Flaky aluminum oxide and pearlescent pigment, and production thereof

A pearlescent pigment comprising particles of a flaky aluminum oxide containing therein titanium oxide in an amount of about 0.1-4 wt. %, based on the aluminum oxide, and a metal oxide coating formed on the surface of said particles.

A paint, plastic, ink, cosmetic, or glaze composition comprising a flaky aluminum oxide containing therein titanium oxide in an amount of about 0.1-4 wt. %, based on the aluminum oxide.

A paint, plastic, ink, cosmetic, or glaze composition comprising a pearlescent pigment which comprises a flaky aluminum oxide containing therein titanium oxide in an amount of about 0.1-4 wt. %, based on the aluminum oxide, and containing thereon a layer of a metal oxide.

A process for producing flaky aluminum oxide, comprising preparing (a) an aqueous solution of at least one water-soluble aluminum salt and at least one titanium salt and (b) an aqueous solution of at least one alkali carbonate in an amount approximately equivalent to said water-soluble aluminum salt and titanium salt in said aqueous solution (a), uniformly dissolving at least one alkali metal sulfate and phosphoric acid or a phosphate in either aqueous solution (a) or aqueous solution (b), mixing said aqueous solutions (a) and (b) to give a suspension or gel containing hydrolyzates, drying the suspension or gel by evaporation, and molten-salt treating the dried product by heating to give a solid product, and optionally water washing, filtering, and drying.

A process for producing flaky aluminum oxide, comprising adding dropwise a solution of at least one water-soluble aluminum salt and a solution of at least one alkali carbonate simultaneously to water in such a way that the former is approximately chemically equivalent to the latter, thereby forming a suspension of hydrated aluminum hydroxide, adding said suspension or solids filtered out from said suspension to an aqueous solution of at least one alkali metal sulfate, adding to the resulting solution a titanium salt and phosphoric acid or a phosphate to give a suspension or gel containing hydrolyzates, drying the suspension or gel by evaporation, and molten-salt treating the dried product to give a solid product, and optionally water washing, filtering, and drying.

Flaky aluminum oxide produced by a process comprising preparing (a) an aqueous solution of at least one water-soluble aluminum salt and at least one titanium salt and (b) an aqueous solution of at least one alkali carbonate in an amount approximately equivalent to said water-soluble aluminum salt and titanium salt in said aqueous solution (a), uniformly dissolving at least one alkali metal sulfate and phosphoric acid or a phosphate in either aqueous solution (a) or aqueous solution (b), mixing said aqueous solutions (a) and (b) to give a suspension or gel containing hydrolyzates, drying the suspension or gel by evaporation, and molten-salt treating the dried product by heating to give a solid product, and optionally water washing, filtering, and drying.

Flaky aluminum oxide produced by a process comprising adding a dropwise solution of at least one water-soluble aluminum salt and a solution of at least one alkali carbonate simultaneously to water in such a way that the former is approximately chemically equivalent to the latter, thereby forming a suspension of hydrated aluminum hydroxide, adding said suspension or solids filtered out from said suspension to an aqueous solution of at least one alkali metal sulfate, adding to the resulting solution a titanium salt and phosphoric acid or a phosphate to give a suspension or gel containing hydrolyzates, drying the suspension or gel by evaporation, and molten-salt treating the dried product to give a solid product, and optionally water washing, filtering, and drying.