# US 5,702,490 A · Water repellent treatment of leather and skins with polysiloxanes functionalized with carboxyl groups in a comb-like manner > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 5,702,490 A - Document ID: US5702490A - Status: Granted - Kind: A - Application number: 08/687,447 - Filed: 1996-08-15 - Granted: 1997-12-30 - Earliest claimed: 1994-02-16 - Assignees: BASF SE - Inventors: Michael Kneip; Peter Danisch - Web page: https://patentgrep.com/patent/US5702490A ## CPC - C14C 9/00: Impregnating leather for preserving, waterproofing, making resistant to heat or similar purposes - C08L 83/06: containing silicon bound to oxygen-containing groups (C08L83/12 takes precedence) - C08L 83/08: containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen - C14C: CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING (bleaching of leather or furs D06L; dyeing of leather or furs D06P) - C08L: COMPOSITIONS OF MACROMOLECULAR COMPOUNDS (compositions based on polymerisable monomers C08F, C08G; artificial filaments or fibres D01F; textile treating compositions D06) ## Abstract Leather and skins are water repellent in aqueous emulsion in the presence of emulsifiers with polysiloxanes which are functionalized with carboxyl groups in a comb-like manner and in which the carboxyl groups are bonded to the polymer main chain via spacer groups in the form of linear or branched C.sub.2 -C.sub.40 -alkylene groups which may be interrupted by up to 8 non-neighboring oxygen atoms or groups of the formula --NR.sup.1 --, CO-- ›sic! or --CO--NR.sup.1 -- and in addition may carry up to 5 carboxyl groups or carboxamido groups of the formula --CO--NR.sup.1 R.sup.2 --, where R.sup.1 and R.sup.2 are each hydrogen or C.sub.1 -C.sub.4 -alkyl, the spacer groups being bonded to the polymer main chain via a direct bond or via an oxygen atom or a group of the formula --NR.sup.1 --, --CO--, --CO--NR.sup.1 -- or --CO--O--. ## Claims ### Claim 1 A process for the water repellant treatment of leather and skins, comprising contacting leather or a skin with carboxyl-containing polysiloxanes in an aqueous emulsion in the presence of emulsifiers, wherein said polysiloxanes have a polymer main chain which is functionalized with carboxyl groups, wherein the carboxyl groups are bonded to the polymer main chain in the form as teeth in a comb via spacer groups in the form of linear or branched ›C.sub.2 --! C.sub.5 -C.sub.40 -alkylene groups optionally interrupted by up to 8 non-neighboring oxygen atoms or groups of the formula --NR.sup.1 --, --CO-- or --CO--NR.sup.1 -- and in addition optionally carry up to 5 carboxyl groups or carboxamido groups of the formula --CO--NR.sup.1 R.sup.2, where R.sup.1 and R.sup.2 are each hydrogen or C.sub.1 -C.sub.4 -alkyl, the spacer groups being bonded to the polymer main chain via a direct bond or via an oxygen atom or a group of the formula --NR.sup.1 --, --CO--, --CO--NR.sup.1 -- or --CO--O--. ### Claim 2 (depends on 1) A process for the water repellent treatment of leather and skins as claimed in claim 1, wherein said aqueous emulsion further contains paraffins, liquid paraffins or white oils, mineral oils, natural fats or natural oils or synthetic or natural waxes. ### Claim 3 (depends on 1) A process for the water repellent treatment of leather and skins as claimed in claim 1, wherein said polysiloxanes have a structure of the formula I ##STR3## where the radicals R.sup.3 are identical or different and, independently of one another, are each hydrogen, hydroxyl, C.sub.1 -C.sub.4 -alkyl, phenyl, C.sub.1 -C.sub.4 -alkoxy, amino, mono-C.sub.1 -C.sub.4 -alkylamino, di-C.sub.1 -C.sub.4 -alkylamino, chlorine or fluorine, optionally R.sup.3 at each of the chain ends is a group --Z--A--COOH, A is linear or branched C.sub.5 -C.sub.25 -alkylene, Z is a direct bond, an oxygen atom or a group of the formula --NR.sup.1 --, --CO--, --CO--NR.sup.1 -- or --CO--O--, where R.sup.1 is hydrogen or C.sub.1 -C.sub.4 -alkyl, and the sum of x and y is from 50 to 200. ### Claim 4 (depends on 3, 8) A process for the water repellent treatment of leather and skins as claimed in claim 3, wherein the spacer groups are bonded to the polymer main chain via an oxygen atom or a group of the formula --NR.sup.1 --, --CO--, --CONR.sup.1 or --CO--O--, wherein R.sup.1 is as defined in claim 8. ### Claim 5 (depends on 1) A process for the water repellent treatment of leather and skins as claimed in claim 1, wherein the alkylene groups of the spacer groups are C.sub.8 -C.sub.40 -alkylene groups. ### Claim 6 (depends on 1) A process for the water repellent treatment of leather and skins as claimed in claim 1, wherein the spacer groups are bonded to the polymer main chain via an oxygen atom or a group of the formula --NR.sup.1 --, --CO--, --CONR.sup.1 or --CO--O--, wherein R.sup.1 is as defined in claim 1. ### Claim 7 An agent for the water repellent treatment of leather and skins in the form of an aqueous emulsion, which comprises polysiloxanes having a polymer main chain which is functionalized with carboxyl groups, wherein the carboxyl groups are bonded to the polymer main chain in the form as teeth in a comb via spacer groups in the form of linear or branched C.sub.2 -C.sub.40 -alkylene groups optionally interrupted by up to 8 non-neighboring oxygen atoms or groups of the formula --NR.sup.1 --, --CO-- or --CO--NR.sup.1 -- and in addition optionally carry up to 5 carboxyl groups or carboxamido groups of the formula --CO--NR.sup.1 R.sup.2 --, where R.sup.1 and R.sup.2 are each hydrogen or C.sub.1 -C.sub.4 -alkyl, the spacer groups being bonded to the polymer main chain via an oxygen atom or a group of the formula --NR.sup.1 --, --CO--, --CO--NR.sup.1 -- or --CO--O--, wherein R.sup.1 is as above defined. ### Claim 8 (depends on 7) An agent for the water repellent treatment of leather and skins in the form of an aqueous emulsion as claimed in claim 7, containing from 3 to 90% by weight of said polysiloxanes functionalized with carboxyl groups, from 3 to 30% by weight of emulsifiers and from 0 to 50% by weight of paraffins, liquid paraffins or white oils, mineral oils, natural fats or natural oils or synthetic or natural waxes.