Treatment of polyvinylchloride
OwnerDerek Frayinventor
Life of this patent
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Abstract
A method is described which allows two hazardous waste products, namely PVC and electric arc furnace dust, both of which have negative commercial value, to be combined to produce an iron oxide suitable for steel making and making pure cadmium lead and zinc and chlorine, all of which can be sold. The heat generated during the exothermic reaction may be used to generate electricity which may be sold or used in plants where the reaction is carded out. The method can also be used for metal scraps.
Claims6
A method of treating PVC, chlorinated rubbers or chlorinated polymers comprising the steps of:
- combining PVC, chlorinated rubber, or chlorinated polymer at an elevated temperature with a mixture of metals and/or metal compounds containing at least one ferrous metal value and at least one non-ferrous metal value, wherein the non-ferrous metal value is selected from zinc, lead, cadmium, copper, and tin;
- reacting the PVC, chlorinated rubber, or chlorinated polymer with an excess of air or oxygen with the mixture to convert the non-ferrous metal values to volatile chlorides, to partially convert the ferrous metals to ferrous metal oxides, and to remain unchanged any ferrous metal oxides.
A method of treating PVC, chlorinated rubbers or chlorinated polymers comprising the steps of:
- burning PVC, chlorinated rubber, or chlorinated polymer in excess of air or oxygen to produce chlorinated combustion gases;
- contacting a mixture of metals and/or metal compounds containing at least one ferrous metal value and at least one non-ferrous metal value with the chlorinated combustion gases in oxygen or excess air, wherein the non-ferrous metal value is selected from zinc, lead, cadmium, copper, and tin, and wherein the non-ferrous metal values are converted to volatile chlorides, the ferrous metals are partially converted to ferrous metal oxides, and the ferrous metal oxides remain unchanged.
A method of treating a feed containing one or more iron metal values contaminated with one or more non-ferrous metal values selected from zinc, lead, cadmium, copper, and tin, comprising the steps of:
- combining said feed with PVC, chlorinated rubber or a chlorinated polymer, and air or oxygen in the presence of boron oxide or silicon oxide at an elevated temperature, wherein the PVC, chlorinated rubber or chlorinated polymer burns in the air or oxygen to produce hydrochloric acid;
- and
- reacting the non-ferrous metal values with the hydrochloric acid to form volatile chlorides and partially converting the ferrous metals into ferrous oxides.
Dependencies are inferred from the claim text.