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US 5,691,443 AGranted
Drawable high tensile strength aramids
AssigneeE. I. Du Pont de Nemours and Company
InventorRobert Samuel Irwin
Life of this patent
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Abstract
Aramids which after drawing have high tensile strengths and tensile moduli are made from units derived from selected 2,2'-disubstituted-4,4'-diaminobiphenyls, p-phenylenediamine, oxydianiline and terephthalic acid. Also disclosed is a process for drawing such aramids at least 1.5%, which results in the drawn aramid having significant crystallinity and higher tensile strength. The aramids are useful for ropes and composites.
Claims36
A process for drawing aramids, comprising,
- heating an aramid selected from the group consisting of:
- aramid A consisting essentially of about 70 to about 95 mole percent of a first unit of the formula ##STR11## and about 30 to about 5 mole percent of a second unit of the formula ##STR12## wherein X.sup.1 and X.sup.2 are independently selected from the group consisting of chlorine, bromine and methyl;
- and
- aranid B consist essentially of about up to 7 mole percent of a first unit of the formula ##STR13## about 30 to about 70 mole percent of a second unit of the formula ##STR14## and about 70 to about 30 mole percent of a third unit of the formula ##STR15## wherein X.sup.1 and X.sup.2 are independently selected from the group consisting of chlorine, bromine and methyl
- to a temperature at which said aramid can be drawn;
- drawing said aramid at said temperature by applying sufficient force to draw said aramid;
- provided that:
- said aramid is drawn at least 1.5%;
- said drawn aramid has an apparent crystallite size of about 35 Angstroms or larger;
- said drawn aramid has an orientation angle of 12.degree. or less;
- said drawn aramid has a tensile strength of about 20 grams per denier or more;
- and
- the tensile strength of said drawn aramid is at least 1.15 times that of said undrawn aramid.
10 more elements
Dependencies are inferred from the claim text.