US 5,689,014 A · Integrated process for producing diisopropyl ether and an isopropyl tertiary alkyl ether

Abstract

A highly integrated process for concurrently producing diisopropyl ether and an isopropyl tertiary alkyl ether has been developed. In a first reactor, propylene and water are reacted to form isopropyl alcohol, a portion of which is further reacted to form diisopropyl ether. After removing unreacted propylene, the effluent of the first reactor is separated into an ether rich stream, a water rich stream and an alcohol rich stream. The alcohol rich stream and isobutylene, isoamylene or a mixture thereof are reacted to form an isopropyl tertiary alkyl ether in a second reactor. The water present in the alcohol rich stream also reacts with the iso-olefin to form tertiary alcohol. The effluent from the second reactor is water washed to produce an oxygenate product stream and an aqueous alcohol recycle stream. Some tertiary alcohol is recycled to the first reactor where it is reacted with propylene to form additional isopropyl tertiary alkyl ether. The isopropyl tertiary alkyl ether and some tertiary alcohol is collected along with the diisopropyl ether in the mixed oxygenate product stream from the water wash.

Claims14

Dependent claims

An integrated process for producing diisopropyl ether and an isopropyl tertiary alkyl ether comprising:

a. reacting propylene, water, a tertiary alcohol, and isopropyl alcohol in the presence of an acidic catalyst to afford a first reaction zone effluent;
b. recycling a portion of the first reaction zone effluent to step (a) and removing propylene from the remainder to afford a propylene-depleted stream;
c. separating the propylene-depleted stream into an ether enriched stream, an alcohol enriched stream, and a water enriched stream;
d. reacting the alcohol enriched stream with isobutylene, isoamylene, or a mixture thereof present in a feed stream further containing inert material, in the presence of an acidic catalyst to afford a second reaction zone effluent and an aqueous stream;
e. recycling the aqueous stream to step (a);
f. removing the inert material, and isobutylene, isoamylene, or the mixture thereof from the second reaction zone effluent to afford an iso-olefin depleted stream;
g. water washing a mixture of the iso-olefin depleted stream, the ether enriched stream, and the water enriched stream to afford an aqueous alcohol stream and an oxygenate stream;
h. recycling the aqueous alcohol stream to step (c);
and
i. collecting the oxygenate stream.

7 more elements

An integrated process for producing diisopropyl ether and an isopropyl tertiary alkyl ether comprising:

a) reacting
i. propylene and water,
ii. an alcohol enriched recycle stream containing water, isopropyl alcohol, and tertiary alcohol, from a separator, and
iii. a recycle stream containing isopropyl alcohol and water, from a second reaction zone,
in a first reaction zone in the presence of an acidic catalyst to produce a first reaction zone effluent containing propylene, water, isopropyl alcohol, diisopropyl ether, tertiary alcohol, and isopropyl tertiary alkyl ether;
b) recycling a portion of the first reaction zone effluent to the first reaction zone and removing the propylene from the remainder to produce a stream containing water, isopropyl alcohol, diisopropyl ether, tertiary alcohol, and isopropyl tertiary alkyl ether;
c) separating a mixture of the stream containing water, isopropyl alcohol, diisopropyl ether, tertiary alcohol, and isopropyl tertiary alkyl ether and a recycle stream from a water wash unit containing isopropyl alcohol, tertiary alcohol, and water in a separator to produce an ether enriched stream containing diisopropyl ether and isopropyl tertiary alkyl ether, an alcohol enriched stream containing water, isopropyl alcohol, and tertiary alcohol, and a water enriched stream;
d) recycling a portion of the alcohol enriched stream to the first reaction zone;
e) reacting the water and isopropyl alcohol present in a portion of the alcohol enriched stream with isobutylene, isoamylene, or a mixture thereof present in a feed stream further containing inert material, in a second reaction zone in the presence of an acidic catalyst to produce a second reaction zone effluent containing isobutylene, isoamylene, or the mixture thereof, water, isopropyl alcohol, tertiary alcohol, isopropyl tertiary alkyl ether, and inert material, and a stream containing water and isopropyl alcohol;
f) recycling the stream containing water and isopropyl alcohol to the first reaction zone;
g) removing the inert material, and isobutylene, isoamylene, or the mixture thereof from the second reaction zone effluent to produce a stream containing water, isopropyl alcohol, tertiary alcohol and isopropyl tertiary alkyl ether;
h) water washing a mixture of the ether enriched stream, the water enriched stream, and the stream containing water, isopropyl alcohol, tertiary alcohol and isopropyl tertiary alkyl ether to produce a stream containing isopropyl alcohol, tertiary alcohol, and water, and a product stream containing diisopropyl ether, isopropyl tertiary alkyl ether and tertiary alcohol;
and
i) recycling the stream containing isopropyl alcohol, tertiary alcohol, and water from the water wash to the separator.

11 more elements

Dependencies are inferred from the claim text.

Integrated process for producing diisopropyl ether and an isopropyl tertiary alkyl ether

Life of this patent

Integrated process for producing diisopropyl ether and an isopropyl tertiary alkyl ether

Life of this patent

Abstract

Claims14