# US 5,700,369 A · Process for adsorboaggregational flotation of Carlin type natural gold ore dressing

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- Number: US 5,700,369 A
- Document ID: US5700369A
- Status: Granted
- Kind: A
- Application number: 08/783,012
- Filed: 1997-01-14
- Granted: 1997-12-23
- Earliest claimed: 1997-01-14
- Assignees: Guangzhou Institute of Geochemistry, Chinese Academy of Sciences
- Inventors: Zheng Zhou; Zailan Zou
- Web page: https://patentgrep.com/patent/US5700369A

## CPC

- B03D 1/02: Froth-flotation processes
- B03D 1/016: Macromolecular compounds
- B03D 2201/002: Coagulants and Flocculants
- B03D 2203/025: Precious metal ores
- B03D: FLOTATION; DIFFERENTIAL SEDIMENTATION (sedimentation in general B01D21/00; in combination with other separation of solids B03B; sink-float separation B03B5/28; detergents, soaps C11D)

## Abstract

A novel process for adsorptive aggregation and also floatation of Carling type gold ores, which goes far beyond the conventional floatation method. Said novel technological procedures comprise fine grinding as well as sluicing of raw ores and adding special floatation agents such as stripping agent, adsorptive aggregation agent as well as collecting agent and flocculant in the course of coarse screening and sweep screenings. The fine ore obtained using the present process is graded as 22 g/T with a recovery yield langer than 83%. Said process has a screening index high and stable, it is safe and reliable and can be effectively put into industrial production.

## Claims

### Claim 1

A novel process for adsorptive aggregation and floatation of Carling type mine natural gold ores, comprising the following procedures:
(1) above 80% mineral ores are finely ground to smaller than 200 mesh;
(2) the mineral ores after being ground are first sluiced;
(3) then the sluiced ores are carried out a floatation which comprises coarse screening and sweep screenings, wherein the following preparations are sequentially added:
a. a stffficient amount of "the stripping agent" is added, the composition (weight percentage) of which is: 0.025.about.1 fiuorosodium silicate, 0.03.about.1 lactic acid, 0.03.about.1.6 lead nitrate, 0.4.about.5 acid, and the rest water;
b. a sufficient amount of "the adsorptive aggregation agent" wherein the composition (weight percentage) is: 5.about.20 coal oil, 0. 1.about.3 machine oil, 0.1.about.2 turpentine oil, 0.1.about.1 ethyl xanthine, 0.05.about.0.5 dodecylamine and the rest water;
c. a sufficient amount of "xanthine collecting agent";
d. a sufficient amount of "flocculant".

### Claim 2

The process of chaim 1 wherein the floatation comprises firstly one coarse screening and subsequently two sweep screenings.

### Claim 3 (depends on 1, 2)

The process of claim 1 or claim 2 wherein the additions of the preparations for each ton of mineral ores in the coarse screening of said floatation are: stripping agent 0.3.about.0.7 kg, adsorptive aggregation agent 0.6.about.1.0 kg, xanthine collecting agent 0.1.about.0.3 kg, flocculant 0.02.about.0.07 kg; and the additions of the preparations for each ton of mineral ores in the sweep screening are: stripping agent 0.15.about.0.35 kg, adsorptive aggregation agent 0.3.about.0.5 kg, xanthine collecting agent 0.05.about.0.15 kg, flocculant 0.01.about.0.03 kg.

### Claim 4 (depends on 1)

The process of claim 1 wherein the said "stripping agent" is prescribeally prepared as follows:
a. fluorosodium silicate solution A of a prescribed concentration range of 0.1.about.4.0%;
b. lactic acid solution B of a prescribed concentration range of 0.12.about.4.0%;
c. lead nitrate solution C of a prescribed concentration range of 0.11.about.5.4%;
d. acid solution D of a prescribed concentration range of 1.5%.about.20%;
e. A is first mixed with B, then C is mixed with D, and finally A+B is mixed with C+D.

### Claim 5 (depends on 1, 4)

The process of claim 1 or 4 wherein the acid in the ingredients of the "stripping agent" is sulfuric acid or nitric acid.

### Claim 6 (depends on 1)

The of claim 1 wherein the said "adsorptive aggregation agent" is prescribedly prepared according to the following procedures:
a. ethyl xanthine and dodecylamine are dissolved in water to form the aqueous solution E, the composition (weight percentage) of which is: 0.2.about.2 acetyl xanthine, 0.05.about.0.5 dodecylamine and the rest water;
b. machine oil, turpentine oil, dodecylamine and water are added into coal oil and mixed up homogeneously, the composition thereof: coal oil 10-40, machine oil 0.2.about.6, turpentine oil 0.2.about.4, dodecylamine 0.05.about.0.5 and water the rest;
c. the mixture solution produced by step b is set static until it is clearly delaminated, then the lower layer solution is removed and water of same weight as that of lower layer solution is supplemented therein to form a new mixture solution F;
d. E and F are simultaneously added into a container, basically according to the ratio (weight) of 1:1 to be emulsified.

### Claim 7 (depends on 1)

The process of claim 1 wherein the said "xanthine collecting agent" is a xanthine mixture, consisting of ethyl xanthine, butyl xanthine, and isopentyl xanthine, the composition thereof (weight percentage): ethyl xanthine 20.about.40, butyl xanthine 20.about.40, and isopentyl xanthine 20.about.40.

### Claim 8 (depends on 1)

The process of claim 1 wherein the flocculant is polyacrylamide, dextrin or starch.

### Claim 9 (depends on 1)

The process of claim 1 wherein the concentration of said flocculant is 0.01.about.0.1%.
