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US 5,691,081 AGranted
Battery containing bis(perfluoroalkylsulfonyl)imide and cyclic perfluoroalkylene disulfonylimide salts
AssigneeMinnesota Mining and Manufacturing Company
InventorsLarry J. Krause, John W. Summerfield
Life of this patent
Estimating the term…
Abstract
A high performance battery containing an aluminum current collector is described which includes a noncorrosive salt disposed in a matrix, said salt being a bis(perfluoroalkylsulfonyl)imide having a total of at least 3 carbon atoms or a cyclic(perfluoroalkylenedisulfonyl)-imide.
Claims18
A battery comprising:
- at least one positive electrode;
- at least one negative electrode;
- at least one aluminum current collector in electrical contact with the positive electrode;
- an electrolyte composition comprising a salt disposed in a matrix, said salt having the formula ##STR9## in which R.sub.f1 and R.sub.f2 are each independently a straight or branched perfluoroalkyl group of 1 to 12 carbon atoms, a perfluorocycloalkyl group or a perfluorocycloalkyl perfluoroalkyl group of 4-7 ring carbon atoms and 1-4 carbon atoms on the alkyl chain wherein the ring carbon atoms may be optionally substituted by a straight or branched perfluoroalkyl group of 1 to 12 carbon atoms, with R.sub.f1 and R.sub.f2 taken together having a total of at least 3 carbon atoms;
- R.sub.f3 is a perfluoroalkylene moiety of 2 to 6 carbon atoms optionally substituted by a straight or branched perfluoroalkyl group of 1 to 12 carbon atoms or a perfluorocycloalkyl group of 4-7 carbon atoms;
- M is a cation with a valence equal to n;
- and
- n is an integer of 1 to 4, wherein the voltage measured at the positive electrode is greater than 3.0 volts vs. Li/Li.sup.+ ;
- and
- the electrolyte composition further comprises a NO.sub.3.sup.- salt.
7 more elements
A rechargeable battery comprising:
- at least one positive electrode;
- at least one negative electrode;
- at least one aluminum current collector in electrical contact with the positive electrode;
- and
- an electrolyte composition comprising a salt disposed in a matrix, said salt having the formula ##STR10## in which R.sub.f1 and R.sub.f2 are each independently a straight or branched perfluoroalkyl group of 1 to 12 carbon atoms, a perfluorocycloalkyl group or a perfluorocycloalkyl perfluoroalkyl group of 4-7 ring carbon atoms and 1-4 carbon atoms on the alkyl chain wherein the ring carbon atoms may be optionally substituted by a straight or branched perfluoroalkyl group of 1 to 12 carbon atoms, with R.sub.f1 and R.sub.f2 taken together having a total of at least 3 carbon atoms;
- R.sub.f3 is a perfluoroalkylene moiety of 2 to 6 carbon atoms optionally substituted by a straight or branched perfluoroalkyl group of 1 to 12 carbon atoms or a perfluorocycloalkyl group of 4-7 carbon atoms;
- M is a cation with a valence equal to n;
- and
- n is an integer of 1 to 4;
- and
- the electrolyte composition further comprises a NO.sub.3.sup.- salt.
8 more elements
Dependencies are inferred from the claim text.