Silicone rubber compositions for high-voltage electrical insulators
AssigneeShin-Etsu Chemical Co., Ltd.
InventorsSyuuichi Azechi, Takeo Yoshida
Life of this patent
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Abstract
A silicone rubber composition comprising (A) an organopolysiloxane having at least two aliphatic unsaturated hydrocarbon groups attached to a silicon atom, (B) finely divided silica, (C) aluminum hydroxide surface treated with silazanes, (D) an organohydrogenpolysiloxane having at least two hydrogen atoms attached to a silicon atom, and (E) a platinum catalyst is suitable for use as a high-voltage electrical insulator. The silicone rubber has durable high-voltage electrical insulating properties and is firmly bondable to core materials.
Claims12
A silicone rubber composition for use as a high-voltage electrical insulator comprising
- (A) 100 parts by weight of an organopolysiloxane of the following average compositional formula (1):
- R.sup.1.sub.a R.sup.2.sub.b SiO.sub.(4-a-b)/2 ( 1)
- wherein R.sup.1 is a halo-substituted or unsubstituted aliphatic unsaturated monovalent hydrocarbon group, R.sup.2 is a halo-substituted or unsubstituted monovalent hydrocarbon group free of an aliphatic unsaturated bond, and letters a and b are positive numbers in the range:
- 0<a.ltoreq.1, 1.ltoreq.b <3, and 1<a+b.ltoreq.3, said organopolysiloxane having at least two aliphatic unsaturated hydrocarbon groups each attached to a silicon atom in a molecule,
- (B) 1 to 100 parts by weight of finely divided silica based on 100 parts by weight of (A),
- (C) 50 to 300 parts by weight of surface treated aluminum hydroxide based on 100 parts by weight of (A), wherein the aluminum hydroxide is of the formula Al.sub.2 O.sub.3hu . 3HO.sub.2 O,
- (D) an organohydrogenpolysiloxane of the following average compositional formula (2):
- R.sup.3.sub.c H.sub.d SiO.sub.(4-c-d)/2 ( 2)
- wherein R.sup.3 is a halo-substituted or unsubstituted monovalent hydrocarbon group exclusive of an aliphatic unsaturated group, and letters c and d are positive numbers in the range:
- 1.ltoreq.c<3, 0<d.ltoreq.1, and 1<c+d.ltoreq.3, said organohydrogenpolysiloxane having at least two hydrogen atoms each attached to a silicon atom in a molecule, in a sufficient amount to provide 0.5 to 20 mol of the silicon atom-attached hydrogen atom per mol of the aliphatic unsaturated hydrocarbon group in component (A) , and
- (E) a catalytic amount of a platinum group catalyst.
Dependencies are inferred from the claim text.