# US 5,702,557 A · Process for the production of an information carrier > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 5,702,557 A - Document ID: US5702557A - Status: Granted - Kind: A - Application number: 08/611,915 - Filed: 1996-03-06 - Granted: 1997-12-30 - Earliest claimed: 1989-05-16 - Assignees: Ciba Specialty Chemicals Corporation - Inventors: Aloysius Hubertus Manser; Jacques Francois - Web page: https://patentgrep.com/patent/US5702557A ## CPC - B32B 7/04: Interconnection of layers - B32B 27/08: of synthetic resin - B32B 37/12: characterised by using adhesives - B42D 25/00: Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof (printing processes to produce identification or security features B41M3/14) - B42D 25/23: Identity cards - B42D 25/24: Passports - B42D 25/47: using adhesives - B32B 2310/08: by wave energy or particle radiation - B32B 2310/0831: using UV radiation - B32B 2425/00: Cards, e.g. identity cards, credit cards - B32B 2429/00: Carriers for sound or information - B42D 25/45: Associating two or more layers - B42D 25/465: using chemicals or adhesives - B42D 2033/04 - B42D 2033/32 - Y10S 428/916: Fraud or tamper detecting - Y10T 428/24802: Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] - Y10T 428/2481: including layer of mechanically interengaged strands, strand-portions or strand-like strips - Y10T 428/24884: Translucent layer comprises natural oil, wax, resin, gum, glue, gelatin - Y10T 428/24942: including components having same physical characteristic in differing degree - Y10T 428/2982: Particulate matter [e.g., sphere, flake, etc.] - B32B: LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM - B42D: BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS - Y10S: TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS - Y10T: TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION ## Abstract The present invention relates to a process for preparing a laminated structure containing at least a main foil which is substantially impervious to light, B) at least one interlayer, and C) a covering foil which is substantially light-permeable. The layers are bonded together using a UV-curable and/or VIS-curable composition. The interlayer, prior to contact with the curable composition, is substantially impervious to the irradiation necessary for curing the curable composition and becomes transparent when impregnated with the curable composition so as to effect polymerization of multiple layers of curable composition in one irradiation step. The laminated structure is prepared by applying a layer of the curable composition to the main foil A), applying the interlayer B) to the main foil A), applying a further layer of the curable composition to the interlayer B), applying a covering foil C) to the interlayer B), and irradiating the laminated structure so obtained through the covering foil C) with UV- and/or VIS-radiation ## Claims ### Claim 1 A process for the preparation of a laminated structure which is bonded with a UV-curable and/or VIS-curable composition and which contains at least the following layers: A) a main foil which is substantially impervious to light, B) at least one interlayer based on a cohesive film or web of woven or non-woven fibrous material or of compacted hollow beads or flakes of a thermoplastic material which carries on the side with its back to the main foil an information in the form of a colour pattern, and C) a covering foil which is substantially light-permeable, with the proviso that the interlayer, prior to contact with the curable composition, is substantially impervious to the irradiation necessary for curing the curable composition and becomes transparent when impregnated with the curable composition so as to effect polymerization of multiple layers of curable composition in one irradiation step, which comprises the steps: a1) applying a layer of a UV-curable and/or VIS-curable composition to the main foil A), a2) applying the interlayer B) to the main foil A), a3) applying a further layer of a UV-curable and/or VIS-curable composition to the interlayer B), a4) applying a covering foil C) to the interlayer B), and a5) irradiating the laminated structure so obtained through the covering foil C) with UV- and/or VIS-radiation of such a wavelength as to effect complete cure of the curable composition or at least to activate the curable composition so that it may be completely cured in a subsequent heat treatment. ### Claim 2 (depends on 1) A process according to claim 1, wherein the main foil A) consists of a thermoplastic material which is uncoated or is coated on the entire surface, or part of the surface, by vapor-depositing a metal thereon. ### Claim 3 (depends on 2) A process according to claim 2, wherein the thermoplastic material is polyethylene terephthalate or polyvinyl chloride. ### Claim 4 (depends on 1) A process according to claim 1 wherein the covering foil C) consists of polyethylene terephthalate or polyvinyl chloride. ### Claim 5 (depends on 1) A process according to claim 1, wherein the interlayer B) consists of paper which is suitable for ink jet printing or of a thermoplastic material which carries on one side a layer of finely particulate polysilicic acids having a high specific surface area. ### Claim 6 (depends on 1) A process according to claim 1, which comprises the use of a UV-curable adhesive composition based on acrylates and/or methacrylates. ### Claim 7 (depends on 6) A process according to claim 6, wherein the adhesive is curable in the wavelength of 320-450 nm. ### Claim 8 (depends on 6) A process according to claim 6, wherein the adhesive contains an .alpha.-aminoacetophenone derivative as photoinitiator and a thixoanthone derivative as photosensitiser. ### Claim 9 (depends on 1) A process according to claim 1, which comprises the use of a UV-curable adhesive composition containing an oligomeric (meth)acrylate, a monomeric (meth)acrylate and a photoinitiator for said (meth)acrylate. ### Claim 10 (depends on 9) A process according to claim 9, wherein the adhesive also contains a flexibiliser and/or a sensitiser for the photoinitiator. ### Claim 11 A process for the preparation of a laminated structure which is bonded with a UV-curable and/or VIS-curable composition and which contains at least the following layers: A) a main foil which is substantially impervious to light, B) at least one interlayer based on a cohesive film or web of woven or non-woven fibrous material or of compacted hollow beads or flakes of a thermoplastic material which carries on the side with its back to the main foil an information in the form of a colour pattern, and C) a covering foil which is substantially light-permeable, with the proviso that the interlayer, prior to contact with the curable composition, is substantially