# US 5,701,761 A · Method and installation for the liquefaction of natural gas

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- Number: US 5,701,761 A
- Document ID: US5701761A
- Status: Granted
- Kind: A
- Application number: 08/652,527
- Filed: 1996-06-03
- Granted: 1997-12-30
- Earliest claimed: 1994-10-05
- Assignees: Institut Francais du Petrole
- Inventors: Isabelle Prevost; Alexandre Rojey
- Web page: https://patentgrep.com/patent/US5701761A

## CPC

- F25J 3/0257: {separation of nitrogen (from air F25J3/04, production of nitrogen in general C01B21/00)}
- F25J 1/0022: {Hydrocarbons, e.g. natural gas}
- F25J 1/004: {by flash gas recovery (F25J1/0267 takes precedence)}
- F25J 1/0042: {by liquid expansion with extraction of work}
- F25J 1/005: {by expansion of a gaseous refrigerant stream with extraction of work}
- F25J 1/0052: {by vaporising a liquid refrigerant stream}
- F25J 1/0055: {originating from an incorporated cascade}
- F25J 1/0092: {Mixtures of hydrocarbons comprising possibly also minor amounts of nitrogen}
- F25J 1/0212: {as a single flow MCR cycle}
- F25J 1/0214: {as a dual level refrigeration cascade with at least one MCR cycle}
- F25J 1/0264: {Arrangement of heat exchanger cores in parallel with different functions, e.g. different cooling streams (F25J1/0272 takes precedence)}
- F25J 3/0209: {Natural gas or substitute natural gas}
- F25J 3/0233: {separation of CnHm with 1 carbon atom or more}
- F25J 2200/02: in a single pressure main column system
- F25J 2200/70: Refluxing the column with a condensed part of the feed stream, i.e. fractionator top is stripped or self-rectified
- F25J 2210/06: Splitting of the feed stream, e.g. for treating or cooling in different ways
- F25J 2215/04: Recovery of liquid products
- F25J 2220/64: Separating heavy hydrocarbons, e.g. NGL, LPG, C4+ hydrocarbons or heavy condensates in general
- F25J: LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS {OR LIQUEFIED GASEOUS} MIXTURES BY PRESSURE AND COLD TREATMENT {OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE (cryogenic pumps F04B37/08; gas storage vessels, gas holders F17; filing vessels with, or discharging from vessels, compressed, liquefied or solidified gases F17C; refrigeration machines, plants, or systems F25B)}

## Abstract

A pressurized natural gas is liquefied through at least one cooling cycle, in which a mixture of cooling fluids is used, comprising at least the following steps: a) at least some of the said cooling mixture is condensed by compression and cooling, for example, using an external cooling fluid to obtain at least one vapor fraction and one liquid fraction, b) at least some of each of the vapor and liquid fractions is expanded separately to obtain a light fluid M1 comprising mostly a vapor phase and a heavy fluid M2 comprising mostly a liquid phase, c) the fluids M1 and M2 are at least partially mixed to obtain a low-temperature mixture, and d) the natural gas is liquified and undercooled under pressure by a process of heat exchange with the low-temperature mixture produced during step c).

## Claims

### Claim 1

Method of liquefying a pressurised natural gas in at least one cooling cycle using a mixture of cooling fluids, comprising the steps of:
at least partially condensing the cooling fluid mixture by compressing it and cooling it using an external cooling fluid, to obtain at least on vapour fraction and at least one liquid fraction,
separating the at least one vapour fraction from the at least one liquid fraction in a separator;
separately expanding each of the vapour and liquid fractions in separate expansion devices to produce a light fluid M1 mainly consisting of a vapour phase and a heavy fluid M2 mainly consisting of a liquid phase, wherein at least a portion of the vapour fraction is fed directly from the separator to the expansion device and directly expanded after being separated from the liquid fraction,
mixing at least some of the fluids M1 and M2 to obtain a low-temperature mixture, and
liquefying and undercooling the pressurised natural gas by a process of heat exchange with the low-temperature mixture.

### Claim 2 (depends on 1)

Method of liquefying a natural gas as claimed in claim 1, wherein the vapour fraction is expanded using a turbine and at least a proportion of the mechanical expansion energy is recuperated.

### Claim 3 (depends on 1)

Method of liquefying a natural gas as claimed in claim 1, wherein the cooling mixture produced as a result of the thermal exchange with the natural gas is recycled to the step of at least partially condensing the cooling fluid mixture.

### Claim 4 (depends on 1)

Liquefaction method as claimed in claim 1, further comprising cooling the fluid M2 before it is mixed with the fluid M1.

### Claim 5 (depends on 1)

Liquefaction method as claimed in claim 1, further comprising at least one additional step of cooling the cooling mixture and/or a liquid fraction and/or a vapour fraction produced by the partial condensation of this mixture and/or the natural gas is carried out.

### Claim 6 (depends on 1)

Method as claimed in claim 1, wherein the cooling fluid mixture comprises nitrogen and hydrocarbons having a number of carbon atoms ranging between 1 sand 5, the cooling fluid mixture containing at least 10% of nitrogen by molar fraction.

### Claim 7 (depends on 1)

Method of liquefying a natural gas as claimed in claim 1, wherein the cooling fluid mixture has a pressure level equal to at least 200 kPa at compressor suction during the step of at least partially condensing the cooling fluid mixture.

### Claim 8 (depends on 1)

Method of liquefying a natural gas as claimed in claim 1, wherein the fluid M1 contains less than 10% of liquid fraction by molar fraction.

### Claim 9 (depends on 1)

Liquefaction method as claimed in claim 1, wherein the natural gas contains constituents comprising hydrocarbons other than methane and/or nitrogen and/or helium, and wherein the method further comprises separating at least some of the constituents from the natural gas by evaporation and/or distillation.

### Claim 10 (depends on 1)

Liquefaction method as claimed in claim 1, further comprising expanding the pressurised natural gas in the undercooled liquid state at least partially in a turbine to a pressure close to atmospheric pressure, producing the liquefied natural gas that is then exported.

### Claim 11

Installation for cooling a fluid, particularly for liquefying a natural gas, using a cooling mixture, comprising a first device for at least partially condensing the cooling mixture, having at least one compressor (K.sub.1) operably connected to at least one condenser (C.sub.1), a separator (S.sub.1) operably connected to an output of the first device for separating a vapour fraction and a liquid fraction resulting from partial condensation in the first device, a first expansion device (T.sub.1) directly connected to a vapour fraction output of the separator (S.sub.1) for directly expanding at least a portion of the vapour fraction, a second expansion device (V.sub.1) operably connected to a liquid fraction output of the separator (S.sub.1) for expanding the liquid fraction, wherein outputs of the first (T.sub.1) and second (V.sub.1) expansion devices are operably connected to provide a mixture of expanded vapour and liquid fractions, and at least one device (E.sub.1) in which the mixture of expanded liquid and vapour fractions is brought into thermal contact with the fluid to be cooled.

### Claim 12 (depends on 11)

Installation as claimed in claim 11, the first expansion device (T.sub.1) and/or the second expansion device (V.sub.1) is a turbine.

### Claim 13 (depends on 11)

Installation as claimed in claim 11, further comprising an additional device for cooling the expanded liquid and/or vapour fractions, the natural gas or the cooling mixture.