# US 5,700,452 A · Compositions for imparting an artificial tan and protecting the skin from ultra-violet radiation > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 5,700,452 A - Document ID: US5700452A - Status: Granted - Kind: A - Application number: 08/576,267 - Filed: 1995-12-21 - Granted: 1997-12-23 - Earliest claimed: 1993-04-16 - Assignees: The Procter & Gamble Company - Inventors: George Endel Deckner; Francisco Antonio Pichardo; Noelle Carolyn Alban; Marsha Carolyn Sills - Web page: https://patentgrep.com/patent/US5700452A ## CPC - A61K 8/06: Emulsions - A61K 8/062: {Oil-in-water emulsions} - A61K 8/35: Ketones, e.g. benzophenone - A61K 8/416: {Quaternary ammonium compounds (A61K8/35 takes precedence)} - A61K 8/8152: {Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers} - A61K 8/8158: {Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers} - A61Q 17/04: Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations - A61Q 19/04: for chemically tanning the skin (topical sun or radiation screening or tanning preparations A61Q17/04) - A61K 2800/5426: cationic - A61K: PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES (devices or methods specially adapted for bringing pharmaceutical products into particular physical or administering forms A61J3/00; chemical aspects of, or use of materials for deodorisation of air, for disinfection or sterilisation, or for bandages, dressings, absorbent pads or surgical articles A61L; soap compositions C11D) - A61Q: SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS ## Abstract The present invention relates to emulsion compositions which are useful for imparting both an artificial tan to human skin and for providing protection to the skin from the harmful effects of UV radiation. These compositions have good stability at acidic pH values, are highly substantive to the skin, and provide a natural looking tan. ## Claims ### Claim 1 An oil-in-water emulsion composition useful for providing an artificial tan and UV protection comprising: (a) from about 0.1% to about 20% dihydroxyacetone; (b) from about 0.1% to about 30% of a sunscreen agent; (c) from about 0.1% to about 10.0% of a crosslinked cationic polymer of the formula: (A).sub.l (B).sub.m (C).sub.n wherein (A) is a dialkylaminoalkyl acrylate monomer or its quaternary ammonium or acid addition salt, (B) is a dialkylaminoalkyl methacrylate monomer or its quaternary ammonium or acid addition salt, (C) is acrylamide, l is an integer of 0 or greater, m is an integer of 1 or greater, and n is an integer of 0 or greater, wherein said polymer contains a crosslinking agent selected from the group consisting of methlenebisacrylamides, diallyldialkyl ammonium halides, polyalkenyl polyethers of polyhydric alcohols, allyl acrylates, vinyloxyalkylacrylates, and polyfunctional vinylidenes; (d) from about 0.1% to about 10% of a cationic emulsifier in the form of a quaternary ammonium salt having the formula: ##STR2## wherein R.sub.1 is a C.sub.12-22 alkyl group or R.sub.5 CO--(CH.sub.2).sub.n -- wherein R.sub.5 is a C.sub.12-22 alkyl group and n is an integer from about 2 to about 6, R.sub.2 is H or a C.sub.1-22 alkyl group, R.sub.3 and R.sub.4 are independently an H or a C.sub.1-3 alkyl group, and X is an anion selected from the group consisting of chloride, bromide iodide, acetate, phosphate, nitrate, sulfate, methyl sulfate, ethyl sulfate, tosylate, lactate citrate, glycolate, and mixtures thereof; (e) from about 30% to about 99.6% water, wherein said composition has a pH from about 2.5 to about 7. ### Claim 2 (depends on 1) The composition according to claim 1 wherein the crosslinking agent is selected from the group consisting of methylene bisacrylamide, ethylene glycol di-(meth)acrylate, di-(meth)acrylamide, cyanomethylacrylate, vinyloxyethyl acrylate, vinyloxyethylmethacrylate, allyl pentaerythritol, trimethylolpropane diallylether, allyl sucrose, butadiene, isoprene, divinyl benzene, divinyl naphthalene, allyl