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US 5,693,826 AGranted
Process for the production of unsaturated phosphonic ester
AssigneeDirector-General of Agency of Industrial Science and Technology
InventorsMasato Tanaka, Li-Biao Han
Life of this patent
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Abstract
An unsaturated phosphonic ester is produced by reaction of an acetylene compound with a secondary phosphite in the presence of a palladium complex catalyst.
Claims2
A process for the production of an unsaturated phosphonic ester expressed by the following formula:
- R.sup.1 CH.dbd.C(R.sup.2)PO(OR.sup.3).sub.2
- wherein R.sup.1 and R.sup.2 are independently selected from the group consisting of a hydrogen atom, an alkyl group, a cycloalkyl group, an aryl group, a heteroaryl group, an aralkyl group, an alkenyl group, an alkoxy group, an aryloxy group and a silyl group and R.sup.3 is selected from the group consisting of an alkyl group, a cycloalkyl group, an aralkyl group and an aryl group, said process comprising reacting an acetylene compound expressed by the following formula:
- R.sup.1 C.dbd.CR.sup.2
- wherein R.sup.1 and R.sup.2 are as defined above, with a secondary phosphite expressed by the following formula:
- HPO(OR.sup.3).sub.2
- wherein R.sup.3 is as defined above, in the presence of a palladium complex catalyst.
3 more elements
A process for the production of an unsaturated phosphonic ester expressed by at least one of the following formulas:
- R.sup.4 CH.dbd.CPO(OR.sup.3).sub.2 !--R.sub.5 --CPO(OR.sup.3).sub.2 !.dbd.CHR.sup.6
- R.sup.4 CPO (OR.sup.3).sub.2 !.dbd.CH--R.sup.5 --CH.dbd.CR.sup.6 PO (OR.sup.3).sub.2 !
- wherein R.sup.3 is selected from the group consisting of an alkyl group, a cycloalkyl group, an aralkyl group and an aryl group, R.sup.4 and R.sup.6 are independently selected from the group consisting of a hydrogen atom, an alkyl group, a cycloalkyl group, an aryl group, a heteroaryl group, an aralkyl group, an alkenyl group, an alkoxy group, an aryloxy group and a silyl group and R.sup.5 is a divalent group selected from the group consisting of an alkylene group, a cycloalkylene group, an arylene group, a heteroarylene group, an aralkylene group, an alkenylene group, an alkylenedioxy group, an arylenedioxy group, an oxaalkylene group and an oxaalkylenearylene group, said process comprising reacting an acetylene compound expressed by the following formula:
- R.sup.4 C.tbd.C--R.sup.5 --C.tbd.CR.sup.6
- wherein R.sup.4, R.sup.5 and R.sup.6 are as defined above, with a secondary phosphite expressed by the following formula:
- HPO(OR.sup.3).sub.2
- wherein R.sup.3 is as defined above, in the presence of a palladium complex catalyst.
4 more elements
Dependencies are inferred from the claim text.