# US 5,700,404 A · Process and device for casting a large-area crystalline salt body > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 5,700,404 A - Document ID: US5700404A - Status: Granted - Kind: A - Application number: 08/553,404 - Filed: 1995-11-22 - Granted: 1997-12-23 - Earliest claimed: 1993-05-25 - Assignees: Siemens Aktiengesellschaft - Inventors: Thomas Berthold - Web page: https://patentgrep.com/patent/US5700404A ## CPC - C30B 11/00: Single-crystal growth by normal freezing or freezing under temperature gradient, e.g. Bridgman-Stockbarger method (C30B13/00, C30B15/00, C30B17/00, C30B19/00 take precedence; under a protective fluid C30B27/00) - C30B 29/12: Halides - C30B: SINGLE-CRYSTAL GROWTH (by using ultra-high pressure, e.g. for the formation of diamonds, B01J3/06); UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL (zone-refining of metals or alloys C22B); PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE (casting of metals, casting of other substances by the same processes or devices B22D; working of plastics B29; modifying the physical structure of metals or alloys C21D, C22F); SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE (for producing semiconductor devices or parts thereof H10); APPARATUS THEREFOR ## Abstract A process and device for producing an optically pure polycrystalline salt body by melting a starting material for the salt and then introducing the melted material into a casting mould having a base which is kept at a temperature of 1.degree. C. to 50.degree. C. below the melting point of the material to form a solid crust on the base and then solidifying the entire melt to form the polycrystalline salt body. ## Claims ### Claim 1 A process for the production of a polycrystalline salt body comprising the steps of: providing a furnace having a single chamber heated to a uniform temperature for melting a starting material with a composition intended for the salt body; providing a melting crucible which is inert to the salt melt, providing a casting mould with a base, producing a salt melt by inserting the crucible with the starting material and the casting mould into the chamber, introducing the salt melt into the casting mould and directly cooling only the base to keep the base at a temperature which is 1.degree.-50.degree. C. below a solidification point of the salt melt to form a solid salt crust directly on the base of the casting mould, maintaining the casting mould at a temperature below the solidification point until the supernatant salt melt has solidified completely into a polycrystalline salt body and then cooling the salt body. ### Claim 2 (depends on 1) Process according to claim 1, wherein the step of introducing the salt melt takes place continuously with the melting. ### Claim 3 (depends on 1) Process according to claim 1, wherein before the step of introducing of the salt melt, includes arranging at least two crystalline salt plates which are in block or plate form and have a composition corresponding to the salt bodies side by side on the base of the casting mould in such a way that gaps of small width remain between the plates, and the step of introducing the salt melt pours the melt over the salt plates until at least the gaps are filled with the salt melt. ### Claim 4 (depends on 3) Process according to claim 3, in which the base of the casting mould is kept at a temperature which is 5.degree.-50.degree. C. below the solidification point of the salt melt. ### Claim 5 (depends on 1) A process according to claim 1, wherein the salt body is a scintillator plate for the detection of gamma rays, in particular for the Anger camera. ### Claim 6 (depends on 1) Process according to claim 1, which includes providing a relative movement between the melting crucible and the casting mould during the introducing of the salt melt. ### Claim 7 (depends on 1) A process according to claim 1, wherein the salt body is a large-area inspection window which is suitable for shielding high-energy radiation. ### Claim 8 (depends on 1) Process according to claim 1, wherein the casting mould is a hollow cylinder with a longitudinal axis and the process includes rotating the hollow cylinder on said axis during the step of introducing the salt melt. ### Claim 9 (depends on 1) Process according to claim 1, which includes providing a protective gas atmosphere so that the melting, maintaining and cooling are carried out in the protective gas atmosphere. ### Claim 10 (depends on 3) Process according to claim 3, wherein the step of arranging uses salt plates with sloping edges so that a support area of the plates in the casting mould is larger than the surface area opposite thereto. ### Claim 11 (depends on 1) A process according to claim 1, wherein the base of the melting crucible has fine outlet openings for the salt melt, the crucible together with the casting mould form a closed device in which the crucible is connected to the mould by pressure equalization channels, wherein the step of introducing of the salt melt takes place continuously with the melting of the starting material through the outlet openings, and wherein the step of directly cooling the base includes directing a flow of cooling medium directly on an outer surface of the base. ### Claim 12 Device for the production of large-area polycrystalline salt bodies comprising: a furnace having a single chamber, a casting mould with an inert lining positioned in the chamber, a melting crucible, which is located above the casting mould and has a base region with fine outlet openings for the salt melt, the melting crucible forming together with the casting mould a closed system with pressure equalization channels, and means for directly cooling the base of the casting mould being placed in said chamber. ### Claim 13 (depends on 12) Device according to claim 12 wherein the means for directly cooling includes a cooling gas line with which a stream of cooling gas can be blown onto the base. ### Claim 14 (depends on 12) Device according to claim 12, in which the casting mould is designed as rotatable hollow cylinder and is located outside the melting crucible. ### Claim 15 (depends on 12) Device according to claim 12, in which the melting crucible and casting mould are lined with glassy carbon or a noble metal. ### Claim 16 (depends on 12) Device according to claim 12, which includes means for carrying out a horizontal relative movement between melting crucible and casting mould. ### Claim 17 (depends on 12) Device according to claim 12, in which the casting mould is designed as a rotatable hollow cylinder in which the melting crucible is located. ### Claim 18 A process for the production of a polycrystalline salt body comprising the steps of: providing a casting mould having a base with a shape of a hollow cylinder with a longitudinal axis, producing a salt melt by melting a starting material with a composition intended for the salt body in a melting crucible which is located inside the mould and is inert toward the salt melt, rotating the hollow cylinder on said axis, introducing the salt melt into the rotating casting mould while keeping at least the base at a temperature which is 1.degree.-50.degree. C. below a solidification point of the salt melt to form a solid crust directly on the base of the casting mould, maintaining the casting mould at a temperature below the solidification point until the supernatant salt melt has solidified completely into a polycrystalline salt body and then cooling the salt body.