impervious to the irradiation necessary for curing the curable composition and becomes transparent when impregnated with the curable composition so as to effect polmerization of multiple layers of curable composition in one irradiation step, which comprises the steps: b1) coating the interlayer B) on one side and the covering foil C) with a UV- and/or VIS-curable composition, b2) applying the interlayer B) to foil A) and then applying foil C) to interlayer B), in each case with the curable composition-coated sides towards foil A), and b3) irradiating the laminated structure so obtained through the covering foil C) with UV- and/or VIS-radiation of such a wavelength as to effect complete cure of the curable composition or at least to activate the curable composition so that it may be completely cured in a subsequent heat treatment. ### Claim 12 A process for the preparation of a laminated structure which is bonded with a UV-curable and/or VIS-curable composition and which contains at least the following layers: A) a main foil which is substantially impervious to light, B) at least one interlayer based on a cohesive film or web of woven or non-woven fibrous material or of compacted hollow beads or flakes of a thermoplastic material which carries on the side with its back to the main foil an information in the form of a colour pattern, and C) a covering foil which is substantially light-permeable, with the proviso that the interlayer, prior to contact with the curable composition, is substantially impervious to the irradiation necessary for curing the curable composition and becomes transparent when impregnated with the curable composition so as to effect polymerization of multiple layers of curable composition in one irradiation step, which comprises the steps: c1) impregnating the interlayer B) with a UV- and/or VIS-curable composition, c2) inserting said interlayer between the main foil A) and the covering foil C), and c3) irradiating the laminated structure so obtained through the covering foil C) with UV- and/or VIS-radiation of such a wavelength as to effect complete cure of the curable composition or at least to activate the curable composition so that it may be completely cured in a subsequent heat treatment. ### Claim 13 A process for the preparation of a laminated structure which is bonded with a UV-curable and/or VIS-curable composition and which contains at least the following layers: A) a main foil which is substantially impervious to light, B) at least one interlayer based on a thermoplastic material which carries at least on the side having its back to the main foil a layer of finely particulate, substantially insoluble material and which carries an information in the form of a colour pattern on the side with its back to the main foil, and C) a covering foil which is substantially light-permeable, with the proviso that the interlayer, prior to contact with the curable composition, is substantially impervious to the irradiation necessary for curing the curable composition and becomes transparent when impregnated with the curable composition so as to effect polymerization of multiple layers of curable composition in one irradiation step, which comprises the steps: a1) applying a layer of a UV-curable and/or VIS-curable composition to the main foil A), a2) applying the interlayer B) to the main foil A), a3) applying a further layer of a UV-curable and/or VIS-curable composition to the interlayer B), a4) applying a covering foil C) to the interlayer B), and a5) irradiating the laminated structure so obtained through the covering foil C) with UV- and/or VIS-radiation of such a wavelength as to effect complete cure of the curable composition or at least to activate the curable composition so that it may be completely cured in a subsequent heat treatment. ### Claim 14 A process for the preparation of a laminated structure which is bonded with a UV-curable and/or VIS-curable composition and which contains at least the following layers: A) a main foil which is substantially impervious to light, B) at least one interlayer based on a thermoplastic material which carries at least on the side having its back to the main foil a layer of finely particulate, substantially insoluble material and which carries an information in the form of a colour pattern on the side with its back to the main foil, and C) a covering foil which is substantially light-permeable, with the proviso that the interlayer, prior to contact with the curable composition, is substantially impervious to the irradiation necessary for curing the curable composition and becomes transparent when impregnated with the curable composition so as to effect polymerization of multiple layers of curable composition in one irradiation step, which comprises the steps: b1) coating the interlayer B) on one side and the covering foil C) with a UV- and/or VIS-curable composition, b2) applying the foil B) to foil A) and then applying foil C) to foil B), in each case with the curable composition -coated sides towards foil A), and b3) irradiating the laminated structure so obtained through the covering foil C) with UV- and/or VIS-radiation of such a wavelength as to effect complete cure of the curable composition or at least to activate the curable composition so that it may be completely cured in a subsequent heat treatment. ### Claim 15 A process for the preparation of a laminated structure which is bonded with a UV-curable and/or VIS-curable composition and which contains at least the following layers: A) a main foil which is substantially impervious to light, B) at least one interlayer based on a thermoplastic material which carries at least on the side having its back to the main foil a layer of finely particulate, substantially insoluble material and which carries an information in the form of a colour pattern on the side with its back to the main foil, and C) a covering foil which is substantially light-permeable, with the proviso that the interlayer, prior to contact with the curable composition, is substantially impervious to the irradiation necessary for curing the curable composition and becomes transparent when impregnated with the curable composition so as to effect polymerization of multiple layers of curable composition in one irradiation step, which comprises the steps: c1) impregnating the interlayer B) with a UV- and/or VIS-curable composition, c2) inserting said interlayer between the main foil A) and the covering foil C), and c3) irradiating the laminated structure so obtained through the covering foil C) with UV- and/or VIS-radiation of such a wavelength as to effect complete cure of the curable composition or at least to activate the curable composition so that it may be completely cured in a subsequent heat treatment.