Preparation of hydroxybenzaldehydes
AssigneeRhone-Poulenc Chimie
InventorHelene Lefranc
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Abstract
Hydroxybenzaldehydes, for example salicylaldehyde, are prepared in high yields by oxidizing the corresponding hydroxybenzyl alcohols, e.g., saligenol, with molecular oxygen or an oxygen-containing gas, in liquid phase, in an aqueous reaction medium containing an alkali, in the presence of (i) a catalytically effective amount of a platinum catalyst and (ii) a cocatalytically effective amount of boron and bismuth compounds.
Claims29
A process for the preparation of a hydroxybenzaldehyde, comprising oxidizing the corresponding hydroxybenzyl alcohol with oxygen, in liquid phase, in an aqueous reaction medium which comprises an alkali, in the presence of (i) a catalytically effective amount of a platinum compound and (ii) a cocatalytically effective amount of both boron and bismuth compounds.
Dependencies are inferred from the claim text.