conductive substrate selected from the group consisting of metallized polymer, metal-filled polymer, conductive particle-filled polymer and conductive polymer and, on at least one surface of said substrate,
a layer of dielectric material between 3 and 40 micrometers in thickness, said dielectric material comprising at least one polymer comprising a silicone,
said layer of dielectric having an exposed surface exhibiting dried liquid toner developer release properties characterized by a surface energy value between 14 end 20 dynes/cm.sup.2, said surface energy having no more than 5% of the energy contributed by a polar component of the energy,
said liquid toner developer comprising a hydrocarbon carrier liquid, and said dielectric material being substantially insoluble in said hydrocarbon carrier liquid used in liquid toner developers,
wherein said dielectric material comprises polymeric materials selected from the group consisting of terpolymers of polydimethylsiloxane, methylmethacrylate, and polystyrene, and copolymers of polydimethylsiloxane and methylmethacrylate,
wherein there is no second dielectric layer between said dielectric layer and said substrate.