acrylate, and mixtures thereof. ### Claim 3 (depends on 2) The composition according to claim 2 wherein said crosslinking agent is methylene bisacrylamide. ### Claim 4 (depends on 3) The composition according to claim 3 wherein the amount of (C) in the cationic polymer is from about 50% to about 90% molar. ### Claim 5 (depends on 3) The composition according to claim 3 wherein l in the cationic polymer is zero and the ratio of (B):(C) is from about 45:55 to about 55:45. ### Claim 6 (depends on 3) The composition according to claim 3 wherein both l and n are zero in the cationic polymer. ### Claim 7 (depends on 1) The composition according to claim 1 wherein said cationic polymer comprises from about 0.1% to about 5%. ### Claim 8 (depends on 7) The composition according to claim 7 wherein said cationic polymer comprises from about 0.5% to about 2%. ### Claim 9 (depends on 8) The composition according to claim 8 wherein said cationic polymer is selected from the group consisting of Polyquaternium 32, Polyquaternium 37, and mixtures thereof. ### Claim 10 (depends on 9) The composition according to claim 9 wherein said cationic emulsifier is selected from the group consisting of dilauryl dimethyl ammoniun chloride, distearyl dimethyl ammonium chloride, dimyristyl dimethyl ammonium chloride, dipalmityl dimethyl ammonium chloride, distearyl dimethyl ammonium chloride, and mixtures thereof. ### Claim 11 (depends on 10) The composition according to claim 10 wherein said dihydroxyacetone comprises from about 2% to about 7%. ### Claim 12 (depends on 11) The composition according to claim 11 wherein said dihydroxyacetone comprises from about 3% to about 5%. ### Claim 13 (depends on 12) The composition according to claim 12 wherein said pH is from about 2.5 to about 6. ### Claim 14 (depends on 13) The composition according to claim 13 wherein said pH is from about about 3.5 to about 5. ### Claim 15 (depends on 14) The composition according to claim 14 wherein said sunscreen agent comprises from about 0.5% to about 25%. ### Claim 16 (depends on 15) The composition according to claim 15 wherein said sunscreen agent comprises from about 1% to about 20%. ### Claim 17 (depends on 16) The composition according to claim 16 wherein said sunscreen agent is selected from the group consisting of 2-ethylhexyl N,N-dimethyl-p-aminobenzoate, 2-ethylhexyl p-methoxycinnamate, octocrylene, octyl salicylate, homomenthyl salicylate, p-aminobenzoic acid, oxybenzone, 2-phenylbenzimidazole-5-sulfonic acid, DEA p-methoxycinnamate, 4,4'-methoxy-t-butyldibenzoylmethane, 4-isopropyl dibenzoylmethane, 3-(4-methylbenzylidene) camphor, 3-benzylidene camphor, titanium dioxide, zinc oxide, iron oxide, and mixtures thereof. ### Claim 18 (depends on 17) The composition according to claim 17 which further comprises from about 0.1% to about 2% of a fatty alcohol. ### Claim 19 (depends on 18) The composition according to claim 18 wherein said fatty alcohol is selected from the group consisting of lauryl alcohol, myristyl alcohol, palmityl alcohol, stearyl alcohol, isostearic alcohol, oleyl alcohl, linoleyl alcohol, linolenyl alcohol, ricinoleyl alcohol, behenyl alcohol, and mixtures thereof. ### Claim 20 (depends on 19) The composition according to claim 19 which further comprises from about 1% to about 5% of a humectant selected from the group consisting of glycerin, butylene glycol, hexylene glycol and mixtures thereof. ### Claim 21 (depends on 20) The composition according to claim 20 which further comprises from about 1% to about 10% of an emollient selected from the group consisting of volatile silicone oils, non-volatile silicone oils, highly branched hydrocarbons, and mixtures thereof. ### Claim 22 (depends on 1) A method for providing both an artificial tan to human skin and protecting human skin from the effects of ultraviolet radiation, said method comprising topically applying to the skin an effective amount of a composition according to claim 1.