US 5,700,884 A · Urethane modified epoxy resin from epoxy phosphate and isocyanate prepolymer

Abstract

There is provided an urethane modified epoxy resin either obtained by reaction of 100 weight portions of a preliminary condensate A! produced by reaction of an epoxy resin and an acid of a phosphorus compound or its salt or ester and 5 to 60 weight portions of an isocyanate group-terminated urethane prepolymer B! produced by reaction of a hydroxy compound and an organic polyisocyanate compound, or obtained by preparing an urethane modified epoxy resin D! from 100 weight portions of an epoxy resin and 5 to 60 weight portions of the same isocyanate group-terminated urethane prepolymer B! as the above and causing the resin D! to react with an acid of the same phosphorus compound as the above or its salt or ester. Such an urethane modified epoxy resin can advantageously be used with an active organic hardening agent to produce an adhesive resin composition, which is highly effective for bonding iron and non-ferrous metals particularly in terms of shearing strength and peeling strength.

Claims1

Dependent claims

A urethane-modified epoxy resin containing epoxy groups obtained by reacting 100 parts by weight of a preliminary condensate A! with from 5 to 60 parts by weight of an isocyanate groups-terminated urethane prepolymer B! wherein

preliminary condensate A! is produced by racing (i) an epoxy resin containing an average of two or more epoxy groups and 0.1 or more hydroxy groups per molecule, the hydroxyl equivalent of the epoxy resin is from 0.04 to 0.11 per 100 g. thereof, with (ii) an acid of a phosphorus compound having at least one P--OH group, its salt or ester per molecule, at a ratio of between 0.09 and 0.47 hydroxy group equivalent of the phosphorus compound per one epoxy group equivalent of the epoxy resin,
the isocyanate groups-terminated urethane prepolymer B! is produced by reacting (i) a polyvalent hydroxy compound with (ii) an organic polyisocyanate compound, and
the equivalent number of hydroxy groups in preliminary condensate A! is greater than the equivalent number of isocyanate groups in urethane prepolymer B!.

Dependencies are inferred from the claim text.

Urethane modified epoxy resin from epoxy phosphate and isocyanate prepolymer

Life of this patent

Urethane modified epoxy resin from epoxy phosphate and isocyanate prepolymer

Life of this patent

Abstract

Claims1