Phenolic resin molding material
AssigneeSumitomo Bakelite Co., Ltd.
InventorsTamotsu Ishida, Masatoshi Yamoto
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Abstract
The present invention provides a phenolic resin molding material high in flowability and heat stability in the molten state and excellent in curability at high temperatures which contains (a) a high ortho-novolak type phenolic resin having a number-average molecular weight of 350-500 and an ortho-bond/para-bond ratio of 1.5-2.5, (b) hexamethylene-tetramine, (c) a low-molecular polyolefin compound and (d) a filler. This phenolic resin molding material can further contain a crystalline phenolic compound having two or more benzene rings and/or a monohydric aliphatic alcohol to further improve the flowability, heat stability and curability.
Claims20
A phenolic resin molding material which contains (a) a high ortho-novolak type phenolic resin having a number-average molecular weight of 350-500 and an ortho-bond/para-bond ratio of 1.5-2.5, (b) hexamethylenetetramine, (c) a low-molecular weight polyolefin compound and (d) a filler.
A phenolic resin injection molding material having a melt viscosity at 100.degree. C. of 10.sup.3 Pa.s or lower, consisting essentially of
- (a) 100 parts by weight of a high ortho-novolak phenolic resin having a number-average molecular weight of 380-450 and an ortho-bond/para-bond ratio of 1.8-2.3,
- (b) 12-20 parts by weight of hexamethylenetetramine,
- (c) 0.1-10 parts by weight of a low-molecular weight polyethylene having a number average molecular weight of 300-3,000,
- (d) filler in an amount of 80-30% by weight based on the total weight of said composition,
- (e) optionally a crystalline phenolic compound having at least two benzene rings, solid at room temperature and forming a low viscosity melt at injection molding temperatures, said crystalline phenolic compound (e) when present being in an amount in a ratio with said phenolic resin of (a)/(e)=20/80 to 90/10,
- (f) optionally a compound for improving curing rate while maintaining low viscosity, said compound (f) having two or more hydroxyl groups on a benzene ring, when present being in an amount based on the total amount of (a) and (e) in the ratio (a)+(e)!/(f)=99/1 to 90/10, and
- (g) optionally 1-20 parts by weight of a monohydric alcohol having 5 or fewer carbon atoms and a boiling point of 80.degree.-140.degree. C.
Dependencies are inferred from the claim